Page 1

6"4& "CARU

Memorándum SEr N9 2649

..-.----.. ......

Para:

Comité Científico

De:

Secretaría Técnica (lng. Alejandro Arcelus)

CC: Fecha:

29/01/2013

Asunto:

Resultados Lab. Pacific Rim - Muestras tomadas e11&11?112 en UPM

----

------

----------

Señores integrantes del Comité Científico: Tengo el agrado de dirigirme a ese Órgano Subsidiario de C.A.R.U., a efectos de hacerles llegar los resultados recibidos del Laboratorio Pacific Rim, correspondientes

a las

muestras tomadas el día 18 de diciembre de 2012, en el marco del Plan de Monitoreo de la Planta Orión (UPM-Ex Botnia). Como referencia, se adjuntan copias de las órdenes de compra remitidas por esta Secretaría Técnica.

ING.A Secreté.'flO TecOICO

ComlSlÓfl Admll,¡str3liora del Río Uruguay

1/1


..\a.:t>\C-

Exova

T: +1 (604) 514-3322 F: +1 514-3323

#104. 1r575-55 A Ave. Surroy. British Columbia V3S 8P8. Canada

Exova

E: Surrayi(lex""a.com

W:

WYl/W.8Xov9.com

Report Transmission Cover Page BIft To:

Pacific Rim laboratories lne.

Project:

Repart To:

Pacífic Rim laboratories Inc.

ID:

#103, 19575 • 55A Avenue

Name:

Surrey, BC. Canada

Localion:

Attn:

V3S8P8

LSD:

Dave Hope

P.O.:

UPM

LoIID:

912807

Control Number: Date Received:

Dee 28, 2012

Dala Reported:

Jan 11,2013

Reporl Numbar:

1795194

Acctcode:

Sampled By: Company:

Contact & AffiUation

Address

Delivery Commilments

DaveHope

#103, 19575· 55A Avenue

On [Lot Veríficationj send

Pacifie Rim Laboralories Ine.

Surrey, Brilish Columbia V3S 8P8 Phone: (604) 532-8711 Fax: (604) 532-8712 Ernail: dave@pacíficrimlabs.com

(COA) by Email- Single Report On (Raport Approvalj send (COC, Tast Report) by Email- Merga Reports On (Lol Approval and Final Test Report Approval] send (COC, Tesl Reporl, Invoiee) by Hand Deliver

M

Notes To Cllenta: • Mise 1 = Dapnia Magna • Daphnia Magna analysis was performed by a subcontraellaboratory. See attaehed 1 page report 12·519522.

The informalion contained on !his and all olher pagas transmitted, is intended fer Ihe addressea only and is considered confidenlial. If!he reader is notlhe ¡ntended recipient, you are hereby notified Ihat any use, disseminalion. distribution or copy of Ihis transmission is strielly prohibited If you receive Ihis transmission by error, or if Ihis transmission is nol satisfactory, pisase notlfy us by tslephone. Terms and Conditions: www.exova.ca/terms&conditions


Exova #104, 19575路55 A..... <e. SU"..;, British Columbia V3S 8P8, Canada

T: +1 (604) 514-3322 F: +1 (Be1) 514-3323 E: Surrey@exova.com W; v.ww.8xova.com

Exova

Sample Custody BiI! To:

Pacific Rim Laboratories Inc.

Report To:

PaciRc Rim Laborator铆es Inc. #103, 19575 - 55A Avenue Surrey, BC, Cenada V3S8P8

AUn: Sampled By:

Oave Hope

ProJect: ID:

Lot ID: Control Number:

UPM

912807

Neme:

Date Received:

Oec 28,2012

Locallon:

Date Reported: Report Number:

Jan 11,2013 1795194

LSO:

P.O.: Acctcode:

Company:

Sample Disposal Date: February 10, 2013 AII samples will be stored until this date unless other instructions are received. Please indicate other requiraments below and retum this form to the address or fax number on the top of this page.

D

Extend Sample Storage Until

--------

The following charges apply to extended sample storage: Storage for an additional 30 days Storage for an additional 60 days Storage for an additional 90 days

D

$ 2.50 per sample $ 5.00 per sample $ 7.50 per sample

Retum Sample, collect. to the address below via:

D Greyhound DOHL

D D

Purolator Other (specify) Name Company Address Phone Fax Signatura

Terms and Conditions: www.exova.ca/terms&condiUons

(M MIOOIYY)


Exova #104,19575-55AAve. Surrey, Brilish Columbia V3S apa, Canada

Paga 1 of 10

T: +1 (604) 514-3322 F: +1 (604) 514·3323 E: Surray@exova.com W: www.eXOV8.com

Exova

Analytical Report BiII To:

Padfie Rim Laboratories Ine.

Projeet:

Report To:

Padfie Rim Laboratorles Ine.

ID:

#103, 19575· 55A Avenue

Name:

Surrey, BC, Canada

Location:

Attn:

V3S 8P8

LSO:

Dave Hope

P,O.:

SampledBy:

Lot ID:

UPM

912807

Control Number: Date Received:

Oee28,2012

Date Reported:

Jan 11, 2013

Report Number:

1795194

Acetcode:

Company:

Reference Number

912807·1

SampleDate

Oee 19, 2012

SampleTlme

NA

Sample Locatlon Sample Descrlptlon Matrlx Analyte

Units

13266821 PR 122796 Wastewater Results

Results

Results

Nominal Oetectlon Umll

Physlcal ene! Aggregate Properties Solids Solids

Total Total Suspended

Terms and CondiUon:;,; • 'WW.exo"a.c:\lterms&conditions

mglL

4120

mglL

<2

5 2


Exova #10·1. 19575-55 A Ave.

