SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 1/12
Winterspice SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Trade name/designation:
Winterspice
Other means of identification: FIBER: 56-1750, 56-1870, 56-1913 UFI: SGA3-CN49-X80V-AYD2
1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture: aromatisation
Relevant identified uses:
Life cycle stage [LCS] PW: Widespread use by professional workers Product Categories [PC] PC 28: Perfumes, fragrances
1.3. Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor): Vaportek Europe Logistic Sarl 6 Route du Grand Lancy 1211 Genève 26 Switzerland Telephone: +41 22 342 2145 E-mail: vaportek@gmail.com
E-mail (competent person): vaportek@gmail.com
1.4. Emergency telephone number 24h: NHS (National Health Service): 111
SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories
Hazard statements
Classification procedure Calculation method.
Skin corrosion/irritation (Skin Irrit. 2)
H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
Calculation method. Calculation method.
H319: Causes serious eye irritation.
Calculation method.
Aspiration hazard (Asp. Tox. 1)
Respiratory or skin sensitisation (Skin Sens. 1)
Serious eye damage/eye irritation (Eye Irrit. 2)
Hazardous to the aquatic environment H400: Very toxic to aquatic life. (Aquatic Acute 1)
Calculation method.
Hazardous to the aquatic environment H410: Very toxic to aquatic life with (Aquatic Chronic 1) long lasting effects.
Calculation method.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 2/12
Winterspice 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms:
GHS07
GHS08
Exclamation mark
Health hazard
GHS09
Environment
Signal word: Danger Hazard components for labelling: Clove terpenes; pin-2(3)-ene; coumarin; Cedar leaf oil Hazard statements for health hazards H304
May be fatal if swallowed and enters airways.
H317
May cause an allergic skin reaction.
H315 H319
Causes skin irritation.
Causes serious eye irritation.
Hazard statements for environmental hazards H410
Very toxic to aquatic life with long lasting effects.
Precautionary statements Prevention P264
Wash hands thoroughly after handling.
P280
Wear protective gloves and eye/face protection.
P273
Avoid release to the environment.
Precautionary statements Response
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 P391
If eye irritation persists: Get medical advice/attention. Collect spillage.
Precautionary statements Disposal P501
Dispose of contents/container to an appropriate recycling or disposal facility.
* 2.3. Other hazards
Adverse physicochemical effects: No further relevant information available. Adverse human health effects and symptoms: This product does not contain a substance that has endocrine disrupting properties with respect to nontarget organisms as no component meets the criteria. Adverse environmental effects: This product does not contain a substance that has endocrine disrupting properties with respect to nontarget organisms as no component meets the criteria. The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. Other adverse effects: No further relevant information available.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 3/12
Winterspice SECTION 3: Composition/information on ingredients 3.2. Mixtures
Hazardous ingredients / Hazardous impurities / Stabilisers: Product identifiers
Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] (R)-p-mentha-1,8-diene Aquatic Acute 1 (H400), Aquatic Chronic 3 (H412), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
9 – ≤ 20 weight-%
Abies sibirica oil Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410), Asp. Tox. 1 (H304), Eye Irrit. 2 (H319), Flam. Liq. 3 (H226), Skin Sens. 1 (H317)
7 – ≤ 15 weight-%
Hexyl Cinnamal Skin Sens. 1 (H317)
4 – ≤ 10 weight-%
CAS No.: 68917-29-3 EC No.: 614-795-2
Clove terpenes Acute Tox. 4 (H302, H312), Asp. Tox. 1 (H304), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
4 – ≤ 10 weight-%
CAS No.: 88-41-5 EC No.: 201-828-7
2-tert-butylcyclohexyl acetate Aquatic Chronic 2 (H411)
1–≤5 weight-%
CAS No.: 14765-30-1 EC No.: 238-830-2
2-sec-butylcyclohexan-1-one Skin Irrit. 2 (H315)
1–≤5 weight-%
CAS No.: 8000-34-8
Patchouly Oil Asp. Tox. 1 (H304), Eye Irrit. 2 (H319), Skin Sens. 1 (H317)
1–≤2 weight-%
CAS No.: 80-56-8 EC No.: 201-291-9
pin-2(3)-ene Acute Tox. 4 (H302), Aquatic Chronic 1 (H410), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
1–≤2 weight-%
coumarin Acute Tox. 4 (H302), Aquatic Chronic 3 (H412), Skin Sens. 1 (H317)
1–≤2 weight-%
CAS No.: 68917-18-0 EC No.: 614-794-7
Cornmint oil Aquatic Chronic 2 (H411), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
