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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/28/2011

Version: 1

Reviewed on 07/28/2011

1 Identification of the substance/mixture and of the company/undertaking · Product identifier · Trade name: Chrysal Clear Bulb T-bag · Article number: C371TB · Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the preparation Cut flower food (professional product) · Details of the supplier of the safety data sheet Chrysal International BV PO BOX 5300 1410 AH Naarden The Netherlands T.: +31 35 6955888 · Manufacturer/Supplier: Chrysal Colombia S.A: Cra 106 No. 15-25 Manzana 9, Bodega 21 Bogotá - Colombia Tel. (571) 4046529 · Information department: Mrs. Alejandra Rodríguez · Emergency telephone number: Tel.: (57) 3165281657 Emergency Contact Number (outside office hours): +018132480585

2 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 77-92-9 citric acid

2.5-10%

3 Hazards identification · Classification of the substance or mixture · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Void · Information concerning particular hazards for human and environment: No hazards to be particularly mentioned. Please note the information of this Material Safety Data Sheet. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · Additional information: Canadian Hazard Symbols: This is not a "controlled product" under WHMIS · Label elements · Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. · Classification system: · HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

0

REACTIVITY 0

Health = 0 Fire = 0 Reactivity = 0 (Contd. on page 2) USA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/28/2011

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Reviewed on 07/28/2011

Trade name: Chrysal Clear Bulb T-bag (Contd. of page 1)

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

4 First aid measures · Description of first aid measures · General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Rinse with warm water. Generally the product does not irritate the skin. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: Rinse out mouth and then drink plenty of water. When physical complaints arise, consult a doctor.

5 Firefighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Advice for firefighters · Protective equipment: No special measures required.

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Not required. · Environmental precautions: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage · Methods and material for containment and cleaning up: Pick up mechanically. · Reference to other sections No dangerous substances are released.

7 Handling and storage · Handling: · Precautions for safe handling No special measures required. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Store away from foodstuffs. · Further information about storage conditions: Store in dry conditions. Keep out of reach of children. · Maximum storage temperature: 40°C USA

(Contd. on page 3)


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/28/2011

Version: 1

Reviewed on 07/28/2011

Trade name: Chrysal Clear Bulb T-bag (Contd. of page 2)

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Not required. · Protection of hands: Not required. · Material of gloves · Penetration time of glove material · Eye protection: When following instructions eye protection is not necessary

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Powder Form: White Color: Characteristic · Odor: · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. · Flash point:

Not applicable.

· Ignition temperature:

1010.0°C (1850°F)

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Density:

Not determined.

· Solubility in / Miscibility with Soluble. Water: · Solvent content: Organic solvents: Solids content:

0.0 % 100.0 %

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. (Contd. on page 4) USA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/28/2011

Version: 1

Reviewed on 07/28/2011

Trade name: Chrysal Clear Bulb T-bag (Contd. of page 3)

· Possibility of hazardous reactions No dangerous reactions known. · Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information · Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: Irritation is possible. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us.

12 Ecological information · Toxicity · Acquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Additional ecological information: · General notes: Generally not hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

13 Disposal considerations · Waste treatment methods · Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. Non contaminated packagings can be treated like household garbage. · Recommended cleansing agent: Water, if necessary with cleaning agents.

14 Transport information · DOT regulations: · Hazard class: (Contd. on page 5) USA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/28/2011

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Reviewed on 07/28/2011

Trade name: Chrysal Clear Bulb T-bag (Contd. of page 4)

· Land transport ADR/RID (cross-border): · ADR/RID class: · Maritime transport IMDG: · IMDG Class: · Marine pollutant: No · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: · Special precautions for user Not applicable.

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. (Contd. on page 6) USA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/28/2011

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Reviewed on 07/28/2011

Trade name: Chrysal Clear Bulb T-bag (Contd. of page 5)

· OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

Version: 3

Reviewed on 05/21/2015

1 Identification · Product identifier · Trade name: Professional 1 (Hydration) · Article number: C552 · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Cut flower pretreatment product · Details of the supplier of the safety data sheet Chrysal International BV PO BOX 5300 1410 AH Naarden The Netherlands T: +31 35 6955888 · Manufacturer/Supplier: Chrysal Colombia S.A: Cra 106 No. 15-25 Manzana 9, Bodega 21 Bogotá - Colombia Tel. (571) 4046529 · Information department: Department: Regulatory Affairs of Chrysal International BV, the Netherlands Chrysal Americas 1-800-247-9725 · Emergency telephone number: ChemTel Inc. 1-800-255-3924 Int. +01-813-248-0585 Tel.: (57) 3165281657 *

2 Hazard(s) identification · Classification of the substance or mixture Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS07 · Signal word Warning · Hazard-determining components of labeling: alkyl alcohol etoxylated mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1) (Contd. on page 2) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

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Reviewed on 05/21/2015 (Contd. of page 1)

· Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. · Precautionary statements P280 Wear protective gloves / eye protection. P280 Wear protective clothing. P273 Avoid release to the environment. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. · Classification system: · NFPA ratings (scale 0 - 4) Health = 1 Fire = 0 Reactivity = 0

0 1

0

· HMIS-ratings (scale 0 - 4) HEALTH

1

FIRE

0

REACTIVITY 0

Health = 1 Fire = 0 Reactivity = 0

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 77-92-9 citric acid ≥10<25% 69011-36-5 alkyl alcohol etoxylated ≥5<10% 55965-84-9 mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 2- 0.1-<0.25% methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1)

4 First-aid measures · Description of first aid measures · After inhalation: No special measures required · After skin contact: Rinse with warm water. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth with water and drink one or two glasses of water. (Contd. on page 3) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

Version: 3

Reviewed on 05/21/2015 (Contd. of page 2)

· Most important symptoms and effects, both acute and delayed Exposure to isothiazolinones may cause allergic skin reaction in susceptible people. Skin reactions usually occur after 24 hours or more after exposure. Sometimes mucosal irritation and respiratory problems can occur · Indication of any immediate medical attention and special treatment needed Symptomatic treatment

5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: No special measures required.

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective clothing. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. *

7 Handling and storage · Precautions for safe handling No special precautions are necessary if used correctly. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None. · Specific end use(s) No further relevant information available.

*

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. (Contd. on page 4) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

Version: 3

Reviewed on 05/21/2015 (Contd. of page 3)

· Breathing equipment: Not required. · Protection of hands: Protective gloves · Material of gloves Short-term use: Chemical protective gloves with CE mark that comply with the standard (low chemical resistant / waterproof). Use chemical resistant gloves classified under standard EN 374 when prolonged or frequently repeated contact could occur. Recommended thickness of the material: ≥ 0.12 mm. Suitable glove material is e. g: Nitrile rubber, NBR Neoprene gloves · Penetration time of glove material Not applicable to gloves that meet the standard EN-374-1. For protective gloves that meet the standard EN 374 breakthrough time > 60 minutes (Protection Index Class 3 or higher). Check before each use the protective gloves for damage. Wear protective gloves no longer than necessary. · Eye protection: Tightly sealed goggles · Limitation and supervision of exposure into the environment Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage *

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Fluid Form: Colorless Color: Odorless · Odor: · pH-value at 20 °C (68 °F):

1.2

· Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 100 °C (212 °F) · Flash point:

Not applicable.

· Ignition temperature:

1010 °C (1850 °F)

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Vapor pressure at 20 °C (68 °F): 23 hPa (17 mm Hg) · Density at 20 °C (68 °F):

1.043 g/cm³ (8.704 lbs/gal) (Contd. on page 5) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

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Reviewed on 05/21/2015 (Contd. of page 4)

· Solubility in / Miscibility with Water:

Fully miscible.

· Solvent content: Organic solvents: Water: · Other information

0.0 % 69.7 % No further relevant information available.

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. *

11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: The product has not been tested. The values listed below are derived from the properties of the individual components: Oral LD50 (rat): > 5000 mg/kg Dermal LD50 (rabbit): > 5000 mg/kg Inhalation LC50 (rat): > 5000 mg/l · Primary irritant effect: · on the skin: Irritating (OECD 404) · on the eye: Irritating (OECD 438) · Sensitization: Sensitization possible through skin contact. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

*

12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. (Contd. on page 6) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

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Reviewed on 05/21/2015 (Contd. of page 5)

· Additional ecological information: · General notes: Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

13 Disposal considerations · Waste treatment methods · Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. Packaging can be reused or recycled after cleaning. · Recommended cleansing agent: Water, if necessary with cleaning agents.

14 Transport information · UN-Number · DOT, ADR, ADN, IMDG, IATA

Void

· UN proper shipping name · DOT, ADR, ADN, IMDG, IATA

Void

· Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class

Void

· Packing group · DOT, ADR, IMDG, IATA

Void

· Environmental hazards: · Marine pollutant:

No

· Special precautions for user

Not applicable.

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information:

Not dangerous according to the above specifications.

· UN "Model Regulation":

USA

(Contd. on page 7)


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Reviewed on 05/21/2015 (Contd. of page 6)

*

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS07 · Signal word Warning · Hazard-determining components of labeling: alkyl alcohol etoxylated mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1) · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. (Contd. on page 8) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

Version: 3

Reviewed on 05/21/2015 (Contd. of page 7)

· Precautionary statements P280 Wear protective gloves / eye protection. P280 Wear protective clothing. P273 Avoid release to the environment. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. · Chemical safety assessment For this product a chemical safety assessment has not been carried out. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing SDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs · Date of preparation / last revision 05/21/2015 / 2 · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3

· * Data compared to the previous version altered. USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015 *

Version: 3

Reviewed on 05/21/2015

1 Identification · Product identifier · Trade name: Chrysal Professional 2 Classic · Article number: C427 · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Cut flower food (professional product) · Details of the supplier of the safety data sheet Chrysal International BV PO BOX 5300 1410 AH Naarden The Netherlands T: +31 35 6955888 · Manufacturer/Supplier: Chrysal Colombia S.A: Cra 106 No. 15-25 Manzana 9, Bodega 21 Bogotá - Colombia Tel. (571) 4046529 · Information department: Department: Regulatory Affairs of Chrysal International BV, the Netherlands Chrysal Americas 1-800-247-9725 · Emergency telephone number: Tel.: (57) 3165281657 ChemTel Inc. 1-800-255-3924 Int. +01-813-248-0585

*

2 Hazard(s) identification · Classification of the substance or mixture Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS07 · Signal word Warning · Hazard-determining components of labeling: mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1) · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. (Contd. on page 2) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

Version: 3

Reviewed on 05/21/2015

Trade name: Chrysal Professional 2 Classic (Contd. of page 1)

· Precautionary statements P280 Wear protective gloves / eye protection. P280 Wear protective clothing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. · Classification system: · NFPA ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0

0 0

0

· HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

0

REACTIVITY 0

Health = 0 Fire = 0 Reactivity = 0

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *

3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 77-92-9 citric acid ≥2.5<5% 55965-84-9 mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 0.0015-<0.06% 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1)

*

4 First-aid measures · Description of first aid measures · After inhalation: No special measures required · After skin contact: Rinse with warm water. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth with water and drink one or two glasses of water. · Most important symptoms and effects, both acute and delayed Exposure to isothiazolinones may cause allergic skin reaction in susceptible people. Skin reactions usually occur after 24 hours or more after exposure. Sometimes mucosal irritation and respiratory problems can occur · Indication of any immediate medical attention and special treatment needed Symptomatic treatment USA

(Contd. on page 3)


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

Version: 3

Reviewed on 05/21/2015

Trade name: Chrysal Professional 2 Classic (Contd. of page 2)

5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: No special measures required. *

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective clothing. · Environmental precautions: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage · Methods and material for containment and cleaning up: Dilute with plenty water. Dispose contaminated material as waste according to item 13. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

*

7 Handling and storage · Precautions for safe handling No special precautions are necessary if used correctly. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None. · Specific end use(s) No further relevant information available.

*

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Wash hands before breaks and at the end of work. · Breathing equipment: Not required. (Contd. on page 4) USA


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Safety Data Sheet acc. to OSHA HCS Printing date 05/21/2015

Version: 3

Reviewed on 05/21/2015

Trade name: Chrysal Professional 2 Classic (Contd. of page 3)

· Protection of hands: Protective gloves · Material of gloves Short-term use: Chemical protective gloves with CE mark that comply with the standard (low chemical resistant / waterproof). Use chemical resistant gloves classified under standard EN 374 when prolonged or frequently repeated contact could occur. Recommended thickness of the material: ≥ 0.12 mm. Suitable glove material is e. g: Nitrile rubber, NBR Neoprene gloves · Penetration time of glove material Not applicable to gloves that meet the standard EN-374-1. For protective gloves that meet the standard EN 374 breakthrough time > 60 minutes (Protection Index Class 3 or higher). Check before each use the protective gloves for damage. Wear protective gloves no longer than necessary. · Eye protection: Tightly sealed goggles · Limitation and supervision of exposure into the environment Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage *

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Fluid Form: Colorless Color: Odorless · Odor: · pH-value at 20 °C (68 °F):

1.9

· Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. · Flash point:

Not applicable.

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Vapor pressure at 20 °C (68 °F): 23 hPa (17 mm Hg) · Density at 20 °C (68 °F):

1.151 g/cm³ (9.605 lbs/gal)

· Solubility in / Miscibility with Water:

Fully miscible. (Contd. on page 5) USA


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Version: 3

Reviewed on 05/21/2015

Trade name: Chrysal Professional 2 Classic (Contd. of page 4)

· Viscosity: Dynamic: Kinematic:

Not determined. Not determined.

· Solvent content: Organic solvents: Water: · Other information

0.0 % 65.9 % No further relevant information available.

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. *

11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: The product has not been tested. The values listed below are derived from the properties of the individual components: Oral LD50 (rat): > 5000 mg/kg Dermal LD50 (rabbit): > 5000 mg/kg Inhalation LC50 (rat): > 5000 mg/l · Primary irritant effect: · on the skin: Irritating (OECD 404) · on the eye: Irritating (OECD 438) · Sensitization: Sensitization possible through skin contact. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

*

12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Bioaccumulative potential No further relevant information available. (Contd. on page 6) USA


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Trade name: Chrysal Professional 2 Classic (Contd. of page 5)

· Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

13 Disposal considerations · Waste treatment methods · Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. Packaging can be reused or recycled after cleaning. · Recommended cleansing agent: Water, if necessary with cleaning agents. *

14 Transport information · UN-Number · DOT, ADR, ADN, IMDG, IATA

Void

· UN proper shipping name · DOT, ADN, IMDG, IATA · ADR

Void Void

· Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class

Void

· Packing group · DOT, ADR, IMDG, IATA

Void

· Environmental hazards: · Marine pollutant:

No

· Special precautions for user

Not applicable.

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information:

Not dangerous according to the above specifications.

