© 2011 BlackLight Power, Inc. All rights reserved.
Chapter 12
454ii
Table 12 .3 . The orbital-nuclear coupling energies Etotal , of molecular hydrinos with the quantum numbers O/ N
orbital-angular momentum vector orientation designated . O/ N O/ N p + + Etotal Etotal 1 2 2 3 3 3 4 4 4 4 5 5 5 5 5
0 0 1 0 1 2 0 1 2 3 0 1 2 3 4
O/ N Etotal
O/ N Etotal
(eV)
( cm )
(eV)
( cm 1 )
0.00E+00 0.00E+00 -5.80E-04 0.00E+00 -2.55E-03 -2.95E-03 0.00E+00 -7.46E-03 -8.61E-03 -9.14E-03 0.00E+00 -1.73E-02 -2.00E-02 -2.12E-02 -2.19E-02
0.0 0.0 -4.7 0.0 -20.6 -23.8 0.0 -60.2 -69.5 -73.7 0.0 -139.7 -161.3 -171.1 -176.7
0.00E+00 0.00E+00 5.80E-04 0.00E+00 2.55E-03 2.95E-03 0.00E+00 7.46E-03 8.61E-03 9.14E-03 0.00E+00 1.73E-02 2.00E-02 2.12E-02 2.19E-02
0.0 0.0 4.7 0.0 20.6 23.8 0.0 60.2 69.5 73.7 0.0 139.7 161.3 171.1 176.7
1
p and , and
REFERENCES 1. A. Carrington, I. R. McNab, C. A. Montgomerie, Spectroscopy of the hydrogen molecular ion, J. Phys. B, 22, (1989), 3551– 3586. 2. A. Carrington, I. R. McNab, C. A. Montgomerie, R. Kennedy, Electronic spectrum (2p u–1 s g) of the D2 ion, Mol. Phys., 67, (1989), 711–738. 3. C. A. Leach, R. E. Moss, Spectroscopy and quantum mechanics of the hydrogen molecular cation: A test of molecular quantum mechanics, Annu. Rev. Phys. Chem., 46, (1995), 55–82. 4. G. R. Fowles, Analytical Mechanics, Third Edition, Holt, Rinehart, and Winston, New York, (1977), pp. 161-164. 5. J. A. Stratton, Electromagnetic Theory, McGraw-Hill Book Company, (1941), pp. 211-215; 257-258. 6. H. Chang, “Fields external to open-structure magnetic devices represented by ellipsoid or spheroid,” British Journal of Applied Physics, Vol. 12, (1961). pp. 160-163. 7. J. A. Stratton, Electromagnetic Theory, McGraw-Hill Book Company, (1941), pp. 56-59. 8. L-W. Li, X-K. Kang, M-S Leong, Spheroidal Wave Functions in Electromagnetic Theory, Wiley Series in Microwave and Optical Engineering, K. Chang, Editor, John Wiley & Sons, Inc., New York, (2002). 9. G. Herzberg, Molecular Spectra and Molecular Structure I. Spectra of Diatomic Molecules, Krieger Publishing Company, Malabar, FL, 2nd Ed., (1989), pp. 530-534. 10. P. W. Atkins, Physical Chemistry, 2nd Ed., W. H. Freeman, San Francisco, (1982), p. 589. 11. J. H. Phillips, Guide to the Sun, Cambridge University Press, Cambridge (1992), pp. 126-127; 360. 12. M. Karplus, R. N. Porter, Atoms and Molecules. An Introduction for Students of Physical Chemistry, The Benjamin/Cummings Publishing Company, Menlo Park, California, (1970), pp. 480-481. 13. M. Karplus, R. N. Porter, Atoms and Molecules. An Introduction for Students of Physical Chemistry, The Benjamin/Cummings Publishing Company, Menlo Park, California, (1970), pp. 469. 14. G. Herzberg, Spectra of Diatomic Molecules, Van Nostrand, Princeton, NJ, (1950).