Page 1

MATERIAL SAFETY DATA SHEET _____________________________________________________________________________________________

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Commercial name Product name Company

: : :

Telefax Telephone (Emergency) e-mail Application

: : : :

Glycerine 99,5 % Glycerine AarhusKarlshamn Sweden AB, Technical Products & Feed S-374 82 KARLSHAMN, SWEDEN +46 454 752005 +46 454 823 00 jenny.porsche@aak.com Cosmetics, food products, tobacco and paints

2. HAZARDS IDENTIFICATION Human health hazards Inhalation : Skin contact Eye contact Ingestion Physical/chemical hazards Environmental hazards

: : :

Not applicable at ambient temperature Vapour from heated product can cause irritation. Not irritating. Can cause irritation. Unlikely to be harmful. Can cause diarrhoea if big amounts are swallowed (> 50g /day for children, > 100g /day for adults)

:

At incomplete combustion can acrolein be formed.

:

None identified.

3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/ preparation : Chemical description : CAS No. : EC No. :

Substance 1,2,3-propane-triol, purity at least 99,5 % 56-81-5 200-289-5

4. FIRST AID MEASURES Inhalation Skin contact Eye contact

: : :

Ingestion

:

Remove to fresh air. Wash off with plenty of water and soap. Wash out with water without delay and obtain medical attention if any sensations persist. Remove material from mouth. Drink plenty of water. If large amount swallowed or symptoms develop obtain medical attention.

5. FIRE-FIGHTING MEASURES Extinguishing media : Unsuitable extinguishing media : Specific hazards : Protection of fire-fighters :

Water spray, foam, dry powder, carbon dioxide. None Formation of acrolein, see point 3 above. Protective clothing and self-contained breathing equipment should be carried (formation of acrolein).

_____________________________________________________________________________________________ Date: 2009-01-27 Trade name: Glycerine 99.5% Manufacturer: AarhusKarlshamn Sweden AB, Technical Products & Feed Web: www.aak.com

1(4)


MATERIAL SAFETY DATA SHEET _____________________________________________________________________________________________

6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions : Methods for cleaning up :

:

No special precautions required.

Minimise contamination of drains, surface and ground waters. Transfer product to suitably labelled containers for disposal at an approved site. Residues and small spillage may be washed away with water and detergent.

7. HANDLING AND STORAGE Handling

:

No specific protective measures are required.

Storage

:

Other information

:

Store in the original closed containers under dry conditions. Avoid extremes of temperatures. For quality reasons: Avoid elevated temperatures.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limit values: Technical measures : Personal protective equipment: :

TWA 10 mg/m³ (mist) Adequate ventilation should be maintained when handling heated product. -

9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : Colour : Odour : pH : Boiling point (1 bara): Solidification point : Flash point (COC) : Autoignition temperature : Explosive/ oxidizing properties : Vapour pressure (20 ºC) : Density (25 ºC) : Solubility : Partition coefficient (log Pow