Lemon - UK

Page 1

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 1/12

Lemon SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Trade name/designation:

Lemon

Other means of identification: FIBER: 56-1994, 56-1990, 56-1708, 56-1721, 56-1322, 56-1328, 56-1927 CORRUGATED MEMBRANES AND CARTRIDGES: 56-1758, 56-1365, 56-1463 UFI: 54A3-ANCQ-Q80W-PM1T

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: aromatisation

Relevant identified uses:

Life cycle stage [LCS] PW: Widespread use by professional workers Product Categories [PC] PC 28: Perfumes, fragrances

1.3. Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Logistic Sarl 6 Route du Grand Lancy 1211 Genève 26 Switzerland Telephone: +41 22 342 2145 E-mail: vaportek@gmail.com

E-mail (competent person): vaportek@gmail.com

1.4. Emergency telephone number 24h: NHS (National Health Service): 111

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories

Hazard statements

Classification procedure Calculation method.

Skin corrosion/irritation (Skin Irrit. 2)

H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

Calculation method.

Aspiration hazard (Asp. Tox. 1)

Respiratory or skin sensitisation (Skin Sens. 1)

Calculation method.

Hazardous to the aquatic environment H412: Harmful to aquatic life with long Calculation method. (Aquatic Chronic 3) lasting effects.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 2/12

Lemon 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms:

GHS07

GHS08

Exclamation mark

Health hazard

Signal word: Danger Hazard components for labelling: citral; Lemon Oil Terpenes; Hexyl Cinnamal; 7-hydroxycitronellal Hazard statements for health hazards H304

May be fatal if swallowed and enters airways.

H317

May cause an allergic skin reaction.

H315

Causes skin irritation.

Hazard statements for environmental hazards H412

Harmful to aquatic life with long lasting effects.

Precautionary statements Prevention P264

Wash hands thoroughly after handling.

P280

Wear protective gloves and eye/face protection.

P273

Avoid release to the environment.

Precautionary statements Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 P391

If eye irritation persists: Get medical advice/attention. Collect spillage.

Precautionary statements Disposal P501

Dispose of contents/container to an appropriate recycling or disposal facility.

* 2.3. Other hazards

Adverse physicochemical effects: No further relevant information available. Adverse human health effects and symptoms: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol 98-55-5 202-680-6 Benzyl salicylate 118-58-1 204-262-9 2,6-di-tert-butyl-p-cresol 128-37-0 204-881-4 Adverse environmental effects: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol 98-55-5 202-680-6 Benzyl salicylate 118-58-1 204-262-9 2,6-di-tert-butyl-p-cresol 128-37-0 204-881-4 The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Other adverse effects: No further relevant information available.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 3/12

Lemon SECTION 3: Composition/information on ingredients 3.2. Mixtures

Hazardous ingredients / Hazardous impurities / Stabilisers: Product identifiers

Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] citral Skin Irrit. 2 (H315), Skin Sens. 1 (H317)

10 – ≤ 20 weight-%

CAS No.: 68917-33-9 EC No.: 614-796-8

Lemon Oil Terpenes Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)

8 – ≤ 15 weight-%

CAS No.: 8050-15-5 EC No.: 232-476-2

Resin acids and Rosin acids, hydrogenated, Me esters Aquatic Chronic 3 (H412)

6 – ≤ 12 weight-%

CAS No.: 5392-40-5 EC No.: 226-394-6 Index No.: 605-019-00-3

Warning

Danger

CAS No.: 101-86-0 EC No.: 202-983-3

Hexyl Cinnamal Skin Sens. 1 (H317) Warning

4–<8 weight-%

CAS No.: 18479-58-8 EC No.: 242-362-4

2,6-dimethyloct-7-en-2-ol Eye Irrit. 2 (H319), Skin Irrit. 2 (H315)

2–≤5 weight-%

CAS No.: 107-75-5 EC No.: 203-518-7

7-hydroxycitronellal Eye Irrit. 2 (H319), Skin Sens. 1B (H317)

1–≤4 weight-%

CAS No.: 105-87-3 EC No.: 203-341-5

geranyl acetate Aquatic Chronic 3 (H412), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)

1 – ≤ 2.5 weight-%

CAS No.: 61792-11-8 EC No.: 263-214-5

3,7-dimethylnona-2,6-dienenitrile Aquatic Chronic 2 (H411)

