SAFETY DATA SHEET
SECTION 1.
IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name:
FREKOTE FREWAX
Proper Shipping Name:
RESIN SOLUTION
Supplier:
HENKEL NEW ZEALAND LIMITED 2 ALLENS ROAD, EAST TAMAKI, AUCKLAND. PHONE (09) 272 6710 FAX (09) 272 6711.
Emergency Contact Details:
0800 CHEMCALL (0800 243 622) For any Hazardous Substance Emergency (24 hours, 365 days)
SECTION 2.
HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE: Hazardous according to the criteria of HSNO. HSNO CLASSIFICATION: 3.1C 6.1E (aspiration hazard) 6.3A 6.4A 6.7A
Warning, flammable liquid and vapour. Danger, may be harmful or fatal if swallowed and enters airways. Warning, causes skin irritation. Warning, causes serious eye irritation. Danger, may cause cancer.
PRECAUTIONARY STATEMENTS: PREVENTION: P102 P103 P104 P201 P202 P210 P233 P240 P241 P242 P243 P264 P280 P281 RESPONSE: P101 P301+P310 P302+P352 P303+P361+P353 P305+P351+P338 P308+P313 DATE OF SDS: Page 1 of 6
Keep out of reach of children. Read label before use. Read Safety Data Sheet before use. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/any other type of equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash hands, arms and face thoroughly after handling. Wear suitable protective equipment. Refer to Section 8. Use personal protective equipment as required. If medical advice is needed, have product container or label at hand. IF SWALLOWED: Immediately call POISON CENTRE or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. 18.07.08
REVISION OF:
22.11.05
IDH NO: 548972
SAFETY DATA SHEET P321 P331 P332+P313 P337+P313 P362 P370+P378
Refer Section 4 of this Safety Data Sheet for more information. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use appropriate media for extinction. See Section 5.
DANGEROUS GOODS INFORMATION: Classified as Dangerous Goods according to the criteria of the New Zealand Code for the Transport of Dangerous Goods on Land (NZS5433:Part 2:2007). DG Class:
3
SECTION 3.
(Flammable liquid)
COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS: CHEMICAL ENTITY
CAS NO.
Naphtha (petroleum) hydrotreated heavy [64742-48-9] Resin blend proprietary
SECTION 4.
PROPORTION > 80% w/w < 10% w/w
FIRST AID MEASURES
Ingestion:
If swallowed, do not induce vomiting. For advice, contact a Poisons Information Centre or a doctor.
Skin:
Remove contaminated clothing and wash affected areas with plenty of soap and water. If irritation occurs, seek medical attention.
Eyes:
Hold eyes open and flush with water. If irritation persists, seek medical attention.
Inhalation:
If inhaled, remove from contaminated area. For all but the most minor symptoms, arrange for patient to be seen by a doctor.
Advice to doctor: Treat symptomatically. Treat symptomatically. Due to a risk of aspiration into the lungs, gastric lavage should only be undertaken after endotracheal intubation. First Aid facilities:
SECTION 5.
Eye wash and safety shower.
FIRE FIGHTING MEASURES
Suitable extinguishing media:
Carbon dioxide, foam, dry chemical.
Hazardous decomposition products: noxious fumes.
Under fire conditions, it will produce oxides of carbon and
Precautions for fire fighters and special protective equipment: Flammable liquid. Vapours are heavier than air and may accumulate in low areas or poorly ventilated areas to be ignited at locations distant from the handling site. Evacuate unprotected personnel from hazardous area. Fire fighters should wear full protective clothing and self-contained breathing apparatus. DATE OF SDS: Page 2 of 6
18.07.08
REVISION OF:
22.11.05
IDH NO: 548972
SAFETY DATA SHEET
SECTION 6.
ACCIDENTAL RELEASE MEASURES
Spills: Isolate all potential sources of ignition. Wear protective gloves, chemical goggles and waterproof boots. Contain and collect spillage with inert absorbent materials (e.g. sand, earth, vermiculite). Transfer to sealable containers suitable for storing spilled material. Clean and flush areas in contact with spilled material with adequate water to render the area safe for human contact. Note: Residues are not water-soluble. Wash down waters may still contain residues that require treatment through local effluent treatment plant. Do not allow to drain or watercourse. Disposal: Dispose of solid residues in chemical waste disposal area in accordance with relevant Council and Government requirements. SECTION 7.
HANDLING AND STORAGE
Safe Handling: Observe recommendations made under SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION. Use with adequate ventilation. Keep away from sources of ignition, heat and flames. Wear impervious gloves and chemical splash goggles. Empty containers may contain product residue. Do not pressurize, cut, heat or weld containers. Use full flameproof equipment and procedures. Storage: Store indoors in a cool, dry, well-ventilated area. Keep containers sealed when not in use. Protect from physical damage. Keep away from incompatible materials. Store according to relevant Dangerous Goods Storage Requirements.
SECTION 8.
EXPOSURE CONTROLS / PERSONAL PROTECTION
National exposure standards:
None established.
Engineering controls:
A local mechanical exhaust system is required where vapour or mist is being generated.
Personal protective equipment: Use good industrial hygiene. Avoid contact with skin and eyes. Wear overalls, safety footwear, impervious gloves and chemical splash goggles. Use with adequate ventilation. If inhalation risk exists, wear an organic vapour respirator complying with the requirements of AS/NZS1715 and 1716. SECTION 9.
PHYSICAL AND CHEMICAL PROPERTIES
Physical data: Appearance: Specific gravity: Solubility: Flash Point (CC): Boiling Point: Vapour Density (air = 1): Odour: SECTION 10.
