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Material Safety Data Sheet Motocryl 2K 60-Serie (leadfree)

1.

Product and company identification

Product name Distributor

: Motocryl 2K 60-Serie (leadfree) : Logicar Inc. 13000 NW 45th Ave. Opa-Locka, FL 33054, USA Technical Contact Info: Tel.: 1-305-685-8044

Validation date Print date Responsible name In case of emergency

: : : :

2.

10/1/2008. 10/1/2008. e-mail: info@automotiveart.com Emergency Tel #: 24 Hour: (CHEMTREC): 1-800-424-9300 Alternate International Emergency Tel #: (CHEMTREC): 1-703-527-3887

Hazards identification

Physical state OSHA/HCS status Emergency overview

: Liquid. : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). : WARNING! FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA. Flammable liquid. May be harmful if absorbed through skin. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing. Contains material that can cause target organ damage. Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling.

Potential acute health effects Inhalation : Ingestion : Skin : Eyes : Potential chronic health effects Chronic effects : Carcinogenicity : Mutagenicity Teratogenicity Developmental effects Fertility effects Target organs

: : : : :

No known significant effects or critical hazards. No known significant effects or critical hazards. Harmful in contact with skin. May cause skin irritation. May cause eye irritation. Contains material that can cause target organ damage. Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of exposure. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Contains material which causes damage to the following organs: blood, kidneys, liver, lymphatic system, gastrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.

Over-exposure signs/symptoms Inhalation : No specific data. 10/1/2008.

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2.

Hazards identification

Ingestion Skin Eyes Medical conditions aggravated by overexposure

: : : :

No specific data. No specific data. No specific data. Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product.

See toxicological information (section 11)

3.

Composition/information on ingredients

Name CAS number % n-butyl acetate 123-86-4 12.5 - 25 xylene 1330-20-7 5 - 12.5 2-methoxy-1-methylethyl acetate 108-65-6 1-5 ethylbenzene 100-41-4 1-5 2-butoxyethyl acetate 112-07-2 1-5 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

4.

First aid measures

Eye contact

: Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.

Skin contact

: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.

Inhalation

: Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.

Ingestion

: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.

Protection of first-aiders

: No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. : No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Notes to physician

5.

Fire-fighting measures

Flammability of the product

Extinguishing media Suitable Not suitable Special exposure hazards

10/1/2008.

: Flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. : Use dry chemical, CO2, water spray (fog) or foam. : Do not use water jet. : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

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5.

Fire-fighting measures

Hazardous thermal decomposition products

: Decomposition products may include the following materials: carbon dioxide carbon monoxide

Special protective equipment for fire-fighters

: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6.

Accidental release measures

Personal precautions

: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8).

Environmental precautions

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods for cleaning up Small spill

: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Large spill

: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal.

7.

Handling and storage

Handling

: Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

Storage

: Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

10/1/2008.

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8.

Exposure controls/personal protection

Product name n-butyl acetate

Exposure limits ACGIH TLV (United States, 1/2006). Notes: 1998 Adoption. STEL: 200 ppm 15 minute(s). TWA: 150 ppm 8 hour(s).

NIOSH REL (United States, 12/2001). STEL: 950 mg/m³ 15 minute(s). TWA: 710 mg/m³ 10 hour(s). OSHA PEL (United States, 11/2006). TWA: 710 mg/m³ 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 950 mg/m³ 15 minute(s). TWA: 710 mg/m³ 8 hour(s). xylene

2-methoxy-1-methylethyl acetate ethylbenzene

ACGIH TLV (United States, 1/2006). Notes: 1996 Adoption Substances for which there is a Biological Exposure Index or Indices Refers to Appendix A -- Carcinogens. STEL: 651 mg/m³, 0 times per shift, 15 minute(s). TWA: 434 mg/m³, 0 times per shift, 8 hour(s). OSHA PEL (United States, 8/1997). TWA: 435 mg/m³, 0 times per shift, 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 655 mg/m³, 0 times per shift, 15 minute(s). TWA: 435 mg/m³, 0 times per shift, 8 hour(s). AIHA WEEL (United States, 1/2006). TWA: 50 ppm 8 hour(s). ACGIH TLV (United States, 1/2006). Notes: Substances for which there is a Biological Exposure Index or Indices 2002 Adoption. STEL: 125 ppm 15 minute(s). TWA: 100 ppm 8 hour(s). NIOSH REL (United States, 12/2001). STEL: 545 mg/m³ 15 minute(s). TWA: 435 mg/m³ 10 hour(s). OSHA PEL (United States, 8/1997). TWA: 435 mg/m³ 8 hour(s). OSHA PEL 1989 (United States, 3/1989). STEL: 545 mg/m³ 15 minute(s). TWA: 435 mg/m³ 8 hour(s).