1 – ≤ 2.5 weight-%

CAS No.: 103-95-7 EC No.: 203-161-7

3-p-cumenyl-2-methylpropionaldehyde Aquatic Chronic 3 (H412), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

1 – ≤ 2.5 weight-%

CAS No.: 88-41-5 EC No.: 201-828-7

2-tert-butylcyclohexyl acetate Aquatic Chronic 2 (H411)

0 – ≤ 2.5 weight-%

CAS No.: 5413-60-5 EC No.: 226-501-6

3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate Aquatic Chronic 3 (H412)

0 – ≤ 2.5 weight-%

CAS No.: 32210-23-4 EC No.: 250-954-9

Warning

Warning

Warning

Warning

4-tert-butylcyclohexyl acetate Skin Sens. 1B (H317) Warning

0–≤1 weight-%

CAS No.: 98-55-5 EC No.: 202-680-6

p-menth-1-en-8-ol Eye Irrit. 2 (H319), Skin Irrit. 2 (H315)

0–≤1 weight-%

CAS No.: 122-40-7 EC No.: 204-541-5

2-benzylideneheptanal Aquatic Acute 1 (H400), Aquatic Chronic 2 (H411)

0 – ≤ 0.5 weight-%

CAS No.: 118-58-1 EC No.: 204-262-9

benzyl salicylate Aquatic Chronic 3 (H412), Eye Irrit. 2 (H319), Skin Sens. 1B (H317)

0 – ≤ 0.5 weight-%

linalool Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

0 – < 0.25 weight-%

CAS No.: 78-70-6 EC No.: 201-134-4

Warning

Warning M-factor (acute): 1

Warning

Warning

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 4/12

Lemon Product identifiers CAS No.: 115-95-7 EC No.: 204-116-4 CAS No.: 128-37-0 EC No.: 204-881-4

Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] linalyl acetate Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)

0 – ≤ 0.25 weight-%

2,6-di-tert-butyl-p-cresol Aquatic Chronic 1 (H410)

0 – ≤ 0.1 weight-%

Warning

Warning Full text of H- and EUH-phrases: see section 16.

SECTION 4: First aid measures 4.1. Description of first aid measures

General information: In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Remove victim out of the danger area. Remove contaminated, saturated clothing. If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended. Warning First aider: Pay attention to self-protection! Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician. In case of skin contact: After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing. If skin irritation or rash occurs: Get medical advice/ attention. After eye contact: In case of contact with eyes, rinse immediately thoroughly with plenty of edible oil and consult an ophthalmologist. Following ingestion: Ingestion of the mixture / product is hardly possible. Rinse mouth. Get medical advice/attention if you feel unwell. Do NOT induce vomiting. Observe risk of aspiration if vomiting occurs. Get immediate medical advice/ attention. Self-protection of the first aider: Use personal protection equipment.

4.2. Most important symptoms and effects, both acute and delayed Causes skin irritation. Allergic reactions Serious eye damage/eye irritation

4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable extinguishing media: alcohol resistant foam Extinguishing powder Carbon dioxide (CO2) Unsuitable extinguishing media: Full water jet

5.2. Special hazards arising from the substance or mixture Combustible Hazardous combustion products: Gases/vapours, irritant according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 5/12

Lemon 5.3. Advice for firefighters

Wear a self-contained breathing apparatus and chemical protective clothing.

5.4. Additional information

Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Personal precautions: Remove persons to safety. Protective equipment: Wear protective gloves/protective clothing/eye protection/face protection.

6.1.2. For emergency responders

Personal protection equipment: Personal protection equipment: see section 8

6.2. Environmental precautions

Do not allow to enter into surface water or drains.

6.3. Methods and material for containment and cleaning up For cleaning up: Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13

6.5. Additional information

Use appropriate container to avoid environmental contamination.

SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures

Advices on safe handling: Wear personal protection equipment (refer to section 8). Fire prevent measures: Take precautionary measures against static discharge. Keep away from sources of ignition - No smoking.

Advices on general occupational hygiene When using do not eat, drink or smoke. Avoid contact with eyes and skin.