STABILITY AND REACTIVITY
Chemical stability: Conditions to avoid: DATE OF SDS: Page 3 of 6
White suspension in solvent 0.76 Not soluble in water 28째C 140째C > 1.0 Hydrocarbon
Stable under normal conditions of temperature and pressure. Heat, naked flames, sparks. 18.07.08
REVISION OF:
22.11.05
IDH NO: 548972
SAFETY DATA SHEET Incompatible materials: Keep away from strong acids and oxidising agents. Hazardous decomposition products: When heated to decomposition, it will emit oxides of carbon and noxious fumes. Hazardous reactions: Product will not polymerise. SECTION 11.
TOXICOLOGICAL INFORMATION
HEALTH EFFECTS: Acute: Ingestion:
If swallowed, may cause irritation to the mouth, throat and digestive tract. Aspiration of liquid into the lungs during ingestion or from vomiting may cause pneumonitis or pulmonary oedema.
Skin:
Contact with skin may result in irritation.
Eyes:
Liquid contact with the eyes can cause irritation.
Inhalation:
Inhalation of vapour or mist may cause respiratory irritation, nausea, headache and dizziness.
Chronic:
Repeated or prolonged skin contact may cause defatting of the skin and lead to dermatitis. This product contains benzene as an impurity. Benzene is classified as a Category 2 carcinogen.
Toxicity information: No data available SECTION 12.
ECOLOGICAL INFORMATION
Potential Environmental Interactions:
Avoid contaminating watercourse and soil.
HSNO Ecotoxicity:
None.
Toxicity:
No data available for this product.
SECTION 13.
DISPOSAL CONSIDERATIONS
Refer to Land Waste Management Authority. Normally suitable for disposal by incineration in approved incineration plant. Containers should be drained and then left open to allow residual solvent films to evaporate prior to disposal to recycler or approved landfill site. SECTION 14.
TRANSPORT INFORMATION
UN Number: Proper Shipping Name: Class: Packing Group: Hazchem code: Emergency Information: SECTION 15.
1866 RESIN SOLUTION 3, Flammable III 3[Y] Dangerous Goods-Initial Emergency Response Guide (SAA/SNZ HB 76) or EPG 3A1 REGULATORY INFORMATION
HSNO Approval Code:
DATE OF SDS: Page 4 of 6
HSR002669 - Surface Coatings and Colourants (Flammable, Toxic [6.7]) Group Standard 2006
18.07.08
REVISION OF:
22.11.05
IDH NO: 548972
SAFETY DATA SHEET HSNO Controls: Trigger quantities beyond which site and storage conditions apply Location and transit depot test certification Hazardous atmosphere zone
Fire extinguishers Response plans and secondary containment Signage
Trigger quantity 500 L (closed containers greater than 5 L) 1,500 L (closed containers up to & including 5 L) 250 L (open containers) 100 L (closed containers) 25 L (decanting) 5 L (open occasionally) 1 L (open containers in continuous use) 500 L 1,000 L 1,000 L
Any location at which a substance is manufactured or stored in quantities that exceed those set out in the table must comply with the relevant conditions for flammable liquids as set out in the document entitled Site and Storage Conditions for Class 3.1 Flammable Liquids published by ERMA, July 2006. Approved Handler Required: When present in quantities greater than 10 L, a HSNO 6.7A substance must beâ&#x20AC;&#x201D; (a) under the personal control of an approved handler who holds a current test certificate to manage HSNO class 6 substances; or (b) secured so that a person cannot gain access to the substance without tools, keys or any other device used for operating locks. Approved handler requirement is subject to the exceptions to the approved handler requirement set out in Surface Coatings and Colourants (Flammable, Toxic[6.7]) Group Standard 2006, available from http://www.ermanz.govt.nz/hs/groupstandards/standards/scc.html Workplace Exposure Standards:
SECTION 16.
None established.
OTHER INFORMATION
Abbreviations/acronyms: NOHSC - National Occupational Health and Safety Commission SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons NFPA - National Fire Protection Agency HSNO - Hazardous Substances and New Organisms AS - Australian Standard NZS - New Zealand Standard TWA - Time-weighted average TLV - Threshold limit value STEL - Short-Term Exposure Limit NOS - Not Otherwise Specified LD50 - Lethal Dose - 50%. The dose of a chemical that will kill 50% of the test animals receiving it. LC50 - Lethal Concentration - 50%. The concentration of a chemical in air or water that will kill 50% of the test organisms. LCLo â&#x20AC;&#x201C; Lowest Lethal Concentration. The lowest concentration of a chemical in air or water reported to have caused the death of animals or humans.
Reference(s): 1. Preparation of Safety Data Sheets: Approved Code of Practice Under the HSNO Act 1996, HSNO CoP 8-1 09-06, New Zealand Chemical Industry Council, September 2006. 2. Workplace Exposure Standards, Occupational Safety and Health Service, Department of Labour, Revised January 2001. DATE OF SDS: Page 5 of 6
18.07.08
REVISION OF:
22.11.05
IDH NO: 548972
SAFETY DATA SHEET
DISCLAIMER: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel New Zealand Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel New Zealand Limited concerning the properties of the material. The information contained in this Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel New Zealand Limited assumes no legal responsibility for reliance upon same. Henkel New Zealand Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material's characteristics and, where appropriate, to conduct their own tests in the specific context of the material's intended use.
DATE OF SDS: Page 6 of 6
18.07.08
REVISION OF:
22.11.05
IDH NO: 548972