Lumber Shield Material Safey Data Sheets

Page 1

Lumber Shield Classic Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date: 06/18/2013

Version: 1.0

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY 1.1.

Product Identifier

1.2.

Intended Use of the Product

1.3.

Name, Address, and Telephone of the Responsible Party

Product Name: Lumber Shield Classic Use of the substance/mixture: Wood Stain Company OZCO Building Products 216 N Interurban Street Richardson, Texas 75081 T 469-916-7503 www.ozcobuildingproducts.com

1.4.

Emergency Telephone Number

Emergency Number

: 214-334-7156

SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US)

Acute Tox. 4 (Inhalation:dust,mist) H332 Muta. 1B H340 Carc. 1A H350

2.2. Label Elements GHS-US Labeling

Hazard Pictograms (GHS-US)

:

Signal Word (GHS-US)

: Danger

Hazard Statements (GHS-US)

: H332 - Harmful if inhaled H340 - May cause genetic defects (Inhalation) H350 - May cause cancer (Inhalation) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P261 - Avoid breathing mist, spray, vapors. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves, eye protection. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTER or doctor if you feel unwell. P405 - Store locked up. P501 - Dispose of contents/container to local, regional, national and international regulations.

GHS07

Precautionary Statements (GHS-US)

2.3.

Other Hazards

2.4.

Unknown Acute Toxicity (GHS-US):

GHS08

No additional information available No data available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1.

Substances

Not applicable 06/18/2013

EN (English US)

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Lumber Shield Classic Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

3.2.

Mixtures

Name Paraffin oils, petroleum, catalytic dewaxed light

Product Identifier (CAS No) 64742-71-8

% 60 – 100

Solvent naphtha, petroleum, light aromatic

(CAS No) 64742-95-6

0.1 - 1

Stoddard solvent

(CAS No) 8052-41-3

0.1 - 1

Classification (GHS-US) Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Carc. 1B, H350 Muta. 1B, H340 Carc. 1A, H350 Asp. Tox. 1, H304 Flam. Liq. 3, H226 Muta. 1B, H340 Carc. 1B, H350 Asp. Tox. 1, H304

Full text of H-phrases: see section 16

SECTION 4: FIRST AID MEASURES 4.1.

Description of First Aid Measures

4.2.

Most important symptoms and effects, both acute and delayed

4.3.

Indication of Any Immediate Medical Attention and Special Treatment Needed

First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). If exposed or concerned: Get medical advice/attention. First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. If exposed or concerned: Get medical advice/attention. First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Symptoms/Injuries: May cause genetic defects. Symptoms/Injuries After Inhalation: Harmful if inhaled. May cause cancer by inhalation. Symptoms/Injuries After Skin Contact: May cause mild skin irritation. Symptoms/Injuries After Eye Contact: May cause eye irritation. Symptoms/Injuries After Ingestion: May be harmful if swallowed. If medical advice is needed, have product container or label at hand.

SECTION 5: FIREFIGHTING MEASURES 5.1.

Extinguishing Media

5.2.

Special Hazards Arising From the Substance or Mixture

5.3.

Advice for Firefighters

Suitable Extinguishing Media: Carbon dioxide, dry chemical, foam. Unsuitable Extinguishing Media: Do not use a heavy water stream. A heavy water stream may spread burning liquid. Fire Hazard: Not considered flammable but may burn at high temperatures. Explosion Hazard: Product is not explosive. Reactivity: No reactivity hazard other than the effects described in sub-sections below. Firefighting Instructions: Exercise caution when fighting any chemical fire. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal Precautions, Protective Equipment and Emergency Procedures 6.1.1. For Non-emergency Personnel

Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel.

6.1.2. For Emergency Responders

Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. 06/18/2013

EN (English US)

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Lumber Shield Classic Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.2.

Environmental Precautions

6.3.

Methods and Material for Containment and Cleaning Up

6.4.

Reference to Other Sections

Prevent entry to sewers and public waters. For Containment: Absorb and/or contain spill with inert material, then place in suitable container. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. See heading 8, Exposure Controls and Personal Protection.

SECTION 7: HANDLING AND STORAGE 7.1.

Precautions for Safe Handling

7.2.

Conditions for Safe Storage, Including Any Incompatibilities

7.3.

Specific End Use(s) Wood Stain

Precautions for Safe Handling: Use only outdoors or in a well-ventilated area. Avoid breathing mist, spray, vapours. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Store locked up. Incompatible Products: Strong acids. Strong bases. Strong oxidizers. Storage Area: Store locked up.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1.

Control Parameters

Stoddard solvent (8052-41-3) USA ACGIH ACGIH TWA (ppm) USA NIOSH NIOSH REL (TWA) (mg/m3)

100 ppm 350 mg/m続

USA NIOSH

NIOSH REL (ceiling) (mg/m3)

1800 mg/m続

USA IDLH

US IDLH (mg/m3)

20000 mg/m続

USA OSHA USA OSHA

OSHA PEL (TWA) (mg/m3) OSHA PEL (TWA) (ppm)

2900 mg/m続 500 ppm

8.2.

Exposure Controls

Appropriate Engineering Controls Personal Protective Equipment

: Ensure adequate ventilation, especially in confined areas. : Mask.

Hand Protection Respiratory Protection

: Wear chemically resistant protective gloves. : Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits. : When using, do not eat, drink or smoke.

Other Information

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1.