7.2. Conditions for safe storage, including any incompatibilities Technical measures and storage conditions: Keep container tightly closed in a cool, well-ventilated place. Storage class (TRGS 510, Germany): 4.1B – Flammable solids

7.3. Specific end use(s) No data available

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 6/12

Lemon SECTION 8: Exposure controls/personal protection 8.1. Control parameters

8.1.1. Occupational exposure limit values

① Long-term occupational exposure limit value ② Short-term occupational exposure limit value ③ Instantaneous value ④ Monitoring and observation processes ⑤ Remark ① 10 mg/m³

Limit value type Substance name (country of origin)

WEL (GB)

2,6-di-tert-butyl-p-cresol CAS No.: 128-37-0 EC No.: 204-881-4

8.1.2. Biological limit values No data available

8.1.3. DNEL-/PNEC-values No data available

8.2. Exposure controls 8.2.1. Appropriate engineering controls No data available

8.2.2. Personal protection equipment

Eye/face protection: Eye glasses with side protection EN 166 Skin protection: Tested protective gloves must be worn EN ISO 374 Suitable material: NBR (Nitrile rubber), In the case of wanting to use the gloves again, clean them before taking off and air them well. Breakthrough times and swelling properties of the material must be taken into consideration. Respiratory protection: Usually no personal respirative protection necessary. Respiratory protection necessary at: Handling larger quantities,

8.2.3. Environmental exposure controls No data available

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state: Liquid Odour: fruity

Safety relevant basis data

Colour: yellow Odour threshold: not determined

Parameter

Value

pH

not applicable

Melting point

① Method ② Remark

not determined

Freezing point

not determined

Decomposition temperature

not determined

Evaporation rate

not determined

Initial boiling point and boiling range not determined Flash point

Auto-ignition temperature

Upper/lower flammability or explosive limits Vapour pressure

according to Regulation (EC) No. 2020/878 (REACH)

71 °C not determined not determined not determined en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 7/12

Lemon Parameter

Value

Vapour density

not determined

Relative density

not determined

Density

① Method ② Remark

> 0.93 – < 0.94 g/cm³

Bulk density

not determined

Water solubility

not determined

Dynamic viscosity

not determined

Partition coefficient: n-octanol/water not determined Kinematic viscosity

not determined

9.2. Other information

Solid, inert fiber block soaked with liquid mixture for odour neutralisation. The properties listed relate to the liquid.

SECTION 10: Stability and reactivity 10.1. Reactivity

Flammable liquid and vapour. This material is considered to be non-reactive under normal use conditions.

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

10.3. Possibility of hazardous reactions No known hazardous reactions.

10.4. Conditions to avoid

Stable under recommended storage and handling conditions.

10.5. Incompatible materials

No further relevant information available.

10.6. Hazardous decomposition products

Thermal decomposition can lead to the escape of irritating gases and vapours.

SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No. 1272/2008 p-menth-1-en-8-ol

CAS No.: 98-55-5 EC No.: 202-680-6

LD50 oral: =4,300 mg/kg

LD50 dermal: >2,000 mg/kg

2-benzylideneheptanal

CAS No.: 122-40-7 EC No.: 204-541-5

LD50 dermal: 3,730 mg/kg

benzyl salicylate

CAS No.: 118-58-1 EC No.: 204-262-9

LD50 oral: >3,000 mg/kg

LD50 dermal: >2,000 mg/kg

Acute oral toxicity: Based on available data, the classification criteria are not met. Acute dermal toxicity: Based on available data, the classification criteria are not met. Acute inhalation toxicity: Based on available data, the classification criteria are not met. Skin corrosion/irritation: Causes skin irritation. Serious eye damage/irritation: Based on available data, the classification criteria are not met. Respiratory or skin sensitisation: May cause an allergic skin reaction. according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 8/12

Lemon Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity: Based on available data, the classification criteria are not met. STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Based on available data, the classification criteria are not met. Aspiration hazard: May be fatal if swallowed and enters airways. Additional information: No data available

11.2. Information on other hazards

Endocrine disrupting properties: The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol 98-55-5 202-680-6 Benzyl salicylate 118-58-1 204-262-9 2,6-di-tert-butyl-p-cresol 128-37-0 204-881-4

SECTION 12: Ecological information 12.1. Toxicity 3,7-dimethylnona-2,6-dienenitrile LC50: 2.4 mg/L 4 d (fish)

CAS No.: 61792-11-8 EC No.: 263-214-5

3-p-cumenyl-2-methylpropionaldehyde LC50: 1 mg/L 4 d (fish)

4-tert-butylcyclohexyl acetate LC50: 8.6 mg/L 4 d (fish)