≤2 weight-%
CAS No.: 8000-48-4
Eucalyptusöl Aquatic Chronic 2 (H411), Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
≤2 weight-%
CAS No.: 115-95-7 EC No.: 204-116-4
linalyl acetate Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
≤2 weight-%
CAS No.: 8007-20-3 EC No.: 616-907-5
Cedar leaf oil Acute Tox. 4 (H302), Aquatic Chronic 2 (H411), Asp. Tox. 1 (H304), Skin Sens. 1 (H317)
≤1 weight-%
CAS No.: 5989-27-5 EC No.: 227-813-5 Index No.: 601-096-00-2
CAS No.: 8021-29-2 EC No.: 617-005-4
CAS No.: 101-86-0 EC No.: 202-983-3
Danger M-factor (acute): 1
Danger M-factor (acute): 1 M-factor (chronic): 1
Warning
Danger
Warning
Danger
CAS No.: 91-64-5 EC No.: 202-086-7
Danger M-factor (acute): 1 M-factor (chronic): 1
Warning
Warning
Danger
Warning
Danger
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 4/12
Winterspice Product identifiers
Substance name Concentration Classification according to Regulation (EC) No. 1272/2008 [CLP] Lemon Oil Terpenes Asp. Tox. 1 (H304), Flam. Liq. 3 (H226), Skin Irrit. 2 (H315), Skin Sens. 1 (H317)
≤1 weight-%
CAS No.: 78-70-6 EC No.: 201-134-4
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
≤ 0.5 weight-%
CAS No.: 68039-49-6 EC No.: 268-264-1
2,4-dimethylcyclohex-3-ene-1-carbaldehyde Aquatic Chronic 2 (H411), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
≤ 0.5 weight-%
CAS No.: 112-54-9 EC No.: 203-983-6
dodecanal Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1B (H317)
≤ 0.5 weight-%
CAS No.: 4707-47-5 EC No.: 225-193-0
methyl 2,4-dihydroxy-3,6-dimethylbenzoate Skin Sens. 1B (H317)
≤ 0.5 weight-%
CAS No.: 6728-26-3 EC No.: 229-778-1
trans-hex-2-enal Acute Tox. 4 (H302), Aquatic Chronic 2 (H411), Eye Irrit. 2 (H319), Skin Irrit. 2 (H315), Skin Sens. 1A (H317)
≤ 0.1 weight-%
CAS No.: 68917-33-9 EC No.: 614-796-8
Danger
Warning
Warning
Warning
Warning
Warning Full text of H- and EUH-phrases: see section 16.
SECTION 4: First aid measures 4.1. Description of first aid measures
General information: In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Remove victim out of the danger area. Remove contaminated, saturated clothing. If unconscious but breathing normally, place in recovery position and seek medical advice. Do not leave affected person unattended. Warning First aider: Pay attention to self-protection! Following inhalation: Provide fresh air. In case of respiratory tract irritation, consult a physician. In case of skin contact: After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing. If skin irritation or rash occurs: Get medical advice/ attention. After eye contact: In case of contact with eyes, rinse immediately thoroughly with plenty of edible oil and consult an ophthalmologist. Following ingestion: Ingestion of the mixture / product is hardly possible. Rinse mouth. Get medical advice/attention if you feel unwell. Do NOT induce vomiting. Observe risk of aspiration if vomiting occurs. Get immediate medical advice/ attention. Self-protection of the first aider: Use personal protection equipment.
4.2. Most important symptoms and effects, both acute and delayed Causes skin irritation. Allergic reactions Serious eye damage/eye irritation
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 5/12
Winterspice 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.
SECTION 5: Firefighting measures 5.1. Extinguishing media
Suitable extinguishing media: alcohol resistant foam Extinguishing powder Carbon dioxide (CO2) Unsuitable extinguishing media: Full water jet
5.2. Special hazards arising from the substance or mixture Combustible Hazardous combustion products: Gases/vapours, irritant
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
5.4. Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel
Personal precautions: Remove persons to safety. Protective equipment: Wear protective gloves/protective clothing/eye protection/face protection.
6.1.2. For emergency responders
Personal protection equipment: Personal protection equipment: see section 8
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up For cleaning up: Take up mechanically, placing in appropriate containers for disposal.
6.4. Reference to other sections
Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13
6.5. Additional information
Use appropriate container to avoid environmental contamination.
SECTION 7: Handling and storage 7.1. Precautions for safe handling Protective measures
Advices on safe handling: Wear personal protection equipment (refer to section 8). Fire prevent measures: Take precautionary measures against static discharge. Keep away from sources of ignition - No smoking.