Information on Basic Physical and Chemical Properties

Physical State Appearance Odor Odor Threshold pH Relative Evaporation Rate (butylacetate=1) Melting Point Freezing Point Boiling Point Flash Point 06/18/2013

: : : : : : : : : :

EN (English US)

Liquid Dark brown, oily liquid. No data available No data available No data available No data available No data available No data available No data available No data available 3/6


Lumber Shield Classic Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Auto-ignition Temperature Decomposition Temperature Flammability (solid, gas) Vapor Pressure Relative Vapor Density at 20 째C Relative Density Specific Gravity Solubility Log Pow Log Kow Viscosity, Kinematic Viscosity, Dynamic Explosive Properties Oxidizing Properties Explosive Limits

9.2.

: : : : : : : : : : : : : : :

No data available No data available No data available No data available No data available No data available Not available No data available No data available No data available No data available No data available No data available No data available Not applicable

Other Information No additional information available

SECTION 10: STABILITY AND REACTIVITY

Reactivity: No reactivity hazard other than the effects described in sub-sections below. Chemical Stability: The product is stable at normal handling and storage conditions. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Hazardous Decomposition Products: Carbon oxides (CO, CO2)

SECTION 11: TOXICOLOGICAL INFORMATION 11.1.

Information On Toxicological Effects

Acute Toxicity

: Harmful if inhaled.

Paraffin oils, petroleum, catalytic dewaxed light (64742-71-8) LD50 Oral Rat 5000 mg/kg LD50 Dermal Rat 2000 mg/kg LC50 Inhalation Rat (mg/l) 2.18 mg/l/4h Solvent naphtha, petroleum, light aromatic (64742-95-6) LD50 Oral Rat 8400 mg/kg LD50 Dermal Rabbit > 2000 mg/kg LC50 Inhalation Rat (mg/l) > 5.2 mg/l (Exposure time: 4 h) LC50 Inhalation Rat (ppm) 3400 ppm (Exposure time: 4 h) Stoddard solvent (8052-41-3) LD50 Oral Rat LD50 Dermal Rabbit

> 5 g/kg Behavioral somnolence > 3 mg/kg

Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Not classified Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: May cause genetic defects (Inhalation). May cause genetic defects. Carcinogenicity: May cause cancer (Inhalation). Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Potential Adverse Human Health Effects and Symptoms: Harmful if inhaled. Symptoms/Injuries After Inhalation: Harmful if inhaled. May cause cancer by inhalation. 06/18/2013

EN (English US)

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Lumber Shield Classic Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Symptoms/Injuries After Skin Contact: May cause mild skin irritation. Symptoms/Injuries After Eye Contact: May cause eye irritation. Symptoms/Injuries After Ingestion: May be harmful if swallowed.

SECTION 12: ECOLOGICAL INFORMATION 12.1.

Toxicity

Solvent naphtha, petroleum, light aromatic (64742-95-6) LC50 Fish 1 9.22 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) EC50 Daphnia 1 6.14 mg/l (Exposure time: 48 h - Species: Daphnia magna)

12.2.

Persistence and Degradability

Lumber Shield Classic Persistence and Degradability

12.3.

Not established.

Bioaccumulative Potential

Lumber Shield Classic Bioaccumulative Potential

Not established.

Stoddard solvent (8052-41-3) Log Pow

3.16 (Octanol/water partition coefficient 3.16/7.06)

12.4.

Mobility in Soil No additional information available

12.5.

Other Adverse Effects

Other Information

: Avoid release to the environment.

SECTION 13: DISPOSAL CONSIDERATIONS 13.1.

Waste treatment methods

Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national and international regulations.

SECTION 14: TRANSPORT INFORMATION In Accordance With ICAO/IATA/DOT/TDG 14.1. UN Number Not applicable

14.2. UN Proper Shipping Name Not regulated for transport. 14.3. Additional Information

Other information

: No supplementary information available.

Transport by Sea Not regulated for transport. Air Transport

SECTION 15: REGULATORY INFORMATION US Federal Regulations Paraffin oils, petroleum, catalytic dewaxed light (64742-71-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Solvent naphtha, petroleum, light aromatic (64742-95-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Stoddard solvent (8052-41-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory

US State Regulations Paraffin oils, petroleum, catalytic dewaxed light (64742-71-8) U.S. - Massachusetts - Right To Know List Stoddard solvent (8052-41-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List 06/18/2013

EN (English US)

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Lumber Shield Classic Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 16: OTHER INFORMATION Other Information

:

This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200.

GHS Full Text Phrases: ------ Acute Tox. 4 (Dermal) ------ Acute Tox. 4 (Inhalation:dust,mist) ------ Asp. Tox. 1 ------ Carc. 1A ------ Carc. 1B ------ Flam. Liq. 3 ------ Muta. 1B ------ H226 ------ H304 ------ H312 ------ H332 ------ H340 ------ H350

Acute toxicity (dermal) Category 4 Acute toxicity (inhalation:dust,mist) Category 4 Aspiration hazard Category 1 Carcinogenicity Category 1A Carcinogenicity Category 1B Flammable liquids Category 3 Germ cell mutagenicity Category 1B Flammable liquid and vapor May be fatal if swallowed and enters airways Harmful in contact with skin Harmful if inhaled May cause genetic defects May cause cancer

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product SDS US (GHS HazCom) - US Only

06/18/2013

EN (English US)

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