· UN "Model Regulation":

USA

(Contd. on page 7)


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*

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS07 · Signal word Warning · Hazard-determining components of labeling: mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1) · Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. (Contd. on page 8) USA


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· Precautionary statements P280 Wear protective gloves / eye protection. P280 Wear protective clothing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. · Chemical safety assessment For this product a chemical safety assessment has not been carried out. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing SDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs · Date of preparation / last revision 05/21/2015 / 2 · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Skin Sens. 1: Sensitisation - Skin, Hazard Category 1

· * Data compared to the previous version altered. USA


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Reviewed on 06/22/2015

1 Identification · Product identifier · Trade name: Chrysal Professional 2 T-bag · Article number: C379 · Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the mixture Cut flower food (professional product) · Details of the supplier of the safety data sheet Chrysal International BV PO BOX 5300 1410 AH Naarden The Netherlands T: +31 35 6955888 · Manufacturer/Supplier: Chrysal Colombia S.A: Cra 106 No. 15-25 Manzana 9, Bodega 21 Bogotá - Colombia Tel. (571) 4046529 · Information department: Chrysal Americas 1-800-247-9725 · Emergency telephone number: Tel.: (57) 3165281657 ChemTel Inc. 1-800-255-3924 Int. +01-813-248-0585

*

2 Hazard(s) identification · Classification of the substance or mixture The product is not classified according to the Globally Harmonized System (GHS). · Label elements · GHS label elements Void · Hazard pictograms Void · Signal word Void · Hazard statements Void · Additional information: Contains 2-octyl-2H-isothiazol-3-one. May produce an allergic reaction (EUH208). Sensitizing effect by skin contact is possible with prolonged exposure. Do not open the sachet (T-Bag). If the sachet is damaged avoid contact with the content. · Classification system: · NFPA ratings (scale 0 - 4)

0 0

0

Health = 0 Fire = 0 Reactivity = 0 (Contd. on page 2) US


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· HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

0

REACTIVITY 0

Health = 0 Fire = 0 Reactivity = 0

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *

3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 77-92-9 citric acid 26530-20-1 2-octyl-2H-isothiazol-3-one

*

≥10<25% <0.05%

4 First-aid measures · Description of first aid measures · General information: No special measures required. · After inhalation: No special measures required · After skin contact: Rinse with warm water. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth with water and drink one or two glasses of water. · Information for doctor: · Most important symptoms and effects, both acute and delayed Exposure to isothiazolinones may cause allergic skin reaction in susceptible people. Skin reactions usually occur after 24 hours or more after exposure. Sometimes mucosal irritation and respiratory problems can occur · Indication of any immediate medical attention and special treatment needed Symptomatic treatment

5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: No special measures required. US

(Contd. on page 3)


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6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Not required. · Environmental precautions: No special measures required. · Methods and material for containment and cleaning up: Pick up mechanically. · Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 Handling and storage · Handling: · Precautions for safe handling No special precautions are necessary if used correctly. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. · Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Not required. · Protection of hands: Not required. · Material of gloves · Penetration time of glove material · Eye protection: When following instructions eye protection is not necessary US

(Contd. on page 4)


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Trade name: Chrysal Professional 2 T-bag (Contd. of page 3)

*

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Solid Form: White Color: Nearly odorless · Odor: Not determined. · Odour threshold: · pH-value:

Not applicable.

· Change in condition Melting point/Melting range: Boiling point/Boiling range:

Undetermined. Undetermined.

· Flash point:

Not applicable.

· Flammability (solid, gaseous):

Not determined.

· Ignition temperature:

1010 °C (1850 °F)

· Decomposition temperature:

Not determined.

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Explosion limits: Lower: Upper:

Not determined. Not determined.

· Vapor pressure:

Not applicable.

· Density: · Relative density · Vapour density · Evaporation rate

Not determined. Not determined. Not applicable. Not applicable.

· Solubility in / Miscibility with Water:

Soluble.

· Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic:

Not applicable. Not applicable.

· Solvent content: Organic solvents: Water:

0.0 % 8.6 %

Solids content: · Other information

100.0 % No further relevant information available. US

(Contd. on page 5)


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10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. *

11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: The product has not been tested. The values listed below are derived from the properties of the individual components: Oral LD50 (rat): > 5000 mg/kg Dermal LD50 (rabbit): > 5000 mg/kg Inhalation LC50 (rat): > 20 mg/l · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: Sensitizing effect by skin contact is possible with prolonged exposure. · Additional toxicological information: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. · Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

*

12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. (Contd. on page 6) US


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· Other adverse effects No further relevant information available.

13 Disposal considerations · Waste treatment methods · Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. · Uncleaned packagings: · Recommendation: Non contaminated packagings can be treated like household garbage. *

14 Transport information · UN-Number · DOT, ADR, ADN, IMDG, IATA

Void

· UN proper shipping name · DOT, ADR, ADN, IMDG, IATA

Void

· Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class

Void

· Packing group · DOT, ADR, IMDG, IATA

Void

· Environmental hazards: · Marine pollutant:

No

· Special precautions for user

Not applicable.

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code

*

· Transport/Additional information:

Not dangerous according to the above specifications.

· UN "Model Regulation":

-

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture No hazards to be particularly mentioned. Please note the information of this Material Safety Data Sheet. · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. (Contd. on page 7) US


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· TSCA (Toxic Substances Control Act): None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · Chemical safety assessment For this product a chemical safety assessment has not been carried out. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing SDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs · Date of preparation / last revision 06/22/2015 / 1 · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent

· * Data compared to the previous version altered. US


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1 Identification · Product identifier · Trade name: Chrysal Professional 3 · Article number: C428 · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Details of the supplier of the safety data sheet Chrysal International BV PO BOX 5300 1410 AH Naarden The Netherlands T: +31 35 6955888 · Manufacturer/Supplier: Chrysal Colombia S.A: Cra 106 No. 15-25 Manzana 9, Bodega 21 Bogotá - Colombia Tel. (571) 4046529 · Information department: Department: Regulatory Affairs of Chrysal International BV, the Netherlands Chrysal Americas 1-800-247-9725 · Emergency telephone number: Tel.: (57) 3165281657 ChemTel Inc. 1-800-255-3924 Int. +01-813-248-0585

*

2 Hazard(s) identification · Classification of the substance or mixture Skin Sens. 1 H317 May cause an allergic skin reaction. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS07 · Signal word Warning · Hazard-determining components of labeling: mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1) · Hazard statements H317 May cause an allergic skin reaction. · Precautionary statements P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. (Contd. on page 2) USA


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· Classification system: · NFPA ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0

0 0

0

· HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

0

REACTIVITY 0

Health = 0 Fire = 0 Reactivity = 0

· Other hazards · Results of PBT and vPvB assessment · PBT: This mixture does not contain substances that meet PBT criteria of REACH, annex XIII · vPvB: This mixture does not contain substances that meet vPvB criteria of REACH, annex XIII *

3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 77-92-9 citric acid ≥1<2.5% 55965-84-9 mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 0.0015-<0.06% 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1)

*

4 First-aid measures · Description of first aid measures · After inhalation: No special measures required · After skin contact: Rinse with warm water. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth with water and drink one or two glasses of water. · Most important symptoms and effects, both acute and delayed Exposure to isothiazolinones may cause allergic skin reaction in susceptible people. Skin reactions usually occur after 24 hours or more after exposure. Sometimes mucosal irritation and respiratory problems can occur · Indication of any immediate medical attention and special treatment needed Symptomatic treatment

5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 3) USA


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· Advice for firefighters · Protective equipment: No special measures required.

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective clothing. · Environmental precautions: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 Handling and storage · Precautions for safe handling No special precautions are necessary if used correctly. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None. · Specific end use(s) No further relevant information available. *

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Wash hands before breaks and at the end of work. · Breathing equipment: Not required. · Protection of hands: Protective gloves recommended. · Material of gloves Short-term use: Chemical protective gloves with CE mark that comply with the standard (low chemical resistant / waterproof). Use chemical resistant gloves classified under standard EN 374 when prolonged or frequently repeated contact could occur. Recommended thickness of the material: ≥ 0.12 mm. Suitable glove material is e. g: Nitrile rubber, NBR Neoprene gloves (Contd. on page 4) USA


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· Penetration time of glove material Not applicable to gloves that meet the standard EN-374-1. For protective gloves that meet the standard EN 374 breakthrough time > 60 minutes (Protection Index Class 3 or higher). Check before each use the protective gloves for damage. Wear protective gloves no longer than necessary. · Eye protection: Goggles recommended during refilling. · Limitation and supervision of exposure into the environment Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage *

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Fluid Form: Colorless Color: Odorless · Odor: Not determined. · Odour threshold: · pH-value at 20 °C (68 °F):

2

· Change in condition Melting point/Melting range: Boiling point/Boiling range:

Undetermined. Undetermined.

· Flash point:

Not applicable.

· Ignition temperature: Decomposition temperature:

Not determined.

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Explosion limits: Lower: Upper:

Not determined. Not determined.

· Vapor pressure at 20 °C (68 °F):

23 hPa (17 mm Hg)

· Density at 20 °C (68 °F): · Relative density · Vapour density · Evaporation rate

1.2 g/cm³ (10.014 lbs/gal) Not determined. Not determined. Not determined.

· Solubility in / Miscibility with Water:

Fully miscible.

· Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic:

Not determined. Not determined.

· Solvent content: Organic solvents: Water:

0.0 % 55.9 % (Contd. on page 5) USA


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· Other information

No further relevant information available.

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. *

11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: The product has not been tested. The values listed below are derived from the properties of the individual components: Oral LD50 (rat): > 5000 mg/kg Dermal LD50 (rabbit): > 5000 mg/kg Inhalation LC50 (rat): > 5000 mg/l · Primary irritant effect: · on the skin: Not irritating · on the eye: Not irritating · Sensitization: Sensitization possible through skin contact. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant · Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

*

12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. (Contd. on page 6) USA


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· Additional ecological information: · General notes: Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · Results of PBT and vPvB assessment · PBT: This mixture does not contain substances that meet the PBT criteria of REACH, Annex XIII. · vPvB: This mixture does not contain substances that meet vPvB criteria of REACH, Annex XIII. · Other adverse effects No further relevant information available.

13 Disposal considerations · Waste treatment methods · Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning. · Recommended cleansing agent: Water, if necessary with cleaning agents.

14 Transport information · UN-Number · DOT, ADR, ADN, IMDG, IATA

Void

· UN proper shipping name · DOT, ADR, ADN, IMDG, IATA

Void

· Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class

Void

· Packing group · DOT, ADR, IMDG, IATA

Void

· Environmental hazards: · Marine pollutant:

No

· Special precautions for user

Not applicable.

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information:

Not dangerous according to the above specifications.

· UN "Model Regulation":

USA

(Contd. on page 7)


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Trade name: Chrysal Professional 3 (Contd. of page 6)

*

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS07 · Signal word Warning · Hazard-determining components of labeling: mixture of: 5-chloro-2-methyl-2 H -isothiazol-3-one [EC No 247-500-7] and 2-methyl-2 H -isothiazol-3-one [EC No 220-239-6] (3:1) · Hazard statements H317 May cause an allergic skin reaction. · Precautionary statements P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. (Contd. on page 8) USA


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Trade name: Chrysal Professional 3 (Contd. of page 7)

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing SDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs · Date of preparation / last revision 05/19/2015 / 1 · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) Skin Sens. 1: Sensitisation - Skin, Hazard Category 1

· * Data compared to the previous version altered. USA


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1 Identification · Product identifier · Trade name: Chrysal Clear Universal (sachets) · Article number: C363 · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Cut flower food · Details of the supplier of the safety data sheet Chrysal International BV PO BOX 5300 1410 AH Naarden The Netherlands T: +31 35 6955888 · Manufacturer/Supplier: Chrysal Colombia S.A: Cra 106 No. 15-25 Manzana 9, Bodega 21 Bogotá - Colombia Tel. (571) 4046529 · Information department: Chrysal Americas 1-800-247-9725 · Emergency telephone number: ChemTel Inc. 1-800-255-3924 Int. +01-813-248-0585 Tel.: (57) 3165281657

*

2 Hazard(s) identification · Classification of the substance or mixture The product is not classified according to the Globally Harmonized System (GHS). · Label elements · GHS label elements Void · Hazard pictograms Void · Signal word Void · Hazard statements Void · Classification system: · NFPA ratings (scale 0 - 4)

0 0

0

Health = 0 Fire = 0 Reactivity = 0 (Contd. on page 2) US


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· HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

0

REACTIVITY 0

*

Health = 0 Fire = 0 Reactivity = 0

3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 77-92-9 citric acid

*

≥2.5<5%

4 First-aid measures · Description of first aid measures · General information: No special measures required. · After inhalation: No special measures required · After skin contact: Immediately rinse with water. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth with water and drink one or two glasses of water. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available. · Advice for firefighters · Protective equipment: No special measures required.

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Not required. · Environmental precautions: No special measures required. · Methods and material for containment and cleaning up: Pick up mechanically. (Contd. on page 3) US


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Trade name: Chrysal Clear Universal (sachets) (Contd. of page 2)

· Reference to other sections No dangerous substances are released.

7 Handling and storage · Handling: · Precautions for safe handling No special measures required. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None. · Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Not required. · Protection of hands: Not required. · Material of gloves · Penetration time of glove material · Eye protection: When following instructions eye protection is not necessary

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Solid Form: According to product specification Color: Characteristic · Odor: · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. (Contd. on page 4) US


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Trade name: Chrysal Clear Universal (sachets) (Contd. of page 3)

· Flash point:

Not applicable.

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Density:

Not determined.

· Solubility in / Miscibility with Soluble. Water: · Viscosity: Dynamic:

Not applicable.

· Solvent content: Organic solvents: Water:

0.0 % 9.3 %

Solids content: · Other information

100.0 % No further relevant information available.

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. *

11 Toxicological information · Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. · Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed. (Contd. on page 5) US


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Trade name: Chrysal Clear Universal (sachets) (Contd. of page 4)

· NTP (National Toxicology Program) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Must not reach bodies of water or drainage ditch undiluted or unneutralized. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

13 Disposal considerations · Waste treatment methods · Recommendation: Smaller quantities can be disposed of with household waste. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleaning agents. *

14 Transport information · UN-Number · DOT, ADR, ADN, IMDG, IATA

Void

· UN proper shipping name · DOT, ADN, IMDG, IATA · ADR

Void Void

· Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class

Void

· Packing group · DOT, ADR, IMDG, IATA

Void

· Environmental hazards: · Marine pollutant:

No (Contd. on page 6) US


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· Special precautions for user

Not applicable.

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code

*

· Transport/Additional information:

Not dangerous according to the above specifications.