T: +1 (604) 514-3322 F: +1 (604) 514-3323

Surrey. BriUsh Columbia V3S apa. Canada

E: Su,rey@exova.com W: 'J.¡ :1W.9xova.com

Paga 2 of 10

Exova

Analytical Report BiII To:

Paeifie Rim Laboratories Ine.

Project:

Report To:

Paeifie Rim Laboratories lne.

ID:

Attn: SampledBy:

#103. 19575 - 55A Avenue

Name:

Surrey, BC. Cenada V3S8P8

Localion:

Oave Hope

Lol ID: Control Number:

UPM

LSO: P.O.:

912807

Date Received:

Oee 28, 2012

Dete Reportad: Report Number:

Jan 11,2013 1795194

Aectcode:

Company:

Referenc:e Number SampleDate SampleTime

912807-1 Oee 19, 2012 NA

Dee 19, 2012 NA

912807-4

13266821 PR 122796 Wastewater

13266881 PR 122799 Waslewater

Results

Results

Sample Locatlon Sample Descriptlon Matrlx Analyte

Unlts

Routlne Water Nitrate· N Nitrite· N Nitrate and Nilrile - N Electrical Conductivity

Term.:. and Conditions:

www.exova.caJterms&condítions

Results

Nominal Datection limlt

mg/L

0.18

0.01

mg/L mglL

0.57 0.75

0.005 0.01

IJS/cmat25 C

4980

1


Exova #104. 19575-55 A Av•. Surroy. Brili6h Columbia V3S apa. Canada

Paga 3 of 10

T: +1 (604) 514-3322 F: +1 (604) 514·3323 E: Surrey@exova.com

W:

Exova

WWW.8XOYa.com

Analytical Report BiI! To: Report To:

Attn:

Paeilie Rim Laboratories Ine. Paeifie Rim Laboratories Ine.

Project: ID:

#103, 19575· 55A Avenua Surrey, BC, Canada

Name: Location:

V3S6P6

LSO:

Dave Hope

P.O.:

SampledBy: Company:

Lot ID: Control Number:

UPM

912807

Date Received: Date Reported:

oee 26, 2012 Jan 11, 2013

Report Number:

1795194

Aectcode:

Reference Number Sample Date SampleTlme

912607-4

912607·3 Oee 19, 2012 NA

Dee 19, 2012 NA

912607·8 oee 19. 2012 NA

1327310 I PR 122798 Wastewater

13266881 PR 122799 Wastewater

13266861PR 122805 Wastewater

Results

Results

Results

Sample loeation Sample Descrlptlon

Matrix Unlts

Analyte

Nominal Dele<:tlon lImil

Inorganlc Nonmetalllc Parameters mglL

0.07

0.05

Total oissolved

mglL

0.75

0.06

Total

mgfL

Ammonia· N Kjeldahl Nitrogen Chlorate Phosphorus

Terms and Conditions: . 'WW .exovs.t..afterms&conditions

<0.5

mglL 0.806

0.1 0.003


,;1104,19575-55 A Ave. Surrey. British Columbia V3S BPB, Canada

Page 4 of 10

T: +1 (604) 514-3322 F: (604) 514·3323 E: Surrey@••ove.com

+,

Exova

W: wv.rt.exova.com

Analytical Report BiII To:

Pacifie Rim Laboratories Inc.

Project:

Report To:

Paeific Rim Laboralories Ine.

ID:

#103, 19575 - 55A Avenue Surrey,BC,Canada

Name: Location:

Attn:

V3S8P8

LSD:

Dave Hope

P.O.:

Lot ID: Control Number:

UPM

912807

Date Received: Date Reported:

oee 28,2012 Jan11,2013

Report Number:

1795194

Acctcode:

SampledBy: Company:

Reference Number SampleDate SampleTlme Sample Locatlon Sample Deserlption Matrix Unlts

Analyte

912807-6

912807-4 Dee 19, 2012

912807-5 Dec 19, 2012

NA

NA

oee 19, 2012 NA

13266881 PR 122799 Wastewater

13266791 PR 122800 Wastewater

13266801 PR 122802 Waslewaler

Resulte

Resulta

Results

Nominal Deleetlon Uroll

Aggregate Organle Constltuents mg 021L mglL

Chemlcal Oxygen oemand Phenol Oi¡ and Grease pH adjustrnent

Total required prior to O&G extraction

Terms ar.d Conditions: WW!I.exova.calterms&conditions

mg/L

285

5 0.002

<0.002 2 No

1


r:

ExO·..B

Page 5 of 10

+1 (604) 514-3322

Exova

F: +1 (604) 514-3323

#104. A A':e. Surrey, Braish Columbia V3S 8P8, CJnada

E: Surrey@exova.com

W:

WWll.eXOVB.com

_1

Analytical Report Bil! To:

Paelfie Rim Laboratories lne.

Projeet:

Report To:

Pacllie Rim Laboraloríes Ine.