2-butoxyethyl acetate

ACGIH TLV (United States, 1/2006). Notes: Refers to Appendix A -Carcinogens. ACGIH 2003 Adoption TWA: 20 ppm 8 hour(s). NIOSH REL (United States, 12/2001). TWA: 33 mg/m³ 10 hour(s).

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8.

Exposure controls/personal protection

Recommended monitoring procedures Engineering measures

Hygiene measures

Personal protection Respiratory

Hands

Eyes

Skin

Environmental exposure controls

9.

: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Physical and chemical properties

Physical state Flash point Specific gravity VOC Solubility

: : : : :

Liquid. Closed cup: 27째C (80.6째F) 1.06 449 to 531 (g/l). Insoluble in the following materials: cold water and hot water.

10 . Stability and reactivity Stability Hazardous polymerization Conditions to avoid Materials to avoid Hazardous decomposition products

10/1/2008.

: The product is stable. : Under normal conditions of storage and use, hazardous polymerization will not occur. : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. : Reactive or incompatible with the following materials: oxidizing materials : Under normal conditions of storage and use, hazardous decomposition products should not be produced.

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11 . Toxicological information Acute toxicity Product/ingredient name 2-butoxyethyl acetate n-butyl acetate

Result LD50 Oral LD50 Dermal LD50 Oral 2-methoxy-1-methylethyl acetate LD50 Oral ethylbenzene LD50 Oral TDLo Intraperitoneal xylene LD50 Dermal LD50 Intraperitoneal LD50 Oral LD50 Subcutaneous Conclusion/Summary : Not available. Chronic toxicity Conclusion/Summary : Not available. Irritation/Corrosion Conclusion/Summary : Not available. Sensitizer Conclusion/Summary : Not available. Carcinogenicity Conclusion/Summary : Not available. Classification Product/ingredient name ACGIH IARC xylene A4 3 ethylbenzene A3 2B 2-butoxyethyl acetate A3 Mutagenicity Conclusion/Summary : Not available. Teratogenicity Conclusion/Summary : Not available. Reproductive toxicity Conclusion/Summary : Not available.

Species Rat Rabbit Rat Rat Rat Rat

Dose 2400 mg/kg >17600 mg/kg 10768 mg/kg 8532 mg/kg 3500 mg/kg 1062 mg/kg

Exposure -

Rabbit Rat

>1700 mg/kg 2459 mg/kg

-

Rat Rat

4300 mg/kg 1700 mg/kg

-

EPA -

NIOSH -

NTP -

OSHA -

12 . Ecological information Environmental effects Aquatic ecotoxicity Product/ingredient name n-butyl acetate

: No known significant effects or critical hazards. Test Mortality Mortality

ethylbenzene

Intoxication Intoxication Mortality Mortality

10/1/2008.

Result Acute LC50 100 mg/L Acute LC50 18 mg/L Acute EC50 2.97 mg/L Acute EC50 2.93 mg/L Acute LC50 4.2 mg/L Acute LC50 9.09 mg/L

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Species Fish

Exposure 96 hours

Fish

96 hours

Daphnia

48 hours

Daphnia

48 hours

Fish

96 hours

Fish

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12 . Ecological information Mortality xylene

Acute LC50 9.6 mg/L Acute LC50 13.4 mg/L Acute LC50 13.3 mg/L Acute LC50 12 mg/L Acute LC50 8.6 mg/L Acute LC50 8.2 mg/L Acute LC50 3.3 mg/L

Mortality Mortality Mortality Mortality Mortality Mortality

Conclusion/Summary Biodegradability Conclusion/Summary

Fish

96 hours

Fish

96 hours

Fish

96 hours

Fish

96 hours

Fish

96 hours

Fish

96 hours

Fish

96 hours

: Not available. : Not available.

