IMTS Civil Eng. (Applied thermodynamics)

Page 91

APPLIED THERMODYNAMICS

87

The curves AB, BC, and A'B' are the vapor pressure curves of solid solvent (ice) liquid water and o

solution containing non volatile solute respectively. T K is the freezing point of pure solvent T 1K is the freezing point of the solution. The freezing point depression depends upon the molal concentration of the solute and does not depend upon the nature of solute. Therefore it is a colligative property.

denominator as compared to W A/MA. Therefore,

If W A is the mass of solvent in kg then nB/WA is the molality of the solution.

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