Advices on general occupational hygiene When using do not eat, drink or smoke. Avoid contact with eyes and skin.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 6/12
Winterspice 7.2. Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions: Keep container tightly closed in a cool, well-ventilated place. Storage class (TRGS 510, Germany): 11 – Combustible solids that cannot be assigned to any of the above storage classes
7.3. Specific end use(s) No data available
SECTION 8: Exposure controls/personal protection 8.1. Control parameters No data available
8.2. Exposure controls 8.2.1. Appropriate engineering controls No data available
8.2.2. Personal protection equipment
Eye/face protection: Eye glasses with side protection EN 166 Skin protection: Tested protective gloves must be worn EN ISO 374 Suitable material: NBR (Nitrile rubber), In the case of wanting to use the gloves again, clean them before taking off and air them well. Breakthrough times and swelling properties of the material must be taken into consideration. Respiratory protection: Usually no personal respirative protection necessary. Respiratory protection necessary at: Handling larger quantities,
8.2.3. Environmental exposure controls No data available
SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state: Liquid Odour: fruity
Safety relevant basis data
Colour: yellow Odour threshold: not determined
Parameter
Value
pH
not applicable
Melting point
① Method ② Remark
not determined
Freezing point
not determined
Decomposition temperature
not determined
Evaporation rate
not determined
Initial boiling point and boiling range not determined Flash point
Auto-ignition temperature
Upper/lower flammability or explosive limits Vapour pressure
61.1 °C not determined not determined not determined
Vapour density
not determined
Relative density
not determined
Density
Bulk density
Water solubility according to Regulation (EC) No. 2020/878 (REACH)
≈ 0.93 g/cm³ not determined Immiscible en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 7/12
Winterspice Parameter
Value
Partition coefficient: n-octanol/water not determined Dynamic viscosity
① Method ② Remark
not determined
Kinematic viscosity
not determined
9.2. Other information
Solid, inert fiber block soaked with liquid mixture for odour neutralisation. The properties listed relate to the liquid.
SECTION 10: Stability and reactivity 10.1. Reactivity
Flammable liquid and vapour. This material is considered to be non-reactive under normal use conditions.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions No known hazardous reactions.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions.
10.5. Incompatible materials
No further relevant information available.
10.6. Hazardous decomposition products
Thermal decomposition can lead to the escape of irritating gases and vapours.
SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No. 1272/2008 pin-2(3)-ene
CAS No.: 80-56-8 EC No.: 201-291-9
LD50 oral: 500 mg/kg
LD50 dermal: >2,000 mg/kg
coumarin
CAS No.: 91-64-5 EC No.: 202-086-7
LD50 oral: 520 mg/kg
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
LD50 oral: >9,000 mg/kg
Acute oral toxicity: Based on available data, the classification criteria are not met. Acute dermal toxicity: Based on available data, the classification criteria are not met. Acute inhalation toxicity: Based on available data, the classification criteria are not met. Skin corrosion/irritation: Causes skin irritation. Serious eye damage/irritation: Causes serious eye irritation. Respiratory or skin sensitisation: May cause an allergic skin reaction. Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity: Based on available data, the classification criteria are not met. according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 8/12
Winterspice STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Based on available data, the classification criteria are not met. Aspiration hazard: May be fatal if swallowed and enters airways. Additional information: No data available
11.2. Information on other hazards
Endocrine disrupting properties: This product does not contain a substance that has endocrine disrupting properties with respect to humans as no component meets the criteria.
SECTION 12: Ecological information 12.1. Toxicity (R)-p-mentha-1,8-diene LC50: <1 mg/L 4 d
pin-2(3)-ene
CAS No.: 5989-27-5 EC No.: 227-813-5
CAS No.: 80-56-8 EC No.: 201-291-9
LC50: 0.303 mg/L 4 d (fish)
EC50: 0.475 mg/L 2 d (crustaceans)
LOEC: 0.494 mg/L 2 d (Algae/water plant)
Eucalyptusöl
CAS No.: 8000-48-4
LC50: ≈0.9 mg/L
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
LC50: 11 mg/L 4 d (fish)
Aquatic toxicity: Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Assessment/classification: No further relevant information available. Additional ecotoxicological information: No further relevant information available.