ID:

#103, 19575 - 55A Avenue Surrey, BC, Canada

Nama:

V3S8P8

LSO:

Attn:

Dava Hopa

UPM

Location:

Lot ID: Control Number:

912807

Date Recelved: Date Raported: Report Number:

Oee 28,2012 Jan 11,2013 1795194

P.O.: Acctcoda:

Samplad By: Company:

Reference Number

912807-7

SampleDate SampleTlme Sample Location Sample Description

Oee 19, 2012

Matrlx

NA 1327309/PR 122803 Wastewater Nominal Oetacllon

Unlts

Results

EPHw10·19

ug/L

133

100

EPHw19-32

ug/L

170

100

Analyte

Results

Results

Umil

Extractable Petroleum Hydroearbons • Water

TermJ and Conditions:

www.exova.calterms&conditions


Exova

Page 6 of 10

T: +1 (604) 514-3322 F: +1 (604) 514-3323 E: Surrej'@exo\t,J,com

#104, 19575-55 A Ava.

Surrey. Brttish Columbia V3S 8P8. Canada

Exova

W: W\o.w.exova.com

Analytical Report Bill To:

Paeiflc RĂ­m laboratories Ine.

Project:

Report To:

Pacifie Rlm laboratories lne.

ID:

#103, 19575 - 55A Avenue

Name:

Surrey, BC, Canada

localion:

V3S8P8

lSO:

Oave Hope

P.O.:

Attn: Sampled By:

lot ID:

UPM

912807

Control Number: Date Received:

Oee 28,2012

Date Reportad:

Jan 11, 2013

Report Number:

1795194

Acclcode:

Company:

Reference Humber

912807-9

SampleDate

Oee 19. 2012

SampleTlme

NA

Sample Loeatlon Sample Deserlptlon Matrlx Analyte

Unlts

1327306/PR 122806 Wastewater Resulta

Results

Results

Nominal Deledlon limit

Inorganle Honmetallle Parameters Sulfide

Total

mgll

0.085

Hydrogen Sul.flde

Calculaled

mg/l

0.090

Terms and Condilians:

www.exova.calterms&conditions

0.005


Exova

Page 7 of 10

T: +1 (604} 514-3322 F: +1 (601) 514-3323

#104. 19575-55 A Ave.

Suney. B,:lish Columbia

E: Surray@exova.com

V3S 3PB. Canada

W:

Exova

"NWW.eXOV8.com

Analytical Report B铆II To:

Pacilic Rim laboratories Inc.

Report To:

Paclfic Rim Laboratories Inc. #103, 19575路 55A Avenue Surrey, BC, Canada V3S8P8

Atto:

Project: ID: Name: Location:

Oec 28,2012 Jan 11,2013

LSO:

Report Number:

1795194

P.O.:

Oave Hope

Sampled By:

912807

Lot ID: Control Number: Date Received: Date Reported:

UPM

Acctcode:

Company:

Reference Number Sample Date SampleTime

912807-11

912807-10 Dec 19, 2012

Dee 19, 2012

NA

NA

1326684/PR 122807 Wastewater

13266851 PR

Resulta

Results

Sample Locatlon Sample Descrlption Matrlx Units

Analyte

122808 Wastewater Results

Nominal Deleetion Limll

Metals Total 0.00001

0.00001

Mercury

Total

mglL

Aluminum Antimony

Total

mglL

0.062

Total

mg/L mg/L

0.0057 0.00300

0.00005

mgll mg/L

0.155

0.00005

0.00006 <0.0001

0.00005

mg/L mgll

0.047

0.0001 .002

0.00014

0.00001

Arsanic Barium Beryllium Bismuth Boron Cadmium Calcium Chromium Cobalt

Total Total Total Total Total Total

mg/L

Total Total

mglL mg/L

mg/L

160

0.005 0.0001

0.05

0.0121 0.0001 0.0013

0.0005 0.0001

0.088 0.0002 0.0065

0.002 0.0001

Total Total

mglL

Total

mg/L

Total Total

mglL

Total

rng/L

Manganese Molybdenum

Total Total

mglL

0.0666

mg/l

0.0134

Nickel

Total Total

mglL

Potassium

0.0002 0.1

Selenium

Total

Silicon Silvar Sodium

Total Total

mglL

0.0523 65.7 0.0003 11.2 <0.00005

Total

0.0005 0.1

Strontium Thallium Thor(um

Total Total

mglL mg/L mg/L mglL

Copper Iron Lead Lithium Magneslum

TIn Titanium Uranium Vanadium Zinc Zirconium

Terms and Conditions:

Total Total

mg/l

mg/l mg/l

mg/L

mg/L

Total Total

mglL

Total Total

mg/L mgll

Total

mg/L

W\"w.exo'.a.ca/lerms&condilions

mg/L

26.0

1090 0.562 0.00012 0.00002 0.0001 0.0012 0.00004 0.0516 0.0036 <0.0005

0.0001

0.0005 0.04 0.001 0.00005

0.0001 0.02

0.0001 0.00001 0.00001 0.0001 0.0005 0.00001 0.0001 0.0005 0.0005


E.o•.a #104, 19575-55 A AVe.

T: +1 (604) 514-3322 F: +1 (604) 514-J323

Surrey, 8ritish Columbia V3S 8pa, Canada

W: www.exovs.com

Page 8 of 10

Exova

E: Su,rey@e.ova.com

Analytical Report BiI! To:

Paeifie Rim Laboratories Ine.

Project:

Report To:

Pacifie Rim Laboratories Ine.

ID:

#103. 19575 - 55A Avenue

Name:

Surray, BC, Canada

Location:

Attn:

V3S8P8

LSO:

Oave Hope

P.O.:

Lot ID: UPM

912807

Control Number: Date Received:

Oee 28,2012

Date Reportad:

Jan 11. 2013

Report Number:

1795194

Aectcode:

Sampled By: Company:

Reference Number Sample Date SampleTIme Sample Locatlon Sample DescrlpUon Matrlx Unlta

Analyte

912807·12 Oee 19, 2012 NA 1326681/PR 122809 Wastewater

Results

Resulta

Resulta

Microtox Pass

Interpretalion (ERCB 0050) ECSO

15 minutes

% Sample

>100

EC50

5 minutes

%Sample

>100

EC20

15 minutes

%Sample

40

EC20

5 minutes

% Sample

56 None

Lab Treatment

330

Mierotox Model 500 unit #

Sump Liquid

SampleType

7.8

pH

Clarified Sample- Initial

Turbidity

As Received

None

Colour

As Received

Yellow

Colour

As Tested

Yellow

Turbidity

As Tested

pH

Clarlfied Sample- Final

None Not Adjusted

95% Confidence Factor

(EC50 - 5 Minutes)

9S% Confidence Factor

(EC20 • 5 Minutes)

2.00 1.40

95% Confidence Faetor

(EC50 ·15 Minutes)

2.68

95% Confidence Factor

(EC20 - 15 Minutes)

Colour Corrected Data

1.54 No

Approved by: Anlhony Neumann, MSc Laboratory Operations Manager Terms and Conditions:

Nominal Oelection

Umil


Page 9 of 10

T: +1 (604) 514-3322 F: +1 (604) 514-3323 E: Surrey@exovQ,com

EXOVA

#104, 1S575-55 A Avr. Brttish Columbia V3S 8P8, Canada

Exova

W: WWW.9XoV8.com

Methodology and Notes Bill To: Paeifie Rim Laboratories Ine. Report To: Pacifie Rim Laboratories Ine. #103, 19575 - 55A Avenue Surrey, BC, Canada V3S8P8 Attn: Oave Hope Sampled By: Company:

Project: ID: Name: Location: LSO: P.O,: Acctcode:

UPM

Lot ID: 912807 Control Number: Date Received: Oee 28, 2012 Date Reported: Jan 11,2013 Report Number: 1795194

Method of Analysls Method Name

Referenee

Alk, pH, EC, Turb in water (Surrey)

APHA

Ammonium·N in Water

Method

Date Analysis Sterted

Location

.. Conductivity, 2510 B

02-Jan-13

Exova Surrey

APHA

• Automated Phenate Method, 4500NH3G

04-Jan-13

Exova Edmonton

Anions (Rouline) by Ion Chromatography

APHA

• Ion Chromatography with Chemical Suppression of Eluent Cond" 4110 B

02-Jan-13

Exova Edmonton

BC ICP-MS Total Metals in Water

USEPA

• Oetermlnatlon of Trace Elements in Waters and Wastes by ICP-MS, 200.8

02-Jan-13

Exova Edmonton

BC Trace Total Metals in Water

APHA

• Inductively Coupled Plasma (ICP) Method, 3120 B

02-Jan-13

Exova Edmonton

Chemieal Oxygen Oemand in water

APHA

• Closed Reflux, Colorimetrie Method, 52200

03-Jan-13

Exova Edmonton

Chlorate and Chlorite by Ion Chromatography

APHA

• Ion Chromatogrephy with Chemlcal Suppression ofEluent Cond" 4110 B

02-Jan-13

Exova Edmonton

EPH -Water

BCELM

02-Jan-13 • Extraeteble Petroleum Hydrocarbons (EPH) in Water by GCIFIO, EPH Water

Exova Surrey

Mercury Low Level (Total) in water (Surrey)

EPA

• Mercury in Water by Cold Vapor Atomie Fluoresoenee Spectrometry, 245.7

03-Jan·13

Exova Surrey

Mierotox·15 Minute Multiple Concentration, ECSO

Envlronment Canada

• Biological Test Method: Toxieity Test Lumlnescent Bacteria, 11RM/24

02-Jan-13

Exova Edmonton

011 and Grease in water (Surray)

BCELM

• on & Grease in Water· Oireet Hexane Extraction, on & Grease

03-Jan·13

Exova Surrey

Phenol in water

APHA

.. Oireet Photometrie Method, 5530 O

04-Jan-13

Exova Edmonton

Phosphorus - total (Iow level) - Surrey

APHA

• Preliminary Acid Hydrolysis, Ascorbie Acid Reduction Method, 4500-P B,E

31-000-12

Exova Surrey

Sollds (Total, Fixed and Volalife)

APHA

.. Total Solids Oried at 103-10S'C, 2540 B

07·Jan-13

Exova Surrey

Solids Suspended (Total, Fixed and Volatile)

APHA

.. Total Suspended Solids Oried at 10310S'C, 2540 O

31-0e0-12

Exova Surrey

Sulfide in water

APHA

• Gas Oialysis, Automated Methylene Blue Method, 4500-52- E

31-000-12

Exova Edmonton

Total and Kjeldahl Nitrogen (Total) in Water

ISO

.. Water Quality - Oetermination of nitragen, ISOITR 11905-2

31-0e0-12

Exova Edmonton

• Re"'"",.. Mlllhod Modifled

References APHA B.C.M.O.E BCELM Environment Canada ISO

Terms and Conditions:

Standard Methods for lhe Examination of Water and Wastewater B.C. Ministry of Envlronment B,C. Environmental Laboratory Manual Toxicity Test Using Luminesoent Bacteria Intemational Organization for Standardization

WW.BXOV8.ca/terms&oond;lions


Exo\"s #104, 19575-55 A Ave, Surrej, Br;lish Columbia V3S apa, Canada

Page 10 of 10

T: +1 (604) 514-3322 F; +, (60.1) 514-3323 E; Surreyll;,exova.com

Exova

W: WW\').Bxova.com

Methodology and Notes BiI! To: Report To:

Attn: SampledBy:

ProJect:

Pacifie Rim Laboratories Ine. PaeíRe Rim Laboralories Ine.

ID:

#103, 19575· 55A Avenue Surrey, BC, Canada

Name: Localion:

V3S8P8

LSO: P,O.:

Oave Hope

UPM

Lot ID: Control Number:

912807

Date Received:

Oee 28, 2012

Date Reported: Report Number:

Jan 11,2013 1795194

Acctcode:

Company:

Comments: • Mise 1

=Dapnia Magna

• Oaphnia Magna analysis was performed by a subcontrael /aboratory. See attaehed 1 page report 12-519522.

Please direct any inquiries regarding this report to our CUent Services group. Results relate only to samples as submitted. The test report shall not be reproduced except in full, without the written approval of the laboratory. Terms and Conditions: 'O.I\IIJW.exova.calterms&conditions


Exova •

Appendix EXOVA (NORWEST)

Cllent:

1,

.

i,

i

'1,

Lab. No: Your ref.rence: Matrlx:

t

T

lllllilíiiIíi mJttp . . ( " , '

'

2275910 PR122797 Water NA NA

Samplecl by:

Slte sampled

Sampllng method: Date sampled (date and bour): Date recelved (datland hour): SIatt of sampled recelved:

Dat. ud hour ltIrt Inalysls (Ohrs):

2012-12-31·

EC5O-4llh (% vfv): Low.r CJ. at 95%: Upper C.L at 95%: Calculatlon method:

>100 NA

NA

Analysed by:

JC

i

',,';

NA 2012-12-3110:00:00 Received more lhan 48 hOlllS after sampfil1ll

2012·12.()2

12:00

Aucune méthode ublisée

"'''''nl. mlgna «24 heures)

<1% of mortality of brood stock 7 dllVS before test 20 7 10 30 300 16hrs IIght 18hrs darkness Dechlorln8led municipal water, hanlness adjusted 172 30 minutes

Averag. numbef of nlOnates per brood: Age al ftrst brood (days): Number of Oaphnlalcontaln.r: Loadlng denslty (mUDaphnla): Volume of test solutlons (mL): Photoperlod: DllutIon .atllr: Culture Ind dUutlon water hardneu (mall eICoo): Pra'leratlon of limPie: P....nratlon rete (mUmlnll :t1): SImple hll'dnetls (mglL CaCoo): Sample hanlneesldlustld (mgIL Cac03): Pre-treatmlnt of limpie: Protocoll Reference method:

I%vlvl

Date end hour end anllysls (48hre):

12:00

Organlsms:

sllllple concentratlon

12-519522

Request number:

number of

Oaphnla Oh...

Immoblllty Immoblllty 48hrs 48hra (number) (%)

O

10

O

O

6.25

10

12.5

10

O O O O O

25

10

50

10

O O O O

100

10

O

SlIllpl. charlcterlstlcs befont anaIysll ReferencIlIslY (Potelllum dlchromatll): Refll'llnCelllay date: LC-50-48h ImglL of Cr): Lower CJ. at 95%: Lower ej. al 95%:

5Cl 540 NA

NA SPE1IRIN14, 2000

mortelltY 48hra (numbel')

mortellty 48hra

O O

O O

O O O O

O O O O

ADDllranct Brll'Ml,cIoudy

2012-12·28 0.291 0.282 0.301

(%)

temperature

pH

¡C)

4811,.

Ohra

Dhlll

ahrs

dllSOlVed °llYll1n 1m 1IL1 Dhrs ahlll

conduetJvlly (JlSlcm) Ohrs

19.6

18.5

7.4

7.7

8.6

8.2

493

19.7

18.7

7.3

7.7

8.4

7.6

854

19.7

18.7

7.5

7.9

8.5

8.0

1311

19.7

18.7

7.6

8.2

8.8

7.9

1794

19.7

18.8

7.6

8.3

8.4

7.7

3170

19.7

18.8

7.6

8.5

8.8

7.7

5580

19.5

Geom.trIc av.rag.: Lower control "mil:

Upper controlllmlt:

7.8

9.5

5680

0.309 0.211 0.407

This ceftifieate musl no! be reproduced, exctpl in Its en1ilety, wi!llout wriIlen CIlI\Sflllt from ltle labor8lory. lile oflitiel \/8nion of lhic C8ftilicIIe is protecIed and _ 1 be mocfitled. lile abcJve.menIlonn Wll¡IIes wiI be rel8íned Ior a period of 30 dayt Iollowing ltle iswe ol1hls cartificale wiIh ltle excepllon of microblology I8mplec or 81 inslnlcled by tIt. cli.nt Rtsutta perlllin onIy lo tite samples I Ior analysls.

.,


WorkOrder Client Paeifie Rim Laboratorles lne. #103, 19575-55A Ave Surrey, B.e. V3S8P8

w.o.#

econotech

E1230S

PRELIMINARV REPORT - Final report is hard eopy

lag # 2066147 Date rec'd Results to email ce Phone Fax #;

Deeember 28, 2012 Dave Hope dave@paeifierlmlabs,eom palVeen@paelflerlmlabs.eom 604-532-8711 604-532-8712 description of samples One (1) effIuent sample

Sample preselVation confirmed by/date: JS/Dec 28/12

mtd/inltlals

Sample ID: PR122804 1326677

Anatvsis

020E/HB

__Lo_.?' 4

:-:'=OO,I';','==-- ·l··172:t.. . . _ .oo__ o__________o_____ .o.__o_ooo Blank Iimit splke reeovery, expected splke reeovery, start, actual Recovery, start spike reeovery, end, actual Recovery, end Recovery Iimlts splke eoncentration Batch dupllcate analysls RPD RPD Limits loe eriteria

eomments:

-

units .•'!'l9.f1:o__-

_o __

__ UQ/L ng

,_ __ __ ____ 01)9_0 _ ,2 0_____________ 00 10000 n9 9140 n9 i ¡ 91.4 % ng 9700 97.0 % 1 78-114 % ,• mo/L 0.1 2.37/2.45 mg/L % 3.49 20 % Passed

I

I

AOX: analyzed in aceordance with USEPA method 1650. Samples were preselVed with HN03 prior to analysls.


Page 1 ofS

SAMPLE RECEIPT FORM / CHEMICAL ANALYSIS FORM FILE #: PR122796

CLIENT:

Comision Administradora Rio Uruguay Costsnera Norte S/N Paysandu,60000 Uruguay Phone - (5982) 47225000 ext 106 Email-Arcelus@caru.org.uy

RECEIVED BY: CONDITION:

J. Del Pozo

DATE/TIME: December 27,2012 (8:50 a.m.)

good,4°C

#of Sample Containers TVDe Water 1 Water 1 1 Water 1 Water Water 1 1 Water Water 1 1 Water 1 Water 1 Water Water 1 1 Water 1 Water 1 Water

Sample (Client Codes) Lab Codes

Test Reguested

1326682 1326683 1327310 1227876 1227649 1227647 1227648 1227881 1227820 1227875 1227890 1227873 1227874 1227872

Total Susoended Solids, Total Solids

-

PR122796 PR122797 PR122798 PR122799 PR122800 PR122801 PR122802 PR122803 PR122804 PR122805 PR122806 PR122807 PR122808 PR122809

Danhnia Magna Total Phosnhorus Nitrate, Nitrite. Ammonia, COD TKN

Phenols PCDD/F Oíl & Grease Total Petroleum Hvdrocarbons AOX Chlorates Sulphide Metals (excent Mercurv) Mercurv Microtox ECSO

STORAGE:

Stored at 4°C

ANALYTES:

HRGC/RRMS analysis for polych1orinated dibenzo(p)dioxins and dibenzofurans (PCDDIF)

SPECIAL INSTRUCTIONS:

b!!su,,-,

PRI22796-2800, 2802-2809 subcontracted out to Exova and Econotech. See separate reports.

valio',c 1\1(.) ut>oratorf,"

0,;$

Pacilie Rim Laboratories ¡ne. #103, 1957S-SSA Avenue, Surte}', BC V3S 8P8 Canada Tel: + 604.532.8711 Fax: + 604.532.8712 Email: info@pacifierimlabs.com www.pacifierimlabs.com


Page 2 of5

METHODOLOGY Reference Method:

PCDDIF: SOP LAB01; EPA Method 1613b, Environment Canaela RM23

Data surnmarized in Data Report Attached Report sent 00: Comments:

Alejandro Arcelus

Date: January 21,2013

Results relate only to iteros tested.

David Hope, PChem, CEO

1'•

S:;',,

Pacifie Rim Laboratories Ine. #103, 19575·55A Avenue, Surrey, BC V3S 8P8 Canada Tel: + 604.532.8711 Fax: + 604.532.8712 Email: info@pacifíerimlabs.eom www.pacifierim1abs.com


Page 3 ofS

DATAREPORT Cllent: ClientlD: PRLID:

Contact: Date Extracted: Date Analysed:

Comlslon Administradora del Rio Uruguay

1326678 PR122801

DIOXINS Conc. Da/L NO NO

DL Da/L 1 1

1,2,3,7,8-PeCOO TotalPeCOO

NO NO

2 2

1,2,3,4,7.B-HxCOO 1,2,3,6,7.B-HxCOO 1,2,3,7,8.9-HxCOO Total HxCOO

NO NO NO NO

2 2 _. 2 2

I

Conaeners 2,3,7,B-TCOO Total TCOO

1,2,3,4,6,7,8-HpCOO Total HpCOO OCOO

(ND=O) Da/L NO

% 75

3

60 Total Dioxln TEQ

FURANS Conaeners 2,3,7,B-TCOF Total TCOF

NO NO NO

2 2 2

1,2,3,4,7,B-HxCOF 1,2,3,6,7,B-HxCOF 1,2,3,7,8,9-HxCOF 2,3,4,6,7,B-HxCOF Total HxCOF

NO NO NO NO NO

2 2 2 2

1,2,3,4,6,7,8·HpCOF 1,2,3,4,7,8,9-HpCOF Total HpCOF

NO

"3-''Ñb--- '-"-"3'_.'

OCOF

NO-'-

--

2 __

..

--_.---

"---4"--

Total PCDD/PCOF Toxic Equivalent

NO ..

- _º-.of..=

NO

0.004

NO

0.0004

0.00

2.63

0.00

3.63

WHO·TEQs

.

(ND=DL)

NO NO

0.1 1

80

1-. NO • __.

69 78

NO NO NO

0.2 0.2 0.2 0.2

"NO-

-----_.0.03

ND

0.03

67

NO

1

0.1

NO ND

I I

0.1

c--

1

0:2--_.._.-.-. '--------

_-

----ÑO-··-l--

f------.64 ---_.&._---

I

..._.-.. _-_...

-

Total Furan TEQ

I

- ---ºJ.._._

(ND=O) pg/L NO

.. --'-3·--- --_60

NO

P.-

0.2 0.2

0.03

Recoveries -......_.%"._--

55 ._-_.-.

1,2,3,7,8·PeCOF 2,3,4,7,8-PeCOF TotalPeCOF

NO NO NO

NO

I·TEQs

5urrogate DL Da/l:'- -' pg/L NO 1 1 NO

2

0.2

--_.-- _.

··-·····4-·-

NO

1------

-_-º:?._-

0.2 -_.0. __._ ..... --&_ .. _---

__

(ND=DL) Da/L 1

1 __

,--.NO NO '--'NÓ-

--____.·_0 _ .• - ___.

----

NO

83 76

WHO·TEQs (ND=O) Da/L NO

(ND=DL) Da/L 1

C-._ _

----.'/2----·

NO __

NO

I·TEQs

5urrogate Recoveries

Sª_

1---:-;-" _.-

Alejandro Arcelus 14-Jan-13 17-Jan·13

l I

"Dc¡¡-L0.1

e----.

'.',o_. -"-

..

.-.-

..

NO

I

0.004

NO

0.0004

0.00

I

2.06

0.00

2.06

0.00

I

4.70

I l

0.00

I

5.69

NO • none detectad

Patrlck Pond, Chief Technical Officer PormName: DOCl8DataRcportDxW 01·Feb-()7 DOH

...,-,

\,ad"" l\lm \ ú"8torle

Pacific Rim Laboratories lnc. # 103, 19S1S-SSA Avenue, Surrey, BC V3S 8P8 Canada Tel: + 604.532.8111 Fax: + 604.532.8712 Emai1: info@pacificrimlabs.com . www.pacificrimlabs.com


page 4 of5

QC REPORT • BLANK CUent: CUentlD: PRLID:

Contact: Date Extracted: Date Analysed:

ComlSlon Administradora del RIo Uruguay

Blank OF13003B

DIOX'NS Conc. pg/L

DL "giL

2,3,7,8-TCOO Total TCOO

NO NO

1,2,3,7,8-PecOO TotalPeCOO

Surrogate Recoveries

%

1 1

93

NO

NO NO

2 2

79

1,2,3,4,7.8-HxCOO 1,2,3,6,7.8-HxCOO 1,2,3,7,8.9-HxCDO Total HxCOO

NO NO NO NO

2 2

1,2,3,4,6,7.8-HpCOO

NO --

89

2

f-NiJ NO -.. ---.---

.. ---94 ----

3--- ._----.-.. .

FURANS ..Da/C- "-liOlC NO 1 NO

1 ._-

1,2,3,7,8-PeCOF 2,3,4,7,8-PeCOF TotalPecDF

NO NO NO

2 2 2

1,2.3,4,7,8-HxCOF 1,2.3,6,7,8-HxCOF 1,2.3,7,8,9-HxCOF 2,3,4,6,7.8-HxCOF Total HxCOF

NO NO NO NO NO

2 2 2 2 2 -

61

1,2,3,4,6,7,8-HoCOF 1,2,3,4,7,8,9-HoCOF Total HpCOF

NO NO NO

3

OCOF

NO

--

.---'Nó-

-0:0040<

0.00

2.63

Da/L NO

0.1

80 68

NO NO

0.1

--

0.03

NO

NO

0.0064

0.00

3.63

(ND=O) "a/L

pa/L

_t:4.P --

0.1

NO NO

0.1 1

.. NO

0.2 0.2 0.2 0.2

-NONO

0.03 0.03

----- ----0.2

NO

ND NO NO

lii5-- i---º:?0.2

·f--gT----

Total PCDD/PCDF Toxic Equivalent

0.2 0.2 0.2

f----.

1

_. NO

103 105 91

___

-

Total Furan TEQ

I

2

WHO-TEQs

90

NO

--'---4---'-

NO

I-TEQs

_ _ _ _o

3 __

1

- - _. - - f------· (ND=DL) Da/L

__

NO

--- ..Ñ'i)'- - r"O.03---·

SurrogBte Recoverles

DL

Congeners

__

,

1------+---_.._ -

NO

(ND=DLl "giL

NO NO NO f------

NO

94

--'-3-'-

(ND=O) pg/L

1---,

Totel Dioxin TEQ

2,3,7,8-TCOF Total TCDF

WHO-TEQs

(ND=DL) pg/L I 1

-

__1___ ._----_._-

_-

I

I

__._-'----- --;r-

.. __.

OCDD

NO - ' - . __ ... -..

14-Jan-13 17-Jan-13

'·TEQs (ND=O) "giL

Congeners

Alejandro Arcelus

I

0.2 -------

NO NO

0.03

NO

0.004

NO

0.0004

0.00

2.06

0.00

2.06

0.00

I

·4.70

f--

I I

0.00

I

5.69

NO - none detected

Patrick Pondo ChiefTechnical Officer Fonn Name: OOCI8 Data Report DllW OI-FeMl7 DOH

:,i'

.:_ film L,boroltor;Il,.

;;;2

Pacifie Rim Laboratories ¡neo #103, 19575-55A Avenue, Surrey, BC V3S 8P8 Canada Tel: + 604.532.8711 Fax: + 604.532.8712 Email: info@pacifierimlabs.eom www.paeificrimlabs.com


Page 50f5

Acronyms used in reporting dioxins and furans: TCDD = Tetrach1orodibenzo-p-dioxin TCOF = Tetrach1orodibenzofuran PeCDF = Pentach1orodibenzofuran PeCDD = Pentach1orodibenzo-p-dioxin HxCDF = Hexach1orodibenzofuran HxCDO = Hexachlorodibenzo-p-dioxin HpCDD = Heptach1orodibenzo-p-dioxin HpCDF = Heptachlorodibenzofuran OCOF = Octachlorodibenzofuran OCOD = Octacblorodibenzo-p-dioxin Acceptable recoveries for surrogates 13C12 -2,3,7,8-TCDD 13C12 -1,2,3,7,8-PeCDD 13C12 -1,2,3,4,7,8-HxCDD 13C12 -1,2,3,6,7,8-HxCDD 13C12 -1,2,3,4,6,7,8-HpCDD 13C12-OCOD 13C12 -2,3,7,8-TCDF 13C12 -1,2,3,7,8-PeCDF 13C12 -2,3,4,7,8-PeCDF 13C12 -1,2,3,4,7,8-HxCDF 13C12 -1,2,3,6,7,8-HxCDF 13C12 -1,2,3,7,8,9-HxCDF 13C12·2,3,4,6,7,8-HxCOF 13C12 -1,2,3,4,6,7,8-HpCDF 13C12 -1,2,3,4,7,8,9-HpCDF

..,¿:

EPA 1613 Min (%) Max (%) 25 164 25 181 32 141 28 130 23 140 17 157 24 24 21 26 26 29 28 28 26

169 185 178 152 123 147 136 143 138

Pacifie Rim Laboratories Ine. #103, 19575-55A Avenue, Surrey, Be V3S 8P8 Canada Tel: + 604.532.8711 Fax: + 604.532.8712 Email: info@pacifierimlabs.eom www.pacificrimlabs.com


COMISION ADMINISTRADORA DEL RIO URUGUAY LABORATORY ANALYSIS PURCHASE ORDER LABORATORY: PACIFIC RIM AOORESS: #103, 19575 55A Avenue Surrey, B. C. Canada V3S 8P8 TEl:

coe

LOT: 911807

FAX:

11111111111111

QUOTATION: e-mail from Dave Hope DATE OF SAMPlES : 19/12/2012 lOCATION: UPM BOX:3

\

""-""

......

\.üii"

SENO REPORT TO: Eng. Alejandro Arcelus arcelus@caru.org.uy

.,.-'::'.

Tel: (005982) 47225500 ext 106 Fax: (005982)47226786 Volume

Analysis . Total Suspended Solids Total50llds

(mI)

,.'

2xl000

Bottle (P: Plastfc, AG: AmbGlass)

Preservation

Sealing" (CARU 10#)

P

Refrigerate

1326682

V''::

Conductivity Daphnia magna

2.

Y

2xl000

P

Refrigerate

1326683

1000

AG

H2S04cc. 2ml/l (pH<2)

1327310

..

2:::t"QIe1

\1

2.:10'\1-

l'

2-'lGl <6

P\' 11 t>t:CA 2e-

am.


COMISION ADMINISTRADORA DEL RIO URUGUAY LABORATORV ANALVSIS PURCHASE ORDER

LABORATORV: PACIFIC RIM ADDRESS: #103, 19575 - 55A Avenue - Surrey, B. C. Canada - V3S 8P8

TEL: 001-604-532-8711 FAX: 001-604-532-8712 QUOTATION: e-mal! from Dave Hope DATE Of SAMPLES : 19/12/2012 LOCATION: UPM

'.'

BOX: 2 SENO REPORT ro: Eng. Alejandro Areelus

.. .

e.mail: arcelus@earu.org.uy

-. - -

Tel: (005982) 47225500 ext 106 Fax: (005982)47226786 Volume Bottle ( P: Plastic, (mI) AG: Amb Glass )

Analysis Nitrate+Nitrite Ammonia

I'L 1.1 '\

COO

p 1000

P

r

1000

AG

V

1000 1000

AG AG

1000

AG

"..

TKN (Total Kjeldhal Nitrogen)¿ Phenolie substances

-6'aMlis , "1g\) 3

Fdl'8l11S

Oi! and Grease Total Petroleum Hydrocarbons

¡/

JI'

PreservatJon

H2S04 ce. 2ml/l (pH<2) pl-h:: 2H2S04 ce. 1 mL/l p¡'¡. 2. (pH<4) I)P9 b Refrigerate

Sealing# (CARU 10#)

1326688

1326679

-4328618'"

ce. (pH<2)

1326680

H2S04 ce. (pH<2)

1327309

1011> '2t'hS04

,,;

&tl \)C\C\l-l:fP1::.CA'2.

50

().1Y\


COMISION ADMINISTRADORA DEL RIO URUGUAY P..,v'" ti

S

,

Chlorates

"'y"

250

P

P\I\" q NaOH 1mL/100ml (pH>8)

1326686

Sulphlde

11'

250

p

Zinc Acetate 10%, 1 S ml/l

1327306

125

P

HN03 cc. 2 ml/l, (pH <2) t),.

1326684

125

P

K2Cr207 5% in HN03 (1+1) 1 ml/1OOmL : 1. (pH <2)

1326685

125

P

b\t fe Refrigerate

1326681

\' tfro \,

"1m ,l

1\

HN03 cc. 2 ml/l (pH <2) 'lo-

see

Metals (except Mercury) P'

Mercury Microtox EC50

)/

P'

l) \\;;

p" -;

Important Note: Identlfy the reported results of each sample with the security seal attached to

,

each bottle and the date of analysis.

RLeCEDVEC: OEC1;82012 ......

Ing. ALEJANDRO ARCELUS

Secretario Técnico-CARU

Anexo 40  
Read more
Read more
Similar to
Popular now
Just for you