2-benzylideneheptanal

LC50: 0.91 mg/L 4 d (fish)

benzyl salicylate

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 32210-23-4 EC No.: 250-954-9

CAS No.: 122-40-7 EC No.: 204-541-5

CAS No.: 118-58-1 EC No.: 204-262-9

LC50: 1.03 mg/L 4 d (fish)

linalyl acetate

CAS No.: 115-95-7 EC No.: 204-116-4

LC50: 11 mg/L 4 d (fish)

2,6-di-tert-butyl-p-cresol

CAS No.: 128-37-0 EC No.: 204-881-4

NOEC: 0.053 mg/L 21 d (fish)

Aquatic toxicity: Harmful to aquatic life with long lasting effects. Assessment/classification: No further relevant information available.

12.2. Persistence and degradability citral

CAS No.: 5392-40-5 EC No.: 226-394-6

Biodegradation: Yes, rapidly

Lemon Oil Terpenes

CAS No.: 68917-33-9 EC No.: 614-796-8

Biodegradation: Yes, rapidly

Hexyl Cinnamal

CAS No.: 101-86-0 EC No.: 202-983-3

Biodegradation: Yes, rapidly

7-hydroxycitronellal

CAS No.: 107-75-5 EC No.: 203-518-7

Biodegradation: Yes, rapidly

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 9/12

Lemon geranyl acetate

CAS No.: 105-87-3 EC No.: 203-341-5

Biodegradation: Yes, rapidly

3,7-dimethylnona-2,6-dienenitrile Biodegradation: Yes, slowly

CAS No.: 61792-11-8 EC No.: 263-214-5

3-p-cumenyl-2-methylpropionaldehyde Biodegradation: Yes, rapidly

4-tert-butylcyclohexyl acetate Biodegradation: Yes, rapidly

2-benzylideneheptanal

CAS No.: 103-95-7 EC No.: 203-161-7

CAS No.: 32210-23-4 EC No.: 250-954-9

CAS No.: 122-40-7 EC No.: 204-541-5

Biodegradation: Yes, rapidly

benzyl salicylate

CAS No.: 118-58-1 EC No.: 204-262-9

Biodegradation: Yes, rapidly

linalool

CAS No.: 78-70-6 EC No.: 201-134-4

Biodegradation: Yes, rapidly

linalyl acetate

CAS No.: 115-95-7 EC No.: 204-116-4

Biodegradation: Yes, rapidly

2,6-di-tert-butyl-p-cresol

CAS No.: 128-37-0 EC No.: 204-881-4

Biodegradation: Yes, rapidly

Biodegradation: Part of the components is biodegradable. Additional information: No further relevant information available.

12.3. Bioaccumulative potential No data available

12.4. Mobility in soil No data available

12.5. Results of PBT and vPvB assessment citral

CAS No.: 5392-40-5 EC No.: 226-394-6

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

Lemon Oil Terpenes

CAS No.: 68917-33-9 EC No.: 614-796-8

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

Hexyl Cinnamal

CAS No.: 101-86-0 EC No.: 202-983-3

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

7-hydroxycitronellal

CAS No.: 107-75-5 EC No.: 203-518-7

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

geranyl acetate

CAS No.: 105-87-3 EC No.: 203-341-5

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

3,7-dimethylnona-2,6-dienenitrile

CAS No.: 61792-11-8 EC No.: 263-214-5

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

3-p-cumenyl-2-methylpropionaldehyde

CAS No.: 103-95-7 EC No.: 203-161-7

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

2-tert-butylcyclohexyl acetate

CAS No.: 88-41-5 EC No.: 201-828-7

4-tert-butylcyclohexyl acetate

CAS No.: 32210-23-4 EC No.: 250-954-9

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

2-benzylideneheptanal

CAS No.: 122-40-7 EC No.: 204-541-5

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

benzyl salicylate

CAS No.: 118-58-1 EC No.: 204-262-9

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 10/12

Lemon linalool

CAS No.: 78-70-6 EC No.: 201-134-4

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

linalyl acetate

CAS No.: 115-95-7 EC No.: 204-116-4

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

2,6-di-tert-butyl-p-cresol

CAS No.: 128-37-0 EC No.: 204-881-4

Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.