12.2. Persistence and degradability (R)-p-mentha-1,8-diene
CAS No.: 5989-27-5 EC No.: 227-813-5
Biodegradation: Yes, rapidly
Abies sibirica oil
CAS No.: 8021-29-2 EC No.: 617-005-4
Hexyl Cinnamal
CAS No.: 101-86-0 EC No.: 202-983-3
Clove terpenes
CAS No.: 68917-29-3 EC No.: 614-795-2
Biodegradation: —
Biodegradation: Yes, rapidly Biodegradation: —
2-sec-butylcyclohexan-1-one
Biodegradation: Yes, rapidly
CAS No.: 14765-30-1 EC No.: 238-830-2
Patchouly Oil
CAS No.: 8000-34-8
pin-2(3)-ene
CAS No.: 80-56-8 EC No.: 201-291-9
Biodegradation: Yes, rapidly Biodegradation: Yes, rapidly
coumarin
CAS No.: 91-64-5 EC No.: 202-086-7
Biodegradation: Yes, rapidly
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
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Winterspice Cornmint oil
CAS No.: 68917-18-0 EC No.: 614-794-7
Eucalyptusöl
CAS No.: 8000-48-4
Biodegradation: —
Biodegradation: Yes, rapidly
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
Cedar leaf oil
CAS No.: 8007-20-3 EC No.: 616-907-5
Biodegradation: Yes, rapidly Biodegradation: —
Lemon Oil Terpenes
CAS No.: 68917-33-9 EC No.: 614-796-8
Biodegradation: Yes, rapidly
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool Biodegradation: Yes, rapidly
2,4-dimethylcyclohex-3-ene-1-carbaldehyde Biodegradation: Yes, rapidly
dodecanal
CAS No.: 78-70-6 EC No.: 201-134-4
CAS No.: 68039-49-6 EC No.: 268-264-1
CAS No.: 112-54-9 EC No.: 203-983-6
Biodegradation: Yes, rapidly
methyl 2,4-dihydroxy-3,6-dimethylbenzoate Biodegradation: Yes, rapidly
trans-hex-2-enal
CAS No.: 4707-47-5 EC No.: 225-193-0
CAS No.: 6728-26-3 EC No.: 229-778-1
Biodegradation: Yes, rapidly
Biodegradation: Part of the components is biodegradable. Additional information: No further relevant information available.
12.3. Bioaccumulative potential
Accumulation / Evaluation: No further relevant information available.
12.4. Mobility in soil
No further relevant information available.
12.5. Results of PBT and vPvB assessment (R)-p-mentha-1,8-diene
CAS No.: 5989-27-5 EC No.: 227-813-5
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Abies sibirica oil
CAS No.: 8021-29-2 EC No.: 617-005-4
Hexyl Cinnamal
CAS No.: 101-86-0 EC No.: 202-983-3
Clove terpenes
CAS No.: 68917-29-3 EC No.: 614-795-2
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
2-tert-butylcyclohexyl acetate
CAS No.: 88-41-5 EC No.: 201-828-7
2-sec-butylcyclohexan-1-one
CAS No.: 14765-30-1 EC No.: 238-830-2
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Patchouly Oil
CAS No.: 8000-34-8
pin-2(3)-ene
CAS No.: 80-56-8 EC No.: 201-291-9
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
coumarin
CAS No.: 91-64-5 EC No.: 202-086-7
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 10/12
Winterspice Cornmint oil
CAS No.: 68917-18-0 EC No.: 614-794-7
Eucalyptusöl
CAS No.: 8000-48-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
linalyl acetate
CAS No.: 115-95-7 EC No.: 204-116-4
Cedar leaf oil
CAS No.: 8007-20-3 EC No.: 616-907-5
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Lemon Oil Terpenes
CAS No.: 68917-33-9 EC No.: 614-796-8
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
Linalool: 3,7-Dimethyl- 1,6-octadien-3-ol; DL-Linalool
CAS No.: 78-70-6 EC No.: 201-134-4
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
2,4-dimethylcyclohex-3-ene-1-carbaldehyde
CAS No.: 68039-49-6 EC No.: 268-264-1
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
dodecanal
CAS No.: 112-54-9 EC No.: 203-983-6
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
methyl 2,4-dihydroxy-3,6-dimethylbenzoate
CAS No.: 4707-47-5 EC No.: 225-193-0
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
trans-hex-2-enal
CAS No.: 6728-26-3 EC No.: 229-778-1
Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII.
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Endocrine disrupting properties
This product does not contain a substance that has endocrine disrupting properties with respect to nontarget organisms as no component meets the criteria.
12.7. Other adverse effects No data available
SECTION 13: Disposal considerations 13.1. Waste treatment methods
The allocation of waste identity numbers/waste descriptions must be carried out according to the EWC, specific to the industry and process.
