Doc 117 b p s xi chemistry iit jee advanced study package 2014 15

Page 260

which is / are correct statements about the product:

Q.10

Q.11

(A)

CH3

is an endocyclic Saytzeff product

(B)

CH2

is an exocyclic Saytzeff product

(C)

CH2

is an exocyclic Hoffmann product

(D)

CH3

is an endocyclic Hoffmann product

CH2 = CHCH2CH = CH2 NBS  → A, A can be (A) CH 2 = CH CH CH = CH 2 | Br

(B) CH2=CHCH=CH–CH2Br

(C) CH2 = CH CH2 CH = CHBr

(D) CH 2 = CH CH 2 C = CH 2 | Br

Which are correct statements? (A) meso-2, 3-dibromo-butane on reaction with NaI / acetone gives trans-2-butene (B) d-or l- 2, 3-dibromobutane on reaction with NaI/acetone gives cis-2-butene (C) meso-2, 3-dibromo-butane on reaction with NaI / acetone gives cis-2-butene (D) d-or l- 2, 3-dibromobutane on reaction with NaI/acetone gives trans-2-butene

Q.12 Ph–CH=CH2 + BrCCl3 peroxide  → Product is: (A)

(B)

(C)

(D)

16

Page 16 of 40 HYDROCARBONS

− BuOK t → Product

Q.9


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