13 . Disposal considerations : The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Waste disposal

Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

14 . Transport information Regulatory information

UN number

Proper shipping name

Classes

DOT Classification

1263

Paint (n-butyl acetate) 3

PG* Label

Additional information

III

FLAMMABLE LIQUID

3

TDG Classification

1263

Paint (n-butyl acetate) 3

III

3

Mexico Classification

1263

Paint (n-butyl acetate) 3

III

3

ADR/RID Class

1263

Paint (n-butyl acetate) 3

III

3

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14 . Transport information IMDG Class

1263

Paint (n-butyl acetate) 3

III 3

IATA-DGR Class

1263

Paint (n-butyl acetate) 3

III

Emergency schedules (EmS) 3-05 -

3

PG* : Packing group

15 . Regulatory information HCS Classification

: Flammable liquid Carcinogen Target organ effects

U.S. Federal regulations

: TSCA 4(a) final test rules: n-butyl acetate; dipropylene glycol methyl ether TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate; dipropylene glycol methyl ether United States inventory (TSCA 8b): All components are listed or exempted. TSCA 12(b) one-time export: n-butyl acetate; dipropylene glycol methyl ether SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: n-butyl acetate; xylene; ethylbenzene; 2-methoxy-1-methylethyl acetate; 2-butoxyethyl acetate SARA 311/312 MSDS distribution - chemical inventory - hazard identification: nbutyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard; 2-methoxy-1-methylethyl acetate: Fire hazard; 2-butoxyethyl acetate: Fire hazard, Immediate (acute) health hazard Clean Water Act (CWA) 307: ethylbenzene; benzene; toluene Clean Water Act (CWA) 311: n-butyl acetate; xylene; ethylbenzene; benzene; toluene Clean Air Act (CAA) 112 accidental release prevention: No products were found. Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

SARA 313 Product name CAS number Concentration 1330-20-7 5 - 12.5 : xylene ethylbenzene 100-41-4 1-5 2-butoxyethyl acetate 112-07-2 1-5 1330-20-7 5 - 12.5 Supplier notification : xylene ethylbenzene 100-41-4 1-5 2-butoxyethyl acetate 112-07-2 1-5 SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. State regulations : Connecticut Carcinogen Reporting: None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed. Florida substances: None of the components are listed. Illinois Chemical Safety Act: None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting: None of the components are listed. Louisiana Spill: None of the components are listed. Massachusetts Spill: None of the components are listed. Massachusetts Substances: The following components are listed: BUTYL ACETATE;ETHYL BENZENE QAMABC2K400LFcorr 8/10 10/1/2008. Form R - Reporting requirements


Motocryl 2K 60-Serie (leadfree)

15 . Regulatory information Michigan Critical Material: None of the components are listed. Minnesota Hazardous Substances: None of the components are listed. New Jersey Hazardous Substances: The following components are listed: n-BUTYL ACETATE;ETHYL BENZENE New Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The following components are listed: Butyl acetate;Ethylbenzene New York Toxic Chemical Release Reporting: None of the components are listed. Pennsylvania RTK Hazardous Substances: The following components are listed: ACETIC ACID, BUTYL ESTER;BENZENE, ETHYLRhode Island Hazardous Substances: None of the components are listed. California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Ingredient name

Cancer

Reproductive

No significant risk level

ethylbenzene toluene

Yes. No.

No. Yes.

No. No.

benzene

United States inventory (TSCA 8b) EU regulations Hazard symbol or symbols

Maximum acceptable dosage level No. 7000μg/ day (ingestion) 13000μg/ day (inhalation) 24μg/ day( i ngest i on)

6. 4μg/ day (ingestion) 13μg/ day( i nhal at i on)49μg/ day( i nhal at i on) : United States inventory (TSCA 8b): All components are listed or exempted. Yes.

Yes.

:

Risk phrases

: R10- Flammable. R20/21- Harmful by inhalation and in contact with skin. R66- Repeated exposure may cause skin dryness or cracking. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases

: S23- Do not breathe vapor or spray. S36/37- Wear suitable protective clothing and gloves. S38- In case of insufficient ventilation, wear suitable respiratory equipment. S46- If swallowed, seek medical advice immediately and show this container or label. S61- Avoid release to the environment. Refer to special instructions/safety data sheet.

International regulations Canada inventory International lists

10/1/2008.

: Canada inventory: Not determined. : Australia inventory (AICS): Not determined. China inventory (IECSC): Not determined. Korea inventory (KECI): Not determined. Philippines inventory (PICCS): Not determined. Japan inventory (ENCS): Not determined. Japan inventory (ISHL): Not determined. QAMABC2K400LFcorr

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16 . Other information Label requirements

: FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA.

Hazardous Material Information System (U.S.A.)

: Health

0

Flammability

0

Physical hazards

0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection : Association (U.S.A.) Flammability

3 Health

1

0

Instability Special

Date of printing

: 10/1/2008. : 10/1/2008. Date of issue Date of previous issue : No previous validation. Version : 2 Indicates information that has changed from previously issued version. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

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