· UN "Model Regulation":

-

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · Chemical safety assessment For this product a chemical safety assessment has not been carried out. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. US

(Contd. on page 7)


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Trade name: Chrysal Clear Universal (sachets) (Contd. of page 6)

*

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing SDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs · Date of preparation / last revision 06/29/2015 / 2 · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA)

· * Data compared to the previous version altered. US


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acc. to WHMIS 2015 Version: 2

Reviewed on 04/06/2016

1 Identification

· Product identifier EPA Registration No.: 71297-5-72992 · Trade name: CVBN (USA)

· Article number: T717 (T720 USA) · Application of the substance / the mixture Cut flower pretreatment product · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Chrysal International BV P.O. Box 5300 1410 AH NAARDEN Gooimeer 7 1411 DD NAARDEN The Netherlands Tel.: +31 (0)35 6955888 Fax: +31 (0)35 6955822 E-mail: info@chrysal.nl

· Information department: Department: Regulatory Affairs of Chrysal International BV, the Netherlands Chrysal Americas 1-800-247-9725 · Emergency telephone number: ChemTel Inc. 1-800-255-3924 Int. +01-813-248-0585 *

2 Hazard(s) identification

· Classification of the substance or mixture Acute Toxicity (Oral) - Category 4 Eye Irritation - Category 2A Specific Target Organ Toxicity - Single Exposure Category 3

H302 Harmful if swallowed. H319 Causes serious eye irritation. H335 May cause respiratory irritation.

· Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS07

· Signal word Warning

· Hazard-determining components of labeling: sodium dichloroisocyanurate, dihydrate · Hazard statements H302 Harmful if swallowed. H319 Causes serious eye irritation. H335 May cause respiratory irritation. · Precautionary statements P270 Do not eat, drink or smoke when using this product.

(Contd. on page 2)

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Trade name: CVBN (USA) (Contd. of page 1)

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P337+P313 If eye irritation persists: Get medical advice/attention. P402+P404 Store in a dry place. Store in a closed container. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Hazard description: · WHMIS 1988 classification

· Classification system: · NFPA ratings (scale 0 - 4)

1

0

OX

0

Health = 1 Fire = 0 Reactivity = 0

The substance possesses oxidizing properties.

3 Composition/information on ingredients

· Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions.

· Dangerous components: Void · Additional information: For the wording of the listed risk phrases refer to section 16.

4 First-aid measures

· Description of first aid measures · General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After skin contact: Wash with water and soap and rinse thoroughly In case of complaints consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Seek immediate medical advice. Rinse out mouth with water and drink 2 glases of water · Information for doctor: Probable mucosal damage may contraindicate the use of gastric lavage · Most important symptoms and effects, both acute and delayed No further relevant information available.

(Contd. on page 3)

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Trade name: CVBN (USA) (Contd. of page 2)

· Indication of any immediate medical attention and special treatment needed Symptomatic treatment

5 Fire-fighting measures

· Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture Negligible fire hazard During heating or in case of fire poisonous gases are produced. · Advice for firefighters · Protective equipment: Mount respiratory protective device.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · Environmental precautions: No special measures required. · Methods and material for containment and cleaning up: Pick up mechanically. Remainder of material can be washed to drain with plenty of water. Dispose of the collected material according to regulations. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 Handling and storage

· Handling: · Precautions for safe handling Prevent formation of dust. · Information about protection against explosions and fires: Keep respiratory protective device available. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Do not store together with acids. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. · Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.

· Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

(Contd. on page 4)

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Trade name: CVBN (USA) · Additional information: The lists that were valid during the creation were used as basis.

(Contd. of page 3)

· Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Breathing equipment: Not required. · Protection of hands: When following instructions no special clothing / skin protection is needed. · Material of gloves · Penetration time of glove material · Eye protection: When using the dispenser no special eye protection is required.

9 Physical and chemical properties

· Information on basic physical and chemical properties · General Information · Appearance: Solid Form: According to product specification Color: Characteristic · Odor: · Change in condition Melting point/Melting range: 250 °C Boiling point/Boiling range: Undetermined. · Flash point:

Not applicable.

· Auto igniting:

Product is not selfigniting.

· Ignition temperature: · Danger of explosion: · Density at 20 °C:

· Bulk density at 20 °C:

250 °C

Product does not present an explosion hazard. .99 g/cm³

1000 kg/m³

· Solubility in / Miscibility with 250 g/l Water at 25 °C: · Solvent content: Organic solvents: Solids content: · Other information

0.0 %

100.0 % No further relevant information available.

10 Stability and reactivity

· Reactivity No further relevant information available. · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.

(Contd. on page 5)

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Trade name: CVBN (USA) · Possibility of hazardous reactions Contact with acids releases toxic gases. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known.

(Contd. of page 4)

11 Toxicological information

· Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 51580-86-0 sodium dichloroisocyanurate, dihydrate Oral LD50 1400 mg/kg (rat) · Primary irritant effect: · on the skin: No irritant effect. · on the eye: Strong irritant with the danger of severe eye injury. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant · Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed.

· OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

12 Ecological information

· Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Very toxic for aquatic organisms Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

(Contd. on page 6)

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Trade name: CVBN (USA) · Other adverse effects No further relevant information available.

(Contd. of page 5)

13 Disposal considerations

· Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations.

14 Transport information · UN-Number · DOT · TDG, IMDG, IATA

· UN proper shipping name · DOT · TDG · IMDG · IATA · Transport hazard class(es)

Void UN3077 Void 3077 Environmentally hazardous substances, solid, n.o.s. (sodium dichloroisocyanurate, dihydrate) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (sodium dichloroisocyanurate, dihydrate), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (sodium dichloroisocyanurate, dihydrate)

· DOT · Class

Void

· Class · Label

9 Miscellaneous dangerous substances and articles 9

· TDG, IMDG, IATA

· Packing group · DOT · TDG, IMDG, IATA

· Environmental hazards: · Marine pollutant:

· Special marking (TDG): · Special marking (IATA):

Void III Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree)

(Contd. on page 7)

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Trade name: CVBN (USA) · Special precautions for user · Danger code (Kemler): · EMS Number:

(Contd. of page 6)

Warning: Miscellaneous dangerous substances and articles 90 F-A,S-F

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information: · DOT

· TDG · Excepted quantities (EQ) · IMDG · Limited quantities (LQ) · Excepted quantities (EQ) · IATA · Remarks:

· UN "Model Regulation":

NOT regulated (if shipped in NON BULK packaging by ground transport) Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g 5 kg Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g Packing instructions 911 / Max net weight 400 kg.

UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (SODIUM DICHLOROISOCYANURATE, DIHYDRATE), 9, III

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): None of the ingredients is listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed.

(Contd. on page 8)

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Trade name: CVBN (USA) · Chemicals known to cause developmental toxicity: None of the ingredients is listed.

(Contd. of page 7)

· Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed.

· TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed.

· MAK (German Maximum Workplace Concentration) None of the ingredients is listed.

· NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · National regulations:

· Other regulations, limitations and prohibitive regulations Following is the hazard information as required on the pesticide label of Chrysal CVBN (reg.no. 72992-12): DANGER: Corrosive. Causes irreversible eye damage. Harmful if swallowed or absorbed through skin. Strong oxidizing agent. Mix this product only with water. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

· Department issuing MSDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs · Date of preparation / last revision 04/06/2016 / 1 · Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Toxicity (Oral) - Category 4: Acute toxicity, Hazard Category 4 Eye Irritation - Category 2A: Serious eye damage/eye irritation, Hazard Category 2A Specific Target Organ Toxicity - Single Exposure - Category 3: Specific target organ toxicity - Single exposure, Hazard Category 3

· * Data compared to the previous version altered.

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1 Identification of the substance/mixture and of the company/undertaking · Product identifier · Trade name: Chrysal Professional Glory · Article number: 261.xxx.xxx · Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the preparation Flower and foliage shield · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Chrysal International BV P.O. Box 5300 1410 AH NAARDEN Gooimeer 7 1411 DD NAARDEN The Netherlands Tel.: +31 (0)35 6955888 Fax: +31 (0)35 6955822 E-mail: info@chrysal.nl · Information department: Department: Regulatory Affairs · Emergency telephone number: Tel.: +31 (0)35 6955851

2 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: Void · Additional information: For the wording of the listed risk phrases refer to section 16.

3 Hazards identification · Classification of the substance or mixture · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Void · Information concerning particular hazards for human and environment: No hazards to be particularly mentioned. Please note the information of this Material Safety Data Sheet. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · Additional information: Canadian Hazard Symbols: This is not a "controlled product" under WHMIS · Label elements · Labelling according to EU guidelines: The substance is not subject to classification according to the sources of literature known to us. Observe the general safety regulations when handling chemicals. · Classification system: · NFPA ratings (scale 0 - 4)

0

1

0

Health = 0 Fire = 1 Reactivity = 0 (Contd. on page 2) USA


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Trade name: Chrysal Professional Glory (Contd. of page 1)

· HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

1

REACTIVITY 0

Health = 0 Fire = 1 Reactivity = 0

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

4 First aid measures · Description of first aid measures · General information: No special measures required. · After inhalation: Supply fresh air. · After skin contact: Generally the product does not irritate the skin. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water.

5 Firefighting measures · Extinguishing media · Suitable extinguishing agents: Use fire fighting measures that suit the environment. · Advice for firefighters · Protective equipment: No special measures required.

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Not required. · Environmental precautions: Dilute with plenty of water. · Methods and material for containment and cleaning up: No special measures required. · Reference to other sections No dangerous substances are released.

7 Handling and storage · Handling: · Precautions for safe handling No special measures required. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None.

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. (Contd. on page 3) USA


DR

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Reviewed on 07/01/2010

Trade name: Chrysal Professional Glory (Contd. of page 2)

· Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Not required. · Protection of hands: Not required. · Material of gloves · Penetration time of glove material · Eye protection: Not required.

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Fluid Form: According to product specification Color: Characteristic · Odor: · Change in condition Melting point/Melting range: 0°C (32°F) Boiling point/Boiling range: 100°C (212°F) · Flash point:

> 100°C (> 212°F)

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Vapor pressure at 20°C (68°F): 23 hPa (17 mm Hg) · Density at 20°C (68°F):

1 g/cm³ (8.345 lbs/gal)

· Solubility in / Miscibility with Water:

Fully miscible.

· Solvent content: Organic solvents: Water:

0.0 % 95.0 %

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Hazardous decomposition products: No dangerous decomposition products known. USA

(Contd. on page 4)


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Trade name: Chrysal Professional Glory (Contd. of page 3)

11 Toxicological information · Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us.

12 Ecological information · Toxicity · Acquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Additional ecological information: · General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.

13 Disposal considerations · Waste treatment methods · Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. · Uncleaned packagings: · Recommendation: Packaging can be reused or recycled after cleaning. · Recommended cleansing agent: Water, if necessary with cleaning agents.

14 Transport information · DOT regulations: · Hazard class: · Land transport ADR/RID (cross-border): · ADR/RID class: · Maritime transport IMDG: · IMDG Class: · Marine pollutant: No · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: (Contd. on page 5) USA


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Trade name: Chrysal Professional Glory (Contd. of page 4)

· Special precautions for user Not applicable. · Transport/Additional information: Not dangerous according to the above specifications.

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): 7732-18-5 water, distilled, conductivity or of similarpurity · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. USA


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Version: 4

Reviewed on 05/28/2015

1 Identification · Product identifier · Trade name: Chrysal LEAFSHINE (aerosol) · Article number: 703.xxx.xxx · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Plant care product · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Chrysal International BV P.O. Box 5300 1410 AH NAARDEN Gooimeer 7 1411 DD NAARDEN The Netherlands Tel.: +31 (0)35 6955888 Fax: +31 (0)35 6955822 E-mail: info@chrysal.nl · Information department: Chrysal Americas 1-800-247-9725 Department: Regulatory Affairs of Chrysal International BV, the Netherlands · Emergency telephone number: ChemTel Inc. 1-800-255-3924 Int. +01-813-248-0585 +31 (0)35 6955851 or +31 (0)35 6955827 (during office hours: UTC+1)

*

2 Hazard(s) identification · Classification of the substance or mixture Flam. Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS02 · Signal word Danger · Hazard statements H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated. · Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. P211 Do not spray on an open flame or other ignition source. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. (Contd. on page 2) USA


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 1)

· Classification system: · NFPA ratings (scale 0 - 4) Health = 0 Fire = 4 Reactivity = 1

4 0

1

· HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

4

REACTIVITY 1

Health = 0 Fire = 4 Reactivity = 1

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *

3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 90622-57-4 Mixture of isoparaffin 106-97-8 butane 74-98-6 propane 67-63-0 propan-2-ol

*

≥25<50% ≥10<25% ≥10<25% ≥5<10%

4 First-aid measures · Description of first aid measures · After inhalation: Supply fresh air. · After skin contact: Rinse with warm water. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth with water and drink one or two glasses of water. · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available.

*

5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 3) USA


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 2)

· Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. *

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Keep away from ignition sources Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. Keep contaminated washing water and dispose of appropriately. · Methods and material for containment and cleaning up: Ensure adequate ventilation. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

*

7 Handling and storage · Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. · Information about protection against explosions and fires: Do not spray on a naked flame or any incandescent material. Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C, i.e. electric lights. Do not pierce or burn, even after use. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. · Specific end use(s) No further relevant information available.

*

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: 106-97-8 butane REL 1900 mg/m³, 800 ppm TLV Varies mg/m³, 1000 ppm 74-98-6 propane PEL 1800 mg/m³, 1000 ppm REL 1800 mg/m³, 1000 ppm TLV Varies mg/m³, 1000 ppm (Contd. on page 4) USA


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 3)

67-63-0 propan-2-ol PEL 980 mg/m³, 400 ppm REL Short-term value: 1225 mg/m³, 500 ppm Long-term value: 980 mg/m³, 400 ppm TLV Short-term value: 984 mg/m³, 400 ppm Long-term value: 492 mg/m³, 200 ppm BEI · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Wash hands before breaks and at the end of work. · Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: Not required. · Material of gloves · Penetration time of glove material · Eye protection: When following instructions eye protection is not necessary *

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Aerosol Form: Colorless Color: Mineral-oil-like · Odor: Not determined. · Odour threshold: · pH-value:

Not determined.

· Change in condition Melting point/Melting range: Boiling point/Boiling range:

Undetermined. < 35 °C (< 95 °F)

· Flash point:

Not applicable, as aerosol.

· Ignition temperature:

365 °C (689 °F)

· Decomposition temperature:

Not determined.

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Not determined.

· Explosion limits: Lower: Upper:

1.5 Vol % 10.9 Vol %

· Vapor pressure at 20 °C (68 °F):

8300 hPa (6226 mm Hg)

· Density at 20 °C (68 °F): · Relative density · Vapour density · Evaporation rate

0.667 g/cm³ (5.566 lbs/gal) Not determined. Not determined. Not applicable. (Contd. on page 5) USA


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 4)

· Solubility in / Miscibility with Water:

Not miscible or difficult to mix.

· Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic:

Not determined. Not determined.

· Solvent content: Organic solvents:

50.0 %

Solids content: · Other information

50.0 % No further relevant information available.