The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

12.6. Endocrine disrupting properties

The product contains a substance that is identified as having endocrine disrupting properties. p-Menth-1-en-8-ol 98-55-5 202-680-6 Benzyl salicylate 118-58-1 204-262-9 2,6-di-tert-butyl-p-cresol 128-37-0 204-881-4

12.7. Other adverse effects No data available

SECTION 13: Disposal considerations 13.1. Waste treatment methods

The allocation of waste identity numbers/waste descriptions must be carried out according to the EWC, specific to the industry and process.

13.1.1. Product/Packaging disposal

Waste codes/waste designations according to EWC/AVV Waste code product

16 03 05 * organic wastes containing hazardous substances *: Evidence for disposal must be provided.

Waste treatment options

Appropriate disposal / Product: Consult the appropriate local waste disposal expert about waste disposal. Appropriate disposal / Package: Non-contaminated packages may be recycled. Completely emptied bricks, disks and membranes can be recycled.

13.2. Additional information * = "S" In Switzerland, commercial hazardous waste shall be delivered to a disposal company.

SECTION 14: Transport information Land transport (ADR/RID) Inland waterway craft (ADN)

Sea transport (IMDG)

Air transport (ICAO-TI / IATA-DGR)

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

No dangerous good in sense of these transport regulations.

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

not relevant

14.1. UN number or ID number

14.2. UN proper shipping name

14.3. Transport hazard class(es) 14.4. Packing group

14.5. Environmental hazards

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 11/12

Lemon Land transport (ADR/RID) Inland waterway craft (ADN)

Sea transport (IMDG)

Air transport (ICAO-TI / IATA-DGR)

not relevant

not relevant

not relevant

14.6. Special precautions for user not relevant

14.7. Maritime transport in bulk according to IMO instruments Additional information: Solid, inert fiber block soaked with liquid mixture for odour neutralisation.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU legislation

Restrictions on use: According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.

15.1.2. National regulations No data available

15.2. Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information 16.1. Indication of changes 2.3.

Other hazards

16.2. Abbreviations and acronyms ACGIH ADN

ADR CAS CLP DIN DNEL EN ES EWC ICAO IMDG IMO LC50 LD50 MAK NFPA NIOSH NOEC PBT PC PNEC REACH RID TRGS UN VOC

American Conference of Governmental Industrial Hygienists European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways European Agreement concerning the International Carriage of Dangerous Goods by Road Chemical Abstracts Service Classification, Labelling and Packaging German Institute for Standardization / German Industrial Standard derived no-effect level European Standard Exposure scenario European Waste Catalogue International Civil Aviation Organization International Maritime Dangerous Goods International Maritime Organization Lethal (fatal) Concentration 50% Lethal (fatal) Dose 50% Maximum concentration in the workplace air (CH) National Fire Protection Association National Institute for Occupational Safety & Health No Observed Effect Concentration persistent and bioaccumulative and toxic Product category Predicted No Effect Concentration Registration, Evaluation and Authorization of Chemicals Dangerous goods regulations for transport by rail Technische Regeln für Gefahrstoffe United Nations Volatile organic compounds

according to Regulation (EC) No. 2020/878 (REACH)

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 19 Dec 2022 Print date: 16 Mar 2023 Version: 2 Page 12/12

Lemon 16.3. Key literature references and sources for data

REACH Dissemination Portal https://echa.europa.eu/de/information-on-chemicals/registered-substances

16.4. Classification for mixtures and used evaluation method according to regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories

Hazard statements

Classification procedure Calculation method.

Skin corrosion/irritation (Skin Irrit. 2)

H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

Calculation method.

Aspiration hazard (Asp. Tox. 1)

Respiratory or skin sensitisation (Skin Sens. 1)

Calculation method.

Hazardous to the aquatic environment H412: Harmful to aquatic life with long Calculation method. (Aquatic Chronic 3) lasting effects.

16.5. Relevant R-, H- and EUH-phrases (Number and full text) Hazard statements H226

Flammable liquid and vapour.

H315

Causes skin irritation.

H304 H317 H319 H400 H410 H411 H412

May be fatal if swallowed and enters airways. May cause an allergic skin reaction. Causes serious eye irritation. Very toxic to aquatic life.

Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects.

Harmful to aquatic life with long lasting effects.

16.6. Training advice No data available

16.7. Additional information No data available

* Data changed compared with the previous version.

according to Regulation (EC) No. 2020/878 (REACH)

en / GB GeSi.de


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