13.1.1. Product/Packaging disposal Waste codes/waste designations according to EWC/AVV Waste code product
16 03 05 * organic wastes containing hazardous substances *: Evidence for disposal must be provided.
Waste treatment options
Appropriate disposal / Product: Consult the appropriate local waste disposal expert about waste disposal. Appropriate disposal / Package: Non-contaminated packages may be recycled. Completely emptied bricks, disks and membranes can be recycled.
13.2. Additional information
* = "S" In Switzerland, commercial hazardous waste shall be delivered to a disposal company.
SECTION 14: Transport information Land transport (ADR/RID)
Sea transport (IMDG)
Air transport (ICAO-TI / IATA-DGR)
UN 3077
UN 3077
UN 3077
14.1. UN number or ID number
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 11/12
Winterspice Land transport (ADR/RID)
Sea transport (IMDG)
Air transport (ICAO-TI / IATA-DGR)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((R)-pmentha-1,8-diene, Abies sibirica oil)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((R)-pmentha-1,8-diene, Abies sibirica oil)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ((R)-pmentha-1,8-diene, Abies sibirica oil)
14.2. UN proper shipping name
14.3. Transport hazard class(es)
9
14.4. Packing group III
14.5. Environmental hazards
9 III
14.6. Special precautions for user Special Provisions: 274 | 335 | 375 | 601 Limited quantity (LQ): 5 kg Excepted Quantities (EQ): E1 Hazard identification number (Kemler No.): 90 Classification code: M7 Tunnel restriction code: (-)
9 III
MARINE POLLUTANT
Special Provisions: 274 | 335 | 966 | 967 | 969 Limited quantity (LQ): 5 kg Excepted Quantities (EQ): E1 EmS-No.: F-A, S-F
Special Provisions: A97 | A158 | A179 | A197 | A215 Limited quantity (LQ): Y956 Excepted Quantities (EQ): E1
14.7. Maritime transport in bulk according to IMO instruments Additional information: Solid, inert fiber block soaked with liquid mixture for odour neutralisation.
SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU legislation
Restrictions on use: According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous substances are prevented. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
15.1.2. National regulations No data available
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information 16.1. Indication of changes 2.3.
Other hazards
16.2. Abbreviations and acronyms
For abbreviations and acronyms, see table on the eSDScom website -ADR: European agreement concerning the international carriage of dangerous goods by road (Accord européen relatif transport des merchandises dangereuses par route)
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006 (REACH) Revision date: 2 Mar 2023 Print date: 16 Mar 2023 Version: 2 Page 12/12
Winterspice -CAS: Chemical Abstracts Service -CLP: Classification, labelling and Packaging -DNEL: Derived No Effect Level -EC50: Effective Concentration 50% -ECHA: European Chemical Agency -LC50: Lethal Concentration 50% -LD50: Lethal Dose 50% -PBT: persistent, bioaccumulative, toxic -PNEC: Predicted No Effect Concentration -REACH: Registration, Evaluation and Authorization of Chemicals -SVHC: Substance of Very High Concern -VOC: Volatile organic compounds -vPvB: very persistent, very bioaccumulative
16.3. Key literature references and sources for data
REACH Dissemination Portal https://echa.europa.eu/de/information-on-chemicals/registered-substances
16.4. Classification for mixtures and used evaluation method according to regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories
Hazard statements
Classification procedure Calculation method.
Skin corrosion/irritation (Skin Irrit. 2)
H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
Calculation method. Calculation method.
H319: Causes serious eye irritation.
Calculation method.
Aspiration hazard (Asp. Tox. 1)
Respiratory or skin sensitisation (Skin Sens. 1)
Serious eye damage/eye irritation (Eye Irrit. 2)
Hazardous to the aquatic environment H400: Very toxic to aquatic life. (Aquatic Acute 1)
Calculation method.
Hazardous to the aquatic environment H410: Very toxic to aquatic life with (Aquatic Chronic 1) long lasting effects.
Calculation method.
16.5. Relevant R-, H- and EUH-phrases (Number and full text) Hazard statements H226
Flammable liquid and vapour.
H304
May be fatal if swallowed and enters airways.
H302 H312 H315 H317 H319 H400 H410 H411 H412
Harmful if swallowed.
Harmful in contact with skin. Causes skin irritation.
May cause an allergic skin reaction. Causes serious eye irritation. Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects.
Harmful to aquatic life with long lasting effects.
16.6. Training advice No data available
16.7. Additional information No data available
* Data changed compared with the previous version.
according to Regulation (EC) No. 2020/878 (REACH)
en / GB GeSi.de