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid Keep away from heat and direct sunlight. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. *

11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 90622-57-4 Mixture of isoparaffin Oral LD50 >5000 mg/kg (rat) (OECD Guideline 401) Dermal LD50 >5000 mg/kg (rabbit) (OECD Guideline 402) Inhalative LC50/4 h >5000 mg/l (rat) (OECD Guideline 403) 67-63-0 propan-2-ol Oral LD50 4570 mg/kg (rat) Dermal LD50 13400 mg/kg (rabbit) Inhalative LC50/4 h >20 mg/l (rat) · Primary irritant effect: · on the skin: Prolonged or repeated exposure mau cause dryness or skin irritation · on the eye: Irritation is possible. · Sensitization: No sensitizing effects known. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) 67-63-0 propan-2-ol

3

· NTP (National Toxicology Program) None of the ingredients is listed. (Contd. on page 6) USA


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 5)

· OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

*

12 Ecological information · Toxicity · Aquatic toxicity: 90622-57-4 Mixture of isoparaffin EC50 / 72h >1000 mg/l (Pseudokirchneriella subcapitata) EC50/ 48h >1000 mg/L (daphnia) IC50 / 72 >1000 mg/l (Oncorhynchus mykiss) NOEC ≥ 1 mg/l (daphnia) · Persistence and degradability No further relevant information available. · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

*

13 Disposal considerations · Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Do not pierce or burn, even after use. · Uncleaned packagings: · Recommendation: Dispose of packaging according to regulations on the disposal of packagings. Non contaminated packagings can be used for recycling.

14 Transport information · UN-Number · DOT, ADR, IMDG, IATA

UN1950

· UN proper shipping name · ADR · IMDG · IATA

1950 AEROSOLS AEROSOLS AEROSOLS, flammable (Contd. on page 7) USA


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 6)

· Transport hazard class(es) · DOT

· Class · Label

2.1 2.1

· ADR

· Class · Label

2 5F Gases 2.1

· IMDG, IATA

· Class · Label

2.1 2.1

· Packing group · DOT, ADR, IMDG, IATA

Void

· Environmental hazards: · Marine pollutant:

No

· Special precautions for user · Danger code (Kemler): · EMS Number:

Warning: Gases F-D,S-U

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information: · ADR · Excepted quantities (EQ) · IMDG · Limited quantities (LQ) · Excepted quantities (EQ) · UN "Model Regulation":

Not dangerous according to the above specifications. Code: E0 Not permitted as Excepted Quantity 1L Code: E0 Not permitted as Excepted Quantity UN1950, Aerosols, 2.1 USA

(Contd. on page 8)


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 7)

*

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): 67-63-0 propan-2-ol · TSCA (Toxic Substances Control Act): 106-97-8 butane 74-98-6 propane 67-63-0 propan-2-ol 63148-62-9 Polydimethylsiloxane · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) 67-63-0 propan-2-ol

A4

· MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms

GHS02 · Signal word Danger · Hazard statements H222-H229 Extremely flammable aerosol. Pressurized container: May burst if heated. · Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P251 Pressurized container: Do not pierce or burn, even after use. (Contd. on page 9) USA


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Trade name: Chrysal LEAFSHINE (aerosol) (Contd. of page 8)

P211 Do not spray on an open flame or other ignition source. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing SDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs · Date of preparation / last revision 05/28/2015 / 3 · Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) Flam. Aerosol 1: Flammable aerosols, Hazard Category 1

· * Data compared to the previous version altered. USA


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Reviewed on 07/09/2012

1 Identification of the substance/mixture and of the company/undertaking · Product identifier · Trade name: Chrysal silk and dried flower cleaner · Article number: T709 · Relevant identified uses of the substance or mixture and uses advised against · Application of the substance / the preparation Silk, dried flower & plant freshner · Details of the supplier of the safety data sheet Chrysal International BV PO BOX 5300 1410 AH Naarden The Netherlands T.: +31 35 6955888 · Manufacturer/Supplier: Chrysal International BV P.O. Box 5300 1410 AH NAARDEN Gooimeer 7 1411 DD NAARDEN The Netherlands Tel.: +31 (0)35 6955888 Fax: +31 (0)35 6955822 E-mail: info@chrysal.nl · Information department: Department: Regulatory Affairs

2 Hazards identification · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Void · Information concerning particular hazards for human and environment: No hazards to be particularly mentioned. Please note the information of this Material Safety Data Sheet. Warning! Pressurized container. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · Label elements · Labelling according to EU guidelines: The substance is not subject to classification according to the sources of literature known to us. Observe the general safety regulations when handling chemicals. · Safety phrases: Keep out of the reach of children. Do not breathe spray. Use only in well-ventilated areas. · Special labelling of certain preparations: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric lights. Do not pierce or burn, even after use. 25.0 % by mass of the contents are flammable (Contd. on page 2) USA


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Trade name: Chrysal silk and dried flower cleaner (Contd. of page 1)

· Classification system: · HMIS-ratings (scale 0 - 4) HEALTH

0

FIRE

0

REACTIVITY 1

Health = 0 Fire = 0 Reactivity = 1

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *

3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 74-98-6 propane 106-97-8 butane 75-28-5 isobutane 90622-57-4 Mixture of isoparaffin · Additional information: For the wording of the listed risk phrases refer to section 16.

2.5-10% 2.5-10% 2.5-10% 2.5-10%

4 First aid measures · Description of first aid measures · General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Rinse with warm water. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Firefighting measures · Extinguishing media · Suitable extinguishing agents: Water haze Foam Carbon dioxide · For safety reasons unsuitable extinguishing agents: Water with full jet · Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 3) USA


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Trade name: Chrysal silk and dried flower cleaner (Contd. of page 2)

· Advice for firefighters · Protective equipment: No special measures required.

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Particular danger of slipping on leaked/spilled product. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Ensure adequate ventilation. · Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

7 Handling and storage · Handling: · Precautions for safe handling Spilling or spraying on floors causes slippery floors with danger of slipping. · Information about protection against explosions and fires: The product is not flammable. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Observe official regulations on storing packagings with pressurized containers. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store in dry conditions. Store receptacle in fume compartment. Protect from frost. Keep out of reach of children. · Maximum storage temperature: 40°C · Minimum storage temperature: 4°C · Specific end use(s) No further relevant information available. *

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: 106-97-8 butane REL 1900 mg/m³, 800 ppm · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Do not eat, drink, smoke or sniff while working. The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. (Contd. on page 4) USA


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Trade name: Chrysal silk and dried flower cleaner (Contd. of page 3)

· Protection of hands: Not required. · Material of gloves · Penetration time of glove material · Eye protection: When following instructions eye protection is not necessary

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Aerosol Form: Whitish Color: Odorless · Odor: Not determined. · Odour threshold: · pH-value at 20°C (68 °F):

6

· Change in condition Melting point/Melting range: Boiling point/Boiling range:

Undetermined. -44°C (-47 °F)

· Flash point:

Not applicable, as aerosol.

· Flammability (solid, gaseous):

Not applicable.

· Ignition temperature:

365°C (689 °F)

· Decomposition temperature:

Not determined.

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Explosion limits: Lower: Upper:

1.5 Vol % 8.5 Vol %

· Vapor pressure at 20°C (68 °F):

23 hPa (17 mm Hg)

· Density at 20°C (68 °F): · Relative density · Vapour density · Evaporation rate

0.841 g/cm³ (7.018 lbs/gal) Not determined. Not determined. Not applicable.

· Solubility in / Miscibility with Water:

Fully miscible.

· Segregation coefficient (n-octonol/water): Not determined. · Viscosity: Dynamic: Kinematic:

Not determined. Not determined.

· Solvent content: Organic solvents: Water:

20.0 % 75.0 %

Solids content:

5.0 % (Contd. on page 5) USA


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· Other information

No further relevant information available.

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Nitrogen oxides (NOx) Carbon monoxide and carbon dioxide *

11 Toxicological information · Information on toxicological effects Oral LD50: LD50 (rat) > 5000 mg /kg Dermal LD50: LD50 (rat) > 5000 mg/kg · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. · Carcinogenic categories · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed.

12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability The single components are biodegradable · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. (Contd. on page 6) USA


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· Other adverse effects No further relevant information available.

13 Disposal considerations · Waste treatment methods · Recommendation: When container is empty, press valve to release all remaining pressure. Wrap and discard empty container in household garbage · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleaning agents.

14 Transport information · UN-Number · DOT, ADR, IMDG, IATA

UN1950

· UN proper shipping name · ADR · IMDG · IATA

1950 AEROSOLS AEROSOLS AEROSOLS, non-flammable

· Transport hazard class(es) · DOT

· Class · Label

2 Gases. 2.2

· ADR

· Class · Label

2 5A Gases 2.2

· IMDG, IATA

· Class · Label

2.2 2.2

· Packing group · DOT, ADR, IMDG, IATA

Void (Contd. on page 7) USA


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Trade name: Chrysal silk and dried flower cleaner (Contd. of page 6)

· Environmental hazards: · Marine pollutant:

No

· Special precautions for user · Danger code (Kemler): · EMS Number:

Warning: Gases F-D,S-U

· Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code · Transport/Additional information:

*

Not dangerous according to the above specifications.

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): 106-97-8 butane 74-98-6 propane 75-28-5 isobutane 7732-18-5 water, distilled, conductivity or of similarpurity · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. (Contd. on page 8) USA


35.0

Page 8/8

Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 07/09/2012

Version: 3

Reviewed on 07/09/2012

Trade name: Chrysal silk and dried flower cleaner (Contd. of page 7)

¡ Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ¡ * Data compared to the previous version altered. USA


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

1. Identification FloralifeÂŽ DCD Cleaner

Product identifier used on label:

Other means of identification, synonyms, etc.: None Recommended use of the product and restrictions on use: Use as a general purpose antimicrobial detergent. Manufacturer/Supplier: Company name: Address:

Floralife, DBA a division of Smithers-Oasis Company 751 Thunderbolt Drive Waterboro, SC 29488 US 843-538-3839 800-471-4248 www.floralife.com

Phone: Fax: Website: Emergency telephone number(s): Emergency Contact:

Rocky Mountain Poison & Drug Center:

303-623-5716 or 877-740-5015

Transportation Emergency: CHEMTREC:

800-424-9300

2. Hazards Identification Classification of the substance or mixture: Physical hazards:

Not classified

Health hazards:

Skin corrosion/irritation Serious eye damage

Category 2 Category 1

Environmental hazards:

Hazardous to the aquatic environment, acute hazard Hazardous to the aquatic environment, long-term hazard

Category 1

OSHA defined hazards:

Not classified

Label elements:

Hazard pictograms: Signal word:

DANGER

Category 2


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

Hazard statements:

Causes serious skin irritation. Causes serious eye damage. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Precautionary statements: Prevention:

Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves. Wear eye/face protection.

Response:

Collect spillage. If on skin: Wash with warm water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Immediately call a poison center/doctor. Specific treatment: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be needed. Store away from incompatible materials. Dispose of contents/container in accordance with local/national regulations â&#x20AC;&#x201C; see Section 13.

Storage: Disposal:

Hazards not otherwise classified: None 3. Composition Information on Ingredients Chemical characterization: Chemical name & concentration . Alcohol ethoxylate

CAS #

%

Proprietary**

2-<5

_Alkyl (68% C12, 32% C14) dimethyl ethylbenzl ammonium chloride

85409-23-0, or 68956-79-6

1-<3

_Alkyl (68% C12, 32% C14) dimethyl benzl ammonium chloride

68391-01-5

1-<3

Soda ash

68131-39-5

2-<5

TRADE SECRET**

Proprietary**

1-<3

Ethanol

64-17-5

<1

Chemia #2412 Citrus Quat

Unknown

< 0.3

FD & C Yellow #5 Dye

Mixture

< 0.1

Water

7732-18-5

80 â&#x20AC;&#x201C; 90


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

** Designates that a specific identity and/or percentage of concentration has been withheld as a trade secret. 4. First Aid Measures General information: Inhalation:

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact:

Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Eye contact:

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Get medical attention immediately.

Ingestion:

Rinse mouth. Get medical attention if symptoms occur.

Most important symptoms/ effects, acute and delayed:

Symptoms may include stinging,tearing, redness, swelling, and blurred vision. Permanent eye damage including bklindness could result. Skin irritation. May cause redness and pain.

Indication of immediate medical attention and special treatment needed: If the product is ingested, probable mucosal damage may contraindicate the use of gastic lavage. Treat the affected person appropriately. 5. Fire Fighting Measures Suitable extinguishing media:

Water spray, foam, carbon dioxide or dry chemical.

Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire. Special hazards arising from the substance or mixture:

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters: Firefighters should wear full protective bunker gear used in fighting fires, including self-contained breathing apparatus. Fire-fighting equipment/ Instructions: Specific methods:

Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials.


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

General fire hazards:

No unusual fire or explosion hazards noted.

6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures: Keep unnecessary personal away. Keep people away from and upwind of spill/leak. Wear appropriate equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillage cannot be contained. For personal protection, see Section 8 of this SDS. Methods and material for containment and cleaning up: Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see Section13 of this SDS. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer without previously notifying the local sewerage treatment authority. For guidance, contact your State Water Board or Regional Office of the EPA. Environmental precautions:

Avoid release to the environment. Contact local authorities in cases of spillage to drains/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or into the ground.

7. Handling and Storage Precautions for safe handling:

Do not get this material in contact with eyes. Avoid contact with skin. Avoid contact with clothing. Provide adequate ventilation. Avoid releases to the environment. Do not empty into drains.


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

Information about protection against explosions and fires: No special measures required.

Conditions for safe storage, including any incompatibilities:

DO NOT CONTAMINATE WATER< FOOD OR FEED BY STORAGE OR DISPOSAL, PESTICIDE STORAGE. Store in a dry place no lower in temperature than 50 °F or higher than 120 °F. Store in original tightly closed container. Store away from incompatible materials, see Section 10 of this SDS.

8. Exposure Controls / Personal Protection Occupational exposure limits:

No exposure limits need for ingredient(s). .

Appropriate engineering controls:

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.

Individual protection measures, such as personal protective equipment:

Eye/face protection:

Wear safety glasses with side shields (or goggles) and a face shield.

Hand protection

Wear appropriate chemical resistant gloves.

Skin protection other:

Wear appropriate chemical resistant clothing.

Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards: General hygienic considerations:

Wear appropriate thermal protective clothing, when necessary.

Always observe good hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance: Physical state:

Liquid


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

Color: Odor: Odor threshold: Vapor pressure at 20 °C (68 °F): Vapor density: Relative density: Specific gravity: pH value: Change in condition: Melting point/Melting range: Boiling point/Boiling range: Flash point: Flammability (solid, gaseous): Flammable or explosion limits: Lower/Upper: Ignition temperature: Auto ignition temperature: Decomposition temperature: Danger of explosion: Solubility in/miscibility with water: Evaporation rate: Partition coefficient (n-octanol/water): Viscosity: Dynamic/Kinematic: Solvent content: Organic solvents: Water: Solids content: Other information:

Green Citrus scent Not available. Not applicable Heavier than air. 8.66 lb/gal 1.041 g/ml 11.7 (13% solids in aqueous medium). 32 °F 212 °F > 201 °F Not applicable. Not available. 600 °F Product is not selfigniting. Not available. Product does not present an explosion hazard as shipped. Complete Slower than ethyl ether Not available. < 100 cP @ 25 °C Not available. Not applicable. Moisture content < 6% >94% Not available.

10. Stability and Reactivity Reactivity:

Chemical Stability:

This product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions.

Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use. Conditions to avoid:

Avoid temperatures exceeding the flash point. Reacts violently with strong acids. This product may react with oxidizing agents. Do not mix with other chemicals, or have contact with incompatible materials No known conditions to be avoided.

Incompatible materials:

Strong oxidizing agents. Anionic surfactants.


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

Hazardous decomposition products:

Carbon decomposition, this product may yield oxides of nitrogen and ammonia, carbon dioxide, carbon monoxide and other low molecular weight hydrocarbons.

11. Toxicological information Information on the likely routes of Exposure: Ingestion:

May be harmful is swallowed.

Inhalation:

Prolonged inhalation may be harmful.

Skin contact:

Causes skin irritation.

Eye contact:

Causes serious eye damage.

Symptoms related to the Physical, chemical and Toxicological characteristics: Information on toxicological effects: Acute Toxicity: Of Product Dermal LD50

Rabbit

> 5,000 mg/kg

Oral LD50

Rat

> 5,000 mg/kg

Skin corrosion/irritation:

Causes skin irritation.

Serious eye damage/ Eye irritation:

Causes serious eye damage.

Respiratory or skin sensitization: Respiratory sensitization:

Not available.

Skin sensitization:

This product is not expected to cause skin sensitization.

Germ cell mutagenicity:

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity:

This product is not considered to be a carcinogen by IARC, ACGIH, NTP or OSHA.

Reproductive toxicity:

This product is not expected to cause reproductive or developmental effects.


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

Specific target organ toxicity single exposure:

Not applicable.

Specific target organ toxicity repeated exposure:

Not applicable.

Aspiration hazard:

Not likely, due to the form of the product.

12. Ecological Information Ecotoxicity:

Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Dermal LD50

Rabbit

> 5,000 mg/kg

Oral LD50

Rat

> 5,000 mg/kg

Components: Sodium Carbonate (or soda ash) (CAS # 497-19-8) Aquatic Crustacea EC50 Water flea (Ceriodaphnia dubia) hrsFish LC50 Bluegill (Lepomis macrochirus)

156.6 â&#x20AC;&#x201C; 298.9 mg/l, 48 300 mg/l 96 hrs

Persistence and degradability:

No data is available on the degradability of this product.

Bioaccumulative potential:

Not data available.

Mobility in soil:

Not data available.

Additional ecological information:

None.

General notes:

None.

Other adverse effects:

No other adverse environmental effects (e.g., ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal Considerations Disposal instructions:

PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. (For products with household/residential use-sites only): CONTAINER DISPOSAL â&#x20AC;&#x201C; Nonrefillable container. Do not reuse or refill this container. Offer for recycling if available.


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

(For products with industrial, institutional and commercial use sites): CONTAINER DISPOSAL â&#x20AC;&#x201C; Nonrefillable container. Do not reuse or refill this container. Offer for recycling, if available. Triple rinse container promptly after emptying. (For containers 5 gallons or less): Triple rinse as follows: Fill container Âź full with water and recap. Agitate vigorously. Follow Pesticide Disposal instructions for rinsate disposal. Drain for 10 seconds after the flow begins to drip. Repeat procedure two more times. Then offer for recycling or reconditioning. If not available, puncture and dispose in a sanitary landfill. Local disposal regulations:

Dispose in accordance with all applicable regulations.

Hazardous waste code:

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Waste from residues/reused Products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues, follow label warnings even after container is emptied. Contaminated packaging:

14. Transport Information DOT Non-Bulk:

Not regulated as dangerous goods.

DOT Bulk:

Not regulated as dangerous goods.

IATA: UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Special precautions for use before handling. IMDG: UN number UN proper shipping name Transport hazard class(es) Class

UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (QUATERNARY AMMONIUM CHLORIDE) 9 III YES Read safety instructions, SDS and emergency procedures

UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (QUATERNARY AMMONIUM CHLORIDE) 9


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

Subsidiary risk Packing group Environmental hazards Special precautions for use before handling.

III YES Read safety instruction, SDS and emergency procedures

Transport in bulk according to Annex II Of MARPOL 73/78 and the IBC Code 4:

Not available..

15. Regulatory Information US Federal Regulations: This product is a USEPA registered pesticide. This material is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.under OSHA regulations. CERCLA Hazardous Substance List (29 CFR 1910.1001-1050) Not listed. US OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories

Acute (Immediate) Health Hazard: Chronic (Delayed) Health Hazard: Fire Hazard: Reactive Hazard: Sudden Release of Pressure:

Yes No No No No

SARA 302 Extremely hazardous substances:

No

SARA 311/312 Hazardous chemical:

No

SARA 313 (TRI Reporting) Chemical name 1,4-dioxane Acetaldehyde

CAS number 123-91-1 75-07-0

% by wt. < 0.1 < 0.1

Other Federal Regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated Clean Air Act (CAA) Section 112® Accidental Release Prevention (40 CFR 68.130) Not regulated Safe Drinking Water Act (SDWA) Not regulated


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

FIFRA Information:

This chemical is a pesticide product registered by the Environmental Protection Agency subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of nonpesticide chemicals. Following is the hazard information as required on the pesticide label. DANGER Corrosive. Causes irreversible eye damage and skin burns. Harmful if swallowed. This pesticide is toxic to fish and aquatic invertebrates.

Signal word: Hazard statement:

US state regulations: CALIFORNIA PROPOSITION 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986. This product contains chemical(s) known to the State of California to cause cancer or reproductive harm. International Inventories: Country(s) or region

Inventory name

Australia Canada Canada China Europe

Australian Inventory of Chemical Substances (AICS) Domestic Substance List (DSL) Non-Domestic Substance List (DSL) Inventory of Existing Chemical Substances in China (ECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing & New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals & Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory

Europe Japan Korea New Zealand Philippines United States & Puerto Rico

On inventory (yes/no)*

*A “Yes” indicates that all components of this product comply with the inventory requirements administered by the governing country(s) or is exempt from listing. A “No” indicates that one or more components of the product are not listed on the inventory administered by the governing country(s). 16. Other Information, including date of preparation or last revision NFPA ratings (scale 0 - 4) Health =1 0 Fire =1

1 1

1

0

No No No No No No No No No No No No


Safety Data Sheet (SDS) for DCD Cleaner OSHA Hazard Communication Standard 29 CFR 1910.1200. Prepared to GHS Rev 04.

Date Issued: 08/11/2015;

Reactivity

=0

HMIS-ratings (scale 0 - 4) Health =1 Fire =1 Reactivity = 0 Classification system: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe Disclaimer:

Floralife, DBA a division of Smithers-Oasis Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the userâ&#x20AC;&#x2122;s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.


SAFETY DATA SHEET

1. Identification Product identifier

Crowning Glory Clear

Other means of identification

None.

Recommended use

Spray treatment for flower freshness.

Recommended restrictions

None known.

Manufacturer/Importer/Supplier/Distributor information Floralife, DBA a division of Smithers-Oasis Company Company name 751 Thunderbolt Drive Address Walterboro, SC 29488 US US 843-538-3839 Telephone www.floralife.com Website Not available. E-mail Emergency phone number

CHEMTREC

800-424-9300 303-623-5716 or 877-740-5015

2. Hazard(s) identification Physical hazards

Not classified.

Health hazards

Not classified.

OSHA defined hazards

Not classified.

Label elements Hazard symbol

None.

Signal word

None.

Hazard statement

The mixture does not meet the criteria for classification.

Precautionary statement Prevention

Observe good industrial hygiene practices.

Response

Wash hands after handling.

Storage

Store away from incompatible materials.

Disposal Hazard(s) not otherwise classified (HNOC)

Dispose of waste and residues in accordance with local authority requirements. None known.

3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.

4. First-aid measures Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact

Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact

Rinse with water. Get medical attention if irritation develops and persists.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed

Direct contact with eyes may cause temporary irritation.

Indication of immediate medical attention and special treatment needed

Treat symptomatically.

Crowning Glory Clear 927122 Version #: 01

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Issue date: 08-May-2015

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Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

General information

5. Fire-fighting measures Suitable extinguishing media

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

The product is not flammable.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.

Methods and materials for containment and cleaning up

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling

Observe good industrial hygiene practices.

Conditions for safe storage, including any incompatibilities

Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection Occupational exposure limits

No exposure limits noted for ingredient(s).

Biological limit values

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection Other

Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Wear suitable protective clothing.

Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment.

Thermal hazards

Wear appropriate thermal protective clothing, when necessary.

General hygiene considerations

Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance Physical state

Liquid.

Form

Liquid.

Color

Clear.

Crowning Glory Clear 927122 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

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Odor

Slight Wintergreen

Odor threshold

Not available.

pH

3.5 - 4.5

Melting point/freezing point

Not available.

Initial boiling point and boiling range

Not available.

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits Not available. Flammability limit - lower (%) Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

Not available.

Vapor density

Not available.

Relative density

>1

Solubility(ies) Soluble.

Solubility (water) Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information Explosive properties

Not explosive.

Oxidizing properties

Not oxidizing.

10. Stability and reactivity Reactivity Chemical

The product is stable and non-reactive under normal conditions of use, storage and transport.

stability Possibility of

Material is stable under normal conditions.

hazardous reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid

Contact with incompatible materials.

Incompatible materials

Strong oxidizing agents.

Hazardous decomposition products

No hazardous decomposition products are known.

11. Toxicological information Information on likely routes of exposure No adverse effects due to inhalation are expected. Skin Inhalation contact

No adverse effects due to skin contact are expected.

Eye contact

Direct contact with eyes may cause temporary irritation.

Ingestion

Expected to be a low ingestion hazard.

Symptoms related to the physical, chemical and toxicological characteristics

Direct contact with eyes may cause temporary irritation.

Information on toxicological effects Acute toxicity

Not available.

Skin corrosion/irritation

Prolonged skin contact may cause temporary irritation.

Crowning Glory Clear 927122 Version #: 01

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Issue date: 08-May-2015

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Serious eye damage/eye irritation

Direct contact with eyes may cause temporary irritation.

Respiratory or skin sensitization Not a respiratory sensitizer. Respiratory sensitization This product is not expected to cause skin sensitization.

Skin sensitization Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

Not classified.

Aspiration hazard

Not an aspiration hazard.

12. Ecological information

Persistence and degradability

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product.

Bioaccumulative potential

No data available.

Mobility in soil

No data available.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

Ecotoxicity

13. Disposal considerations Disposal instructions

Collect and reclaim or dispose in sealed containers at licensed waste disposal site.

Local disposal regulations

Dispose in accordance with all applicable regulations.

Hazardous waste code

The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

Waste from residues / unused products Contaminated packaging

14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not established. Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information US federal regulations

One or more components are not listed on TSCA. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Crowning Glory Clear 927122 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

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CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Hazard categories Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical

No

SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA)

Not regulated.

US state regulations US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Pennsylvania Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Australia

Inventory name Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)* No

Canada

Domestic Substances List (DSL)

Canada

Non-Domestic Substances List (NDSL)

No

China

Inventory of Existing Chemical Substances in China (IECSC)

No

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe

European List of Notified Chemical Substances (ELINCS)

No

Japan

Inventory of Existing and New Chemical Substances (ENCS)

No

Korea

Existing Chemicals List (ECL)

No

New Zealand

New Zealand Inventory

No

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

No

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

No

Yes

Yes

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) or is exempt from listing. A "No" indicates that one or more components of the product are not listed on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date

08-May-2015

Revision date

-

Version #

01

Crowning Glory Clear 927122 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

5/6


HMISÂŽ ratings

Health: 0 Flammability: 0 Physical hazard: 0

Disclaimer

Floralife, DBA a division of Smithers-Oasis Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the userâ&#x20AC;&#x2122;s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

Crowning Glory Clear 927122 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

6/6


SAFETY DATA SHEET

1. Identification Product identifier

Crowning Glory Regular

Other means of identification

None.

Recommended use

Spray treatment for flower freshness.

Recommended restrictions

None known.

Manufacturer/Importer/Supplier/Distributor information

Telephone Website E-mail

Floralife, DBA a division of Smithers-Oasis Company 751 Thunderbolt Drive Walterboro, SC 29488 US US 843-538-3839 www.floralife.com Not available.

Emergency phone number

CHEMTREC

Company name Address

800-424-9300 303-623-5716 or 877-740-5015

2. Hazard(s) identification Physical hazards

Not classified.

Health hazards

Not classified.

OSHA defined hazards

Not classified.

Label elements Hazard symbol

None.

Signal word

None.

Hazard statement

The mixture does not meet the criteria for classification.

Precautionary statement Prevention

Observe good industrial hygiene practices.

Response

Wash hands after handling.

Storage

Store away from incompatible materials.

Disposal

Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwise classified (HNOC)

None known.

3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.

4. First-aid measures Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact

Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact

Rinse with water. Get medical attention if irritation develops and persists.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed

Direct contact with eyes may cause temporary irritation.

Indication of immediate medical attention and special treatment needed

Treat symptomatically.

Crowning Glory Regular 927086 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

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Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

General information

5. Fire-fighting measures Suitable extinguishing media

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

The product is not flammable.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.

Methods and materials for containment and cleaning up

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling

Observe good industrial hygiene practices.

Conditions for safe storage, including any incompatibilities

Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection Occupational exposure limits

No exposure limits noted for ingredient(s).

Biological limit values

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection Other

Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Wear suitable protective clothing.

Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment.

Thermal hazards

Wear appropriate thermal protective clothing, when necessary.

General hygiene considerations

Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance

Milky liquid.

Physical state

Liquid.

Form

Liquid.

Color

Milky white.

Crowning Glory Regular 927086 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

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Odor

Slight acrylic.

Odor threshold

Not available.

pH

7.5 - 8.5

Melting point/freezing point

Not available.

Initial boiling point and boiling range

Not available.

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits Not available. Flammability limit - lower (%) Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available. Not available.

Vapor pressure Vapor density

Not available.

Relative density

>1

Solubility(ies) Solubility (water)

Soluble.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information Explosive properties

Not explosive.

Oxidizing properties

Not oxidizing.

10. Stability and reactivity Reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability

Material is stable under normal conditions.

Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid

Contact with incompatible materials.

Incompatible materials

Strong oxidizing agents.

Hazardous decomposition products

No hazardous decomposition products are known.

11. Toxicological information Information on likely routes of exposure No adverse effects due to inhalation are expected. Inhalation Skin contact

No adverse effects due to skin contact are expected.

Eye contact

Direct contact with eyes may cause temporary irritation.

Ingestion

Expected to be a low ingestion hazard.

Symptoms related to the physical, chemical and toxicological characteristics

Direct contact with eyes may cause temporary irritation.

Information on toxicological effects Acute toxicity

Not available.

Skin corrosion/irritation

Prolonged skin contact may cause temporary irritation.

Crowning Glory Regular 927086 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

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Serious eye damage/eye irritation

Direct contact with eyes may cause temporary irritation.

Respiratory or skin sensitization Not a respiratory sensitizer. Respiratory sensitization This product is not expected to cause skin sensitization.

Skin sensitization Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

Not classified.

Aspiration hazard

Not an aspiration hazard.

12. Ecological information

Persistence and degradability

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product.

Bioaccumulative potential

No data available.

Mobility in soil

No data available.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

Ecotoxicity

13. Disposal considerations Disposal instructions

Collect and reclaim or dispose in sealed containers at licensed waste disposal site.

Local disposal regulations

Dispose in accordance with all applicable regulations.

Hazardous waste code

The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

Waste from residues / unused products Contaminated packaging

14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not established. Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information US federal regulations

One or more components are not listed on TSCA. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Crowning Glory Regular 927086 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

4/6


CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical

No

SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA)

Not regulated.

US state regulations US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Pennsylvania Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Australia

Inventory name Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)* No

Canada

Domestic Substances List (DSL)

No

Canada

Non-Domestic Substances List (NDSL)

No

China

Inventory of Existing Chemical Substances in China (IECSC)

No

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe

European List of Notified Chemical Substances (ELINCS)

No

Japan

Inventory of Existing and New Chemical Substances (ENCS)

No

Korea

Existing Chemicals List (ECL)

No

New Zealand

New Zealand Inventory

No

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

No

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

Yes

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s), or is exempt from listing. A "No" indicates that one or more components of the product are not listed on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date

08-May-2015

Revision date

-

Version #

01

Crowning Glory Regular 927086 Version #: 01

SDS US Revision date: -

Issue date: 08-May-2015

5/6


HMISÂŽ ratings

Disclaimer

Crowning Glory Regular 927086 Version #: 01

Health: 0 Flammability: 0 Physical hazard: 0 Floralife, DBA a division of Smithers-Oasis Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the userâ&#x20AC;&#x2122;s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

SDS US Revision date: -

Issue date: 08-May-2015

6/6


SAFETY DATA SHEET

1. Identification Product identifier

Hydroflor 100 (Powder)

Other means of identification

None.

Recommended use

Postharvest uptake hydration treatment for cut flowers.

Recommended restrictions

None known.

Manufacturer/Importer/Supplier/Distributor information Floralife, DBA a division of Smithers-Oasis Company Company name 751 Thunderbolt Drive Address Walterboro, SC 29488 US US 843-538-3839 Telephone www.floralife.com Website Not available. E-mail Emergency phone number

CHEMTREC

800-424-9300 303-623-5716 or 877-740-5015

2. Hazard(s) identification Physical hazards

Not classified.

Health hazards

Serious eye damage/eye irritation

OSHA defined hazards

Not classified.

Category 1

Label elements

Signal word

Danger

Hazard statement

Causes serious eye damage.

Precautionary statement Prevention

Wear eye/face protection.

Response

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor.

Storage

Store away from incompatible materials.

Disposal Hazard(s) not otherwise classified (HNOC)

Dispose of waste and residues in accordance with local authority requirements. None known.

Supplemental information Toxic to aquatic life with long lasting effects.

3. Composition/information on ingredients Mixtures Chemical name

CAS number

%

Aluminium sulfate

10043-01-3

93

TRADE SECRET

Proprietary

7

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

Hydroflor 100 (Powder) 925749 Version #: 02

SDS US Revision date: 25-June-2015

Issue date: 18-March-2015

1/7


4. First-aid measures Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact

Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Ingestion

Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Rinse mouth. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Dusts may irritate the respiratory tract, skin and eyes.

Indication of immediate medical attention and special treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures Suitable extinguishing media

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

This material hydrolyzes in water to form aluminium hydroxide and sulfuric acid.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Move containers from fire area if you can do it without risk. Use water spray to cool unopened containers.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

The product is not flammable.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Absorb in vermiculite, dry sand or earth and place into containers. Collect dust using a vacuum cleaner equipped with HEPA filter. Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste container. Avoid the generation of dusts during clean-up. Following product recovery, flush area with water. Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Hydroflor 100 (Powder) 925749 Version #: 02

Minimize dust generation and accumulation. Provide appropriate exhaust ventilation at places where dust is formed. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Protect from moisture. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).

SDS US Revision date: 25-June-2015

Issue date: 18-March-2015

2/7


8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components

Type

Aluminium sulfate (CAS 10043-01-3)

TWA

Value 1 mg/m3

Form Respirable fraction.

US. NIOSH: Pocket Guide to Chemical Hazards Components

Type

Aluminium sulfate (CAS 10043-01-3)

TWA

Value 2 mg/m3

Biological limit values

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. If engineering measures are not sufficient to maintain concentrations of dust particulates below the Occupational Exposure Limit (OEL), suitable respiratory protection must be worn. If material is ground, cut, or used in any operation which may generate dusts, use appropriate local exhaust ventilation to keep exposures below the recommended exposure limits. Provide eyewash station.

Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles) and a face shield. Eye/face protection Skin protection Hand protection Other

Wear appropriate chemical resistant gloves. Wear suitable protective clothing.

Respiratory protection Thermal hazards General hygiene considerations

Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance Physical state

Solid.

Form

Powder.

Color

White.

Odor

Odorless.

Odor threshold

Not available.

pH

Not available.

Melting point/freezing point

Not available.

Initial boiling point and boiling range

Not available.

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Non flammable.

Upper/lower flammability or explosive limits Not available. Flammability limit - lower (%) Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

Not available.

Vapor density

Not available.

Hydroflor 100 (Powder) 925749 Version #: 02

SDS US Revision date: 25-June-2015

Issue date: 18-March-2015

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700 (kg/m3)

Relative density Solubility(ies)

Not available.

Solubility (water) Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information Explosive properties

Not explosive.

Oxidizing properties

Not oxidizing.

Percent volatile

Non-volatile

10. Stability and reactivity Reactivity Chemical

The product is stable and non-reactive under normal conditions of use, storage and transport.

stability Possibility of

Material is stable under normal conditions.

hazardous reactions

Corrosive to metals in the presence of water.

Conditions to avoid

Contact with incompatible materials.

Incompatible materials

Water, moisture. Strong oxidizing agents.

Hazardous decomposition products

This material hydrolyzes in water to form aluminium hydroxide and sulfuric acid.

11. Toxicological information Information on likely routes of exposure Dust may irritate respiratory system. Prolonged inhalation may be harmful. Inhalation Skin contact

Dust or powder may irritate the skin.

Eye contact

Causes serious eye damage.

Ingestion

Expected to be a low ingestion hazard.

Symptoms related to the physical, chemical and toxicological characteristics

Severe eye irritation. Dusts may irritate the respiratory tract, skin and eyes. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.

Information on toxicological effects Acute toxicity

Not available.

Skin corrosion/irritation

Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye irritation

Causes serious eye damage.

Respiratory or skin sensitization Not a respiratory sensitizer. Respiratory sensitization This product is not expected to cause skin sensitization.

Skin sensitization Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

Not classified.

Aspiration hazard

Not an aspiration hazard.

Chronic effects

Prolonged inhalation may be harmful.

Hydroflor 100 (Powder) 925749 Version #: 02

SDS US Revision date: 25-June-2015

Issue date: 18-March-2015

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12. Ecological information Ecotoxicity

Toxic to aquatic life with long lasting effects.

Persistence and degradability

No data is available on the degradability of this product.

Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) TRADE SECRET No data available. Mobility in soil

-0.64

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

Other adverse effects

13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.

14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS Hydroflor 100 (Powder) 925749 Version #: 02

UN3077 Environmentally hazardous substances, solid, n.o.s. (TRADE SECRET) 9 9 III Yes Read safety instructions, SDS and emergency procedures before handling. 8, 146, 335, A112, B54, IB8, IP3, N20, T1, TP33 155 213 240 UN3077 Environmentally hazardous substance, solid, n.o.s. (TRADE SECRET) 9 - III Yes 9L Read safety instructions, SDS and emergency procedures before handling. UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (TRADE SECRET) 9 III Yes F-A, S-F SDS US

Revision date: 25-June-2015

Issue date: 18-March-2015

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Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Aluminium sulfate (CAS 10043-01-3)

LISTED

Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Hazard categories Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical

Yes

SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA)

Not regulated.

US state regulations US. Massachusetts RTK - Substance List Aluminium sulfate (CAS 10043-01-3) US. New Jersey Worker and Community Right-to-Know Act Aluminium sulfate (CAS 10043-01-3) US. Pennsylvania Worker and Community Right-to-Know Law Aluminium sulfate (CAS 10043-01-3) US. Rhode Island RTK Aluminium sulfate (CAS 10043-01-3) US. California Proposition 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. International Inventories Country(s) or region Australia

Inventory name Australian Inventory of Chemical Substances (AICS)

Canada

Domestic Substances List (DSL)

Yes

Canada

Non-Domestic Substances List (NDSL)

No

China

Inventory of Existing Chemical Substances in China (IECSC)

Yes

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

Yes

Europe

European List of Notified Chemical Substances (ELINCS)

Hydroflor 100 (Powder) 925749 Version #: 02

On inventory (yes/no)* Yes

No SDS US

Revision date: 25-June-2015

Issue date: 18-March-2015

6/7


Country(s) or region Japan

Inventory name Inventory of Existing and New Chemical Substances (ENCS)

On inventory (yes/no)* Yes

Korea

Existing Chemicals List (ECL)

Yes

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

Yes

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) or is exempt from listing. A "No" indicates that one or more components of the product are not listed on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date

18-March-2015

Revision date

25-June-2015

Version #

02 Health: 3 Flammability: 0 Physical hazard: 1

HMISÂŽ ratings

List of abbreviations Disclaimer

Hydroflor 100 (Powder) 925749 Version #: 02

TWA: Time weighted average. Floralife, DBA a division of Smithers-Oasis Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the userâ&#x20AC;&#x2122;s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

SDS US Revision date: 25-June-2015

Issue date: 18-March-2015

7/7


SAFETY DATA SHEET

1. Identification Product identifier Other means of identification

Hydroflor Clear 100 None.

Recommended use

Postharvest hydrating pretreatment.

Recommended restrictions

None known.

Manufacturer/Importer/Supplier/Distributor information

Telephone Website E-mail

Floralife, DBA a division of Smithers-Oasis Company 751 Thunderbolt Drive Walterboro, SC 29488 US US 843-538-3839 www.floralife.com Not available.

Emergency phone number

CHEMTREC

Company name Address

800-424-9300 303-623-5716 or 877-740-5015

2. Hazard(s) identification Physical hazards

Not classified.

Health hazards

Skin corrosion/irritation

Category 2

Serious eye damage/eye irritation

Category 2A

Not classified.

OSHA defined hazards Label elements

Signal word

Warning

Hazard statement

Causes skin irritation. Causes serious eye irritation.

Precautionary statement Prevention

Wash thoroughly after handling. Wear protective gloves. Wear eye/face protection.

Response

If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Storage

Store away from incompatible materials.

Disposal

Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwise classified (HNOC)

None known.

3. Composition/information on ingredients Mixtures Chemical name Citric acid Sulfuric acid Trade secret ingredients Water Hydroflor Clear 100 925762 Version #: 01

CAS number

%

77-92-9

<8

7664-93-9

<1

Trade Secret

<1

7732-18-5

> 90 SDS US

Revision date: -

Issue date: 12-March-2015

1/7


*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact

Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur.

Eye contact Ingestion Most important symptoms/effects, acute and delayed

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.

Indication of immediate medical attention and special treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures Suitable extinguishing media

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

This product is an aqueous mixture which will not burn.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Should not be released into the environment. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities

Hydroflor Clear 100 925762 Version #: 01

Avoid contact with eyes, skin, and clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

SDS US Revision date: -

Issue date: 12-March-2015

2/7


8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components

Type

Value

Sulfuric acid (CAS 7664-93-9)

PEL

1 mg/m3

Components

Type

Value

Form

Sulfuric acid (CAS 7664-93-9)

TWA

0.2 mg/m3

Thoracic fraction.

US. ACGIH Threshold Limit Values

US. NIOSH: Pocket Guide to Chemical Hazards Components

Type

Value

Sulfuric acid (CAS 7664-93-9) Biological limit values

TWA

1 mg/m3

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.

Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection

Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing.

Other Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment.

Thermal hazards

Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

General hygiene considerations

9. Physical and chemical properties Appearance Physical state

Liquid.

Form

Liquid.

Color

Colorless to light yellow.

Odor

Slight odor.

Odor threshold

Not available.

pH

1.2 - 1.3

Melting point/freezing point

Not available.

Initial boiling point and boiling range

Not available.

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits Not available. Flammability limit - lower (%) Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Hydroflor Clear 100 925762 Version #: 01

SDS US Revision date: -

Issue date: 12-March-2015

3/7


Vapor pressure

Not available.

Vapor density

Not available.

Relative density

1.08

Solubility(ies) Solubility (water)

Soluble.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information Explosive properties

Not explosive.

Oxidizing properties

Not oxidizing.

10. Stability and reactivity Reactivity

Reacts violently with strong alkaline substances. This product may react with reducing agents.

Chemical stability

Material is stable under normal conditions.

Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid

Do not mix with other chemicals. Contact with incompatible materials.

Incompatible materials

Bases. Reducing agents.

Hazardous decomposition products

Carbon oxides. Halogens. Metal oxides. Nitrogen oxides. Sulfur oxides.

11. Toxicological information Information on likely routes of exposure Prolonged inhalation may be harmful. Inhalation Skin contact

Causes skin irritation.

Eye contact

Causes serious eye irritation.

Ingestion

May cause discomfort if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.

Information on toxicological effects Acute toxicity Components

Species

Test Results

Rat

2140 mg/kg

Sulfuric acid (CAS 7664-93-9) Acute Oral LD50 Skin corrosion/irritation

Causes skin irritation.

Serious eye damage/eye irritation

Causes serious eye irritation.

Respiratory or skin sensitization Not a respiratory sensitizer. Respiratory sensitization This product is not expected to cause skin sensitization.

Skin sensitization Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Hydroflor Clear 100 925762 Version #: 01

This product is not expected to cause reproductive or developmental effects.

SDS US Revision date: -

Issue date: 12-March-2015

4/7


Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

Not classified.

Aspiration hazard

Not an aspiration hazard.

12. Ecological information

Persistence and degradability

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product.

Bioaccumulative potential

No data available.

Mobility in soil

No data available.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

Ecotoxicity

13. Disposal considerations Disposal instructions

Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.

14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not established. Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are listed on or exempt from the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Sulfuric acid (CAS 7664-93-9)

LISTED

Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Hazard categories Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No

Hydroflor Clear 100 925762 Version #: 01

SDS US Revision date: -

Issue date: 12-March-2015

5/7


SARA 302 Extremely hazardous substance Chemical name

CAS number

Reportable quantity (pounds)

Threshold planning quantity (pounds)

Sulfuric acid

7664-93-9

1000

1000

SARA 311/312 Hazardous chemical

Threshold planning quantity, lower value (pounds)

Threshold planning quantity, upper value (pounds)

Yes

SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Sulfuric acid (CAS 7664-93-9) Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Sulfuric acid (CAS 7664-93-9) 6552 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Sulfuric acid (CAS 7664-93-9) DEA Exempt Chemical Mixtures Code Number Sulfuric acid (CAS 7664-93-9)

20 %WV 6552

US state regulations US. Massachusetts RTK - Substance List Sulfuric acid (CAS 7664-93-9) US. New Jersey Worker and Community Right-to-Know Act Sulfuric acid (CAS 7664-93-9) US. Pennsylvania Worker and Community Right-to-Know Law Sulfuric acid (CAS 7664-93-9) US. Rhode Island RTK Sulfuric acid (CAS 7664-93-9) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Sulfuric acid (CAS 7664-93-9) International Inventories Country(s) or region Australia

Inventory name Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)* Yes

Canada

Domestic Substances List (DSL)

Canada

Non-Domestic Substances List (NDSL)

China

Inventory of Existing Chemical Substances in China (IECSC)

Yes

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

Yes

Europe

European List of Notified Chemical Substances (ELINCS)

No

Japan

Inventory of Existing and New Chemical Substances (ENCS)

No

Korea

Existing Chemicals List (ECL)

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

Yes

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

Yes No

No

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s), or is exempt from listing. A "No" indicates that one or more components of the product are not listed on the inventory administered by the governing country(s).

Hydroflor Clear 100 925762 Version #: 01

SDS US Revision date: -

Issue date: 12-March-2015

6/7


16. Other information, including date of preparation or last revision Issue date

12-March-2015

Revision date

-

Version #

01 Health: 2 Flammability: 0 Physical hazard: 0

HMISÂŽ ratings

List of abbreviations

Disclaimer

Hydroflor Clear 100 925762 Version #: 01

PEL: Permissible Exposure Limit. TWA: Time weighted average. Floralife, DBA a division of Smithers-Oasis Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the userâ&#x20AC;&#x2122;s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

SDS US Revision date: -

Issue date: 12-March-2015

7/7


SAFETY DATA SHEET

1. Identification Product identifier

Quick Dip

Other means of identification

None.

Recommended use

Instant hydration pretreatment for fresh cut flowers.

Recommended restrictions

None known.

Manufacturer/Importer/Supplier/Distributor information

Telephone Website E-mail

Floralife, DBA a division of Smithers-Oasis Company 751 Thunderbolt Drive Walterboro, SC 29488 US US 843-538-3839 www.floralife.com Not available.

Emergency phone number

CHEMTREC

Company name Address

800-424-9300 303-623-5716 or 877-740-5015

2. Hazard(s) identification Physical hazards

Not classified.

Health hazards

Not classified.

OSHA defined hazards

Not classified.

Label elements Hazard symbol

None.

Signal word

None.

Hazard statement

The mixture does not meet the criteria for classification.

Precautionary statement Prevention

Observe good industrial hygiene practices.

Response

Wash hands after handling.

Storage

Store away from incompatible materials.

Disposal

Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwise classified (HNOC)

None known.

3. Composition/information on ingredients Mixtures Chemical name

CAS number

%

77-92-9

<5

Sulfuric acid

7664-93-9

<1

Water

7732-18-5

> 95

Citric acid

4. First-aid measures Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact

Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact

Rinse with water. Get medical attention if irritation develops and persists.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Quick Dip 926274 Version #: 01

SDS US Revision date: -

Issue date: 16-April-2015

1/6


Most important symptoms/effects, acute and delayed

Direct contact with eyes may cause temporary irritation.

Indication of immediate medical attention and special treatment needed

Treat symptomatically.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures Suitable extinguishing media

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

This product is an aqueous mixture which will not burn.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up

Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors and spray mists. Ensure adequate ventilation. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Avoid contact with eyes, skin, and clothing. Avoid inhalation of vapors and spray mists. Wear appropriate personal protective equipment. Avoid prolonged exposure. Provide adequate ventilation. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components

Type

Value

Sulfuric acid (CAS 7664-93-9)

PEL

1 mg/m3

Components

Type

Value

Form

Sulfuric acid (CAS 7664-93-9)

TWA

0.2 mg/m3

Thoracic fraction.

US. ACGIH Threshold Limit Values

US. NIOSH: Pocket Guide to Chemical Hazards Components

Type

Value

Sulfuric acid (CAS 7664-93-9)

TWA

1 mg/m3

Quick Dip 926274 Version #: 01

SDS US Revision date: -

Issue date: 16-April-2015

2/6


Biological limit values

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection Other

Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Wear suitable protective clothing.

Respiratory protection

In case of insufficient ventilation, wear suitable respiratory equipment.

Thermal hazards

Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

General hygiene considerations

9. Physical and chemical properties Appearance Physical state

Liquid.

Form

Liquid.

Color

Colorless to light yellow.

Odor

Slight odor.

Odor threshold

Not available.

pH

Not available.

Melting point/freezing point

Not available.

Initial boiling point and boiling range

Not available.

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Not applicable.

Upper/lower flammability or explosive limits Not available. Flammability limit - lower (%) Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available. Not available.

Vapor pressure Vapor density

Not available.

Relative density

1.02

Solubility(ies) Solubility (water)

Not available.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information Explosive properties

Not explosive.

Oxidizing properties

Not oxidizing.

10. Stability and reactivity Reactivity Quick Dip 926274 Version #: 01

The product is stable and non-reactive under normal conditions of use, storage and transport. SDS US Revision date: -

Issue date: 16-April-2015

3/6


Chemical stability

Material is stable under normal conditions.

Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid

Contact with incompatible materials.

Incompatible materials

Strong oxidizing agents.

Hazardous decomposition products

No hazardous decomposition products are known.

11. Toxicological information Information on likely routes of exposure No adverse effects due to inhalation are expected. Inhalation Skin contact

No adverse effects due to skin contact are expected.

Eye contact

Direct contact with eyes may cause temporary irritation.

Ingestion

Expected to be a low ingestion hazard.

Symptoms related to the physical, chemical and toxicological characteristics

Direct contact with eyes may cause temporary irritation.

Information on toxicological effects Acute toxicity Components

Species

Test Results

Rat

2140 mg/kg

Sulfuric acid (CAS 7664-93-9) Acute Oral LD50 Skin corrosion/irritation

Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye irritation

Direct contact with eyes may cause temporary irritation.

Respiratory or skin sensitization Not a respiratory sensitizer. Respiratory sensitization This product is not expected to cause skin sensitization.

Skin sensitization Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

Not classified.

Aspiration hazard

Not an aspiration hazard.

12. Ecological information Ecotoxicity Persistence and degradability

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product.

Bioaccumulative potential Mobility in soil

No data available.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations Disposal instructions

Collect and reclaim or dispose in sealed containers at licensed waste disposal site.

Local disposal regulations

Dispose in accordance with all applicable regulations.

Quick Dip 926274 Version #: 01

SDS US Revision date: -

Issue date: 16-April-2015

4/6


Hazardous waste code Waste from residues / unused products Contaminated packaging

When this product as supplied is to be discarded as waste, it does not meet the definition of a RCRA waste under 40 CFR 261. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not established. Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information US federal regulations

This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Sulfuric acid (CAS 7664-93-9)

LISTED

Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name

CAS number

Reportable quantity (pounds)

Threshold planning quantity (pounds)

Sulfuric acid

7664-93-9 No

1000

1000

Threshold planning quantity, lower value (pounds)

Threshold planning quantity, upper value (pounds)

SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Sulfuric acid (CAS 7664-93-9) Not regulated. Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Sulfuric acid (CAS 7664-93-9) 6552 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Sulfuric acid (CAS 7664-93-9) Quick Dip 926274 Version #: 01

20 %WV SDS US

Revision date: -

Issue date: 16-April-2015

5/6


DEA Exempt Chemical Mixtures Code Number Sulfuric acid (CAS 7664-93-9)

6552

US state regulations US. Massachusetts RTK - Substance List Sulfuric acid (CAS 7664-93-9) US. New Jersey Worker and Community Right-to-Know Act Sulfuric acid (CAS 7664-93-9) US. Pennsylvania Worker and Community Right-to-Know Law Sulfuric acid (CAS 7664-93-9) US. Rhode Island RTK Sulfuric acid (CAS 7664-93-9) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Sulfuric acid (CAS 7664-93-9) International Inventories Country(s) or region Australia

Inventory name Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)* Yes

Canada

Domestic Substances List (DSL)

Canada

Non-Domestic Substances List (NDSL)

China

Inventory of Existing Chemical Substances in China (IECSC)

Yes

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

Yes

Europe

European List of Notified Chemical Substances (ELINCS)

Japan

Inventory of Existing and New Chemical Substances (ENCS)

Yes

Korea

Existing Chemicals List (ECL)

Yes

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

Yes

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

Yes No

No

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s), or is exempt from listing. A "No" indicates that one or more components of the product are not listed on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date

16-April-2015

Revision date

-

Version #

01 Health: 0 Flammability: 0 Physical hazard: 0

HMISÂŽ ratings

Disclaimer

Quick Dip 926274 Version #: 01

Floralife, DBA a division of Smithers-Oasis Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the userâ&#x20AC;&#x2122;s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

SDS US Revision date: -

Issue date: 16-April-2015

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SAFETY DATA SHEET

1. Identification Product identifier

FloralifeÂŽ Rose Food Clear 300

Other means of identification

None.

Recommended use

Powder product for vase solutions for cut flowers.

Recommended restrictions

None known.

Manufacturer/Importer/Supplier/Distributor information Floralife, DBA a division of Smithers-Oasis Company Company name 751 Thunderbolt Drive Address Walterboro, SC 29488 US US 843-538-3839 Telephone www.floralife.com Website Not available. E-mail Emergency phone number

CHEMTREC

800-424-9300 303-623-5716 or 877-740-5015

2. Hazard(s) identification Physical hazards

Not classified.

Health hazards

Serious eye damage/eye irritation

OSHA defined hazards

Not classified.

Category 2A

Label elements

Signal word

Warning

Hazard statement

Causes serious eye irritation.

Precautionary statement Prevention

Wash thoroughly after handling. Wear eye protection/face protection.

Response

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage

Store away from incompatible materials.

Disposal Hazard(s) not otherwise classified (HNOC)

Dispose of waste and residues in accordance with local authority requirements. None known.

3. Composition/information on ingredients Mixtures Chemical name

CAS number

%

Dextrose, Anhydrous

50-99-7

> 90

Citric acid

77-92-9

<5

Proprietary

<1

TRADE SECRET

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Components not listed are either non-hazardous or are below reportable limits. Composition comments

FloralifeÂŽ Rose Food Clear 300 927490 Version #: 01 Revision date: -

SDS US Issue date: 25-June-2015

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4. First-aid measures Inhalation

Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact

Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact

Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur.

Ingestion Most important symptoms/effects, acute and delayed

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Dusts may irritate the respiratory tract, skin and eyes.

Indication of immediate medical attention and special treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures Suitable extinguishing media

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire fighting equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

No unusual fire or explosion hazards noted.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Absorb in vermiculite, dry sand or earth and place into containers. Collect dust using a vacuum cleaner equipped with HEPA filter. Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste container. Avoid the generation of dusts during clean-up. Following product recovery, flush area with water. Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Environmental precautions

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Minimize dust generation and accumulation. Provide appropriate exhaust ventilation at places where dust is formed. Avoid contact with eyes. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection Occupational exposure limits

No exposure limits noted for ingredient(s).

Biological limit values

No biological exposure limits noted for the ingredient(s).

FloralifeÂŽ Rose Food Clear 300 927490 Version #: 01 Revision date: -

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Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. If material is ground, cut, or used in any operation which may generate dusts, use appropriate local exhaust ventilation to keep exposures below the recommended exposure limits. Provide eyewash station.

Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations

Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Wear suitable protective clothing. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance Physical state

Solid.

Form

Powder.

Color

White.

Odor

Odorless.

Odor threshold

Not available.

pH

Not available.

Melting point/freezing point

Not available.

Initial boiling point and boiling range

Not available.

Flash point

Not available.

Evaporation rate

Not available.

Flammability (solid, gas)

Not available.

Upper/lower flammability or explosive limits Not available. Flammability limit - lower (%) Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

Not available.

Vapor density

Not available.

Relative density

0.68 g/cc

Solubility(ies) Solubility (water)

Not available.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information Explosive properties

Not explosive.

Oxidizing properties

Not oxidizing.

FloralifeÂŽ Rose Food Clear 300 927490 Version #: 01 Revision date: -

SDS US Issue date: 25-June-2015

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10. Stability and reactivity Reactivity Chemical

The product is stable and non-reactive under normal conditions of use, storage and transport.

stability Possibility of

Material is stable under normal conditions.

hazardous reactions

No dangerous reaction known under conditions of normal use.

Conditions to avoid

Contact with incompatible materials.

Incompatible materials

Strong oxidizing agents.

Hazardous decomposition products

No hazardous decomposition products are known.

11. Toxicological information Information on likely routes of exposure Dust may irritate respiratory system. Inhalation Skin contact

Dust or powder may irritate the skin.

Eye contact

Causes serious eye irritation.

Ingestion

Expected to be a low ingestion hazard.

Symptoms related to the physical, chemical and toxicological characteristics

Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Dusts may irritate the respiratory tract, skin and eyes.

Information on toxicological effects Acute toxicity

Not available.

Skin corrosion/irritation

Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye irritation

Causes serious eye irritation.

Respiratory or skin sensitization Not a respiratory sensitizer. Respiratory sensitization Skin sensitization

This product is not expected to cause skin sensitization.

Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity single exposure

Not classified.

Specific target organ toxicity repeated exposure

Not classified.

Aspiration hazard

Not an aspiration hazard.

12. Ecological information Ecotoxicity Persistence and degradability

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product.

Bioaccumulative potential Mobility in soil

No data available.

Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

FloralifeÂŽ Rose Food Clear 300 927490 Version #: 01 Revision date: -

SDS US Issue date: 25-June-2015

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Waste from residues / unused products Contaminated packaging

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code

15. Regulatory information US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. One or more components are not listed on TSCA.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Hazard categories Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical

Yes

SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA)

Not regulated.

US state regulations US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Pennsylvania Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated.

FloralifeÂŽ Rose Food Clear 300 927490 Version #: 01 Revision date: -

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US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Australia

Inventory name Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)* Yes

Canada

Domestic Substances List (DSL)

Yes

Canada

Non-Domestic Substances List (NDSL)

No

China

Inventory of Existing Chemical Substances in China (IECSC)

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe

European List of Notified Chemical Substances (ELINCS)

No

Japan

Inventory of Existing and New Chemical Substances (ENCS)

No

Korea

Existing Chemicals List (ECL)

No

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

Yes

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes No

Yes

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) or is exempt from listing. A "No" indicates that one or more components of the product are not listed on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date

25-June-2015

Revision date

-

Version #

01 Health: 2 Flammability: 1 Physical hazard: 0

HMIS® ratings

Disclaimer

Floralife, DBA a division of Smithers-Oasis Company cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.

Floralife® Rose Food Clear 300 927490 Version #: 01 Revision date: -

SDS US Issue date: 25-June-2015

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Material Safety Data Sheet Section 1 â&#x20AC;&#x201C; Product Identification

Product Name : Intended Use: Company Name:

HAWAIIAN FLORAL MIST Flower re-hydration spray Alohilani Farms 200 Kanelehua Ave. #400 Hilo, Hawaii 96720

Emergency Contacts: alohilanifarms@gmail.com US 310-831-5057 Intl 163-0999-8008180 Section 2-Ingredients No Hazardous Ingredients known Section 3-Health Hazard Data Eye Contact: May cause eye irritation. Skin Contact: May cause skin irritation. Inhalation Hazard: High doses may cause nasal or lung irritation. Ingestion Hazard: May cause stomach and throat irritation. Section 4-Emergency / First Aid Procedures Eye Contact: Flush eyes with water . Skin Contact: Flush affected area with water. Inhalation: Remove to fresh air. Ingestion: Seek medical advice.

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Section 5-Personel Protection / Exposure Eyes: Use goggles when exposure hazards exist. Skin: Use protective gloves for prolonged or repeated exposure. Respirator: None required under normal usage. Ventilation: Local ventilation acceptable

Exposure Limits OSHA PELS: ACGIH: NIOSH:

Non-hazardous none established Non-hazardous none established Non-hazardous none established

Section 6-Fire Fighting / Explosion Hazard Data Flammable Limits: Non-combustible Fire Extinguishing: Water or appropriate extinguishing media for surrounding fire. Special Procedures: None, Recognize that all fires release hazardous products of combustion, and exposure to flames and smoke should be avoided. Section 7- Reactivity / Stability / Toxicological Stability: Product is considered stable Hazardous Polymerization: Product will not undergo polymerization. Toxicity: Product is not considered toxic. Section 8 - Physical Data Physical Form : Liquid Appearance: Clear Odor: Semi- Odorless Boiling Point: 100C â&#x20AC;&#x201C; 212F (water) Stability in Water: 100% Volatile by Volume: 0% Volatile by Weight: 0% Vapor Pressure: Non Volatile Evaporation Rate: No Information

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Section 9- Spill / Disposal EPA Waste Class : Not regulated Release / spill: Contain spill with inert material (sand/earth) Sweep or shovel into Empty plastic lined container, dispose of according to local/state/ federal laws. Section 10- Transportation US Dept Transportation Hazard Class: Section 11-Storage Storage Temperature:

Non-Regulated

Minimum temperature 1C / 34 F Maximum temperature 49C / 120 F Keep from freezing.

Section 12- Regulatory Information

SARA Title lll Section 311/312: Section 313:

This product is not a hazardous chemical under 29CFR 1910.1200, and therefore is not covered by Title lll of SARA. This product does not contain a chemical listed in section 313 above de minims concentrations.

RCRA:

When this product becomes waste, it is classified as a nonhazardous waste under criteria of the Resource Conservation and Recovery Act (40CFR 216)

CERLA:

Releases of this product into the air, land or water are not reportable to the National Response Center under the Comprehensive Enviromental Response, Compensation, and Liability ACT (CERCLA) or to state and local emergency planning committees under the Super fund Amendments and Reauthorization Act SARA Title lll section 304. 3 of 3


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 08/12/2011

Version: 1

Reviewed on 08/12/2011

1 Identification of the substance/mixture and of the company/undertaking · Product identifier · Trade name: RosePro liquid · Article number: 452.017.155 · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Chrysal International BV P.O. Box 5300 1410 AH NAARDEN Gooimeer 7 1411 DD NAARDEN The Netherlands Tel.: +31 (0)35 6955888 Fax: +31 (0)35 6955822 E-mail: info@chrysal.nl · Information department: Department: Regulatory Affairs

2 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of substances with nonhazardous additions. · Dangerous components: 77-92-9 citric acid

2.5-10%

3 Hazards identification · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Void · Information concerning particular hazards for human and environment: No hazards to be particularly mentioned. Please note the information of this Material Safety Data Sheet. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · Additional information: Canadian Hazard Symbols: This is not a "controlled product" under WHMIS · Label elements · Labelling according to EU guidelines: The substance is not subject to classification according to the sources of literature known to us. Observe the general safety regulations when handling chemicals. · Classification system: · NFPA ratings (scale 0 - 4)

0

0

0

Health = 0 Fire = 0 Reactivity = 0

· Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. CA

(Contd. on page 2)


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 08/12/2011

Version: 1

Reviewed on 08/12/2011

Trade name: RosePro liquid (Contd. of page 1)

4 First aid measures · Description of first aid measures · General information: No special measures required. · After inhalation: No special measures required · After skin contact: Rinse with warm water. Generally the product does not irritate the skin. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water.

5 Firefighting measures · Extinguishing media · Suitable extinguishing agents: Use fire fighting measures that suit the environment. · Advice for firefighters · Protective equipment: No special measures required.

6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Not required. · Environmental precautions: Dilute with plenty of water. · Methods and material for containment and cleaning up: No special measures required. · Reference to other sections No dangerous substances are released.

7 Handling and storage · Handling: · Precautions for safe handling No special measures required. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: None.

8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. (Contd. on page 3) CA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 08/12/2011

Version: 1

Reviewed on 08/12/2011

Trade name: RosePro liquid (Contd. of page 2)

· Breathing equipment: Not required. · Protection of hands: Not required. · Material of gloves · Penetration time of glove material · Eye protection: Not required.

9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Fluid Form: According to product specification Color: Characteristic · Odor: Not determined. · Odour threshold: · pH-value at 20°C:

2.7

· Change in condition Melting point/Melting range: Boiling point/Boiling range:

Undetermined. 100°C

· Flash point:

Not applicable.

· Ignition temperature: Decomposition temperature:

Not determined.

· Auto igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Explosion limits: Lower: Upper:

Not determined. Not determined.

· Vapor pressure at 20°C:

23 hPa

· Density at 20°C: · Relative density · Vapour density · Evaporation rate

1.307 g/cm³ Not determined. Not determined. Not determined.

· Solubility in / Miscibility with Water:

Fully miscible.

· Segregation coefficient (n-octonol/water): Not determined. · Viscosity: Dynamic: Kinematic:

Not determined. Not determined.

· Solvent content: Organic solvents: Water:

0.0 % 37.2 %

Solids content:

62.5 % (Contd. on page 4) CA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 08/12/2011

Version: 1

Reviewed on 08/12/2011

Trade name: RosePro liquid (Contd. of page 3)

· Other information

No further relevant information available.

10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information · Information on toxicological effects · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us.

12 Ecological information · Toxicity · Acquatic toxicity: No further relevant information available. · Persistence and degradability No further relevant information available. · Additional ecological information: · General notes: Do not allow product to reach ground water or water course and do not allow undiluted product to reach sewage system. Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available.

13 Disposal considerations · Waste treatment methods · Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. (Contd. on page 5) CA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 08/12/2011

Version: 1

Reviewed on 08/12/2011

Trade name: RosePro liquid (Contd. of page 4)

· Uncleaned packagings: · Recommendation: Non contaminated packagings can be treated like household garbage. · Recommended cleansing agent: Water, if necessary with cleaning agents.

14 Transport information · DOT regulations: · Hazard class: · TDG (Transport dangerous goods): · TDG class: · Maritime transport IMDG: · IMDG Class: · Marine pollutant: No · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: · Special precautions for user Not applicable. · Transport/Additional information: Not dangerous according to the above specifications.

15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture No hazards to be particularly mentioned. Please note the information of this Material Safety Data Sheet. · Sara · Section 355 (extremely hazardous substances): None of the ingredient is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. (Contd. on page 6) CA


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Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 08/12/2011

Version: 1

Reviewed on 08/12/2011

Trade name: RosePro liquid (Contd. of page 5)

· NTP (National Toxicology Program) None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH) None of the ingredients is listed. · MAK (German Maximum Workplace Concentration) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Chrysal International BV, the Netherlands Department: Product Safety & Regulatory Affairs CA


SAFETY DATA SHEET

1. Identification Product identifier

Superclean 4154

Other means of identification Product code

0620273

Recommended use

Cleaner

Recommended restrictions

None known.

Manufacturer

Superior Oil Company, Inc. 1402 North Capitol Avenue, Suite #100 Indianapolis, IN 46202 US Information (317) 781-4400 Emergency (317) 781-4400

2. Hazard(s) identification Physical hazards

Not classified.

Health hazards

Skin corrosion/irritation

Category 2

Serious eye damage/eye irritation

Category 2A

Hazardous to the aquatic environment, acute hazard

Category 2

Hazardous to the aquatic environment, long-term hazard

Category 3

Environmental hazards

OSHA defined hazards

Not classified.

Label elements

Signal word

WARNING!

Hazard statement H315 H319 H401 H412

Causes severe skin irritation and possible skin damage/burn. Causes serious eye irritation. Toxic to aquatic life. Harmful to aquatic life with long lasting effects.

Prevention

P264 P273 P280 P280

Response

P302 + P350 - IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 - If skin irritation occurs: Get medical advice/attention. P337 + P313 - If eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse.

Storage

Store away from incompatible materials.

Disposal

P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.

-

Wash hands thoroughly after handling. Avoid release to the environment. Wear protective gloves. Wear eye/face protection.

3. Composition/information on ingredients Mixtures Chemical name

Common name and synonyms

CAS number

%

Alkyl Dimethyl Benzyl Ammonium Chloride (C12-C16)

68424-85-1

0.1-10

Disodium Trioxosilicate

6834-92-0

0.1-10

Non-hazardous and other components below reportable levels Material name: Superclean 4154 2401 Version #: 01 Issue date: 05-14-2015

90-100 SDS US

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4. First-aid measures Inhalation

If overexposure to vapors or mist, move to fresh air. Call a physician if breathing becomes difficult.

Skin contact

Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Ingestion

Rinse mouth. Get medical attention if symptoms occur.

Indication of immediate medical attention and special treatment needed

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures Suitable extinguishing media

Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from the chemical

During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Fire-fighting equipment/instructions

Move containers from fire area if you can do so without risk.

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

No unusual fire or explosion hazards noted.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Methods and materials for containment and cleaning up

This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Environmental precautions

Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage Precautions for safe handling

Avoid contact with skin. Avoid contact with eyes. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains.

Conditions for safe storage, including any incompatibilities

Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection Occupational exposure limits

No exposure limits noted for ingredient(s).

Biological limit values

No biological exposure limits noted for the ingredient(s).

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.

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Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection

Wear appropriate chemical resistant gloves.

Skin protection Other Respiratory protection General hygiene considerations

Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance

Clear.

Physical state

Liquid.

Form

Liquid.

Color

Green.

Odor

Mild Amine.

Odor threshold

Not available.

pH

> 12

Melting point/freezing point

32 째F (0 째C)

Initial boiling point and boiling range

212 째F (100 째C) approx.

Flash point

Not available.

Evaporation rate

Same as Water.

Flammability (solid, gas)

Not available.

Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit - upper (%)

Not available.

Vapor pressure

17.5 mm Hg (Water)

Vapor pressure temp.

@ 20 Deg. C

Vapor density

Not available.

Relative density

Not available.

Solubility(ies) Solubility (water)

Complete.

Partition coefficient (n-octanol/water)

Not available.

Auto-ignition temperature

Not available.

Decomposition temperature

Not available.

Viscosity

Not available.

Other information Pounds per gallon

8.51 lb/gal

Specific gravity

1.02

VOC (Weight %)

0.34 %

10. Stability and reactivity Reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability

Stable under normal conditions.

Possibility of hazardous reactions

Hazardous polymerization does not occur.

Conditions to avoid

Contact with incompatible materials.

Incompatible materials

Strong oxidizers and strong acids.

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Hazardous decomposition products

No hazardous decomposition products are known if stored and applied as directed.

11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation

No adverse effects due to inhalation are expected.

Skin contact

Causes skin irritation.

Eye contact

Causes serious eye irritation.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.

Information on toxicological effects Acute toxicity Components

Species

Test Results

Disodium Trioxosilicate (CAS 6834-92-0) Acute

Oral LD50

Mouse

2400 mg/kg

Rat

1280 mg/kg

* Estimates for product may be based on additional component data not shown. Skin corrosion/irritation

Causes skin irritation.

Serious eye damage/eye irritation

Causes serious eye irritation.

Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization

This product is not expected to cause skin sensitization.

Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity - single exposure

Not classified.

Specific target organ toxicity - repeated exposure

Not classified.

Aspiration hazard

Not available.

12. Ecological information Ecotoxicity

Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.

Components

Species

Test Results

Alkyl Dimethyl Benzyl Ammonium Chloride (C12-C16) (CAS 68424-85-1) Aquatic Fish

LC50

Striped bass (Morone saxatilis)

10.4 - 19.1 mg/l, 96 hours

0.28 - 0.57 mg/l, 48 hours

Disodium Trioxosilicate (CAS 6834-92-0) Aquatic Crustacea

EC50

Water flea (Ceriodaphnia dubia)

Fish

LC50

Western mosquitofish (Gambusia affinis) 1800 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown. Persistence and degradability

No data is available on the degradability of this product.

Bioaccumulative potential

No data available.

Mobility in soil

No data available.

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Other adverse effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations Disposal instructions

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations

Dispose in accordance with all applicable regulations.

Waste from residues / unused products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.

14. Transport information DOT BULK UN number Proper shipping name Hazard class Packing group ERG code

3266 Corrosive Liquids, Basic, Inorganic, N.O.S. (Disodium Trioxosilicate, Quaternary Ammonium) 8 III 154

DOT NON-BULK UN number Proper shipping name Hazard class Packing group ERG code

3266 Corrosive Liquids, Basic, Inorganic, N.O.S. (Disodium Trioxosilicate, Quaternary Ammonium) 8 III 154

15. Regulatory information US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical

Yes

SARA 313 (TRI reporting) Chemical name Direct Blue 86 Organically Bound Copper

CAS number

% by wt.

1330-38-7 7440-50-8

0.1-10 0.1-10

Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA)

Not regulated.

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US state regulations US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not regulated. US. Pennsylvania RTK - Hazardous Substances Not regulated. US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Australia

Inventory name Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)* Yes

Canada

Domestic Substances List (DSL)

Canada

Non-Domestic Substances List (NDSL)

China

Inventory of Existing Chemical Substances in China (IECSC)

Europe

European Inventory of Existing Commercial Chemical Substances (EINECS)

No

Europe

European List of Notified Chemical Substances (ELINCS)

No

Yes No Yes

Japan

Inventory of Existing and New Chemical Substances (ENCS)

Korea

Existing Chemicals List (ECL)

Yes

No

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances (PICCS)

Yes

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision Issue date

05-14-2015

Version #

01

Disclaimer

This information is based on data available to us and is accurate and reliable to the best of our knowledge at the time of printing. However, no warranty is expressed or implied regarding the accuracy or completeness of the information contained herein. Final determination of the suitability of this material for the use contemplated is the sole responsibility of the user. Buyer assumes all risk and liabilities. Buyer accepts and uses this material on these conditions.

Revision Information

Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Component Summary Physical & Chemical Properties: Multiple Properties Transport Information: Material Transportation Information Regulatory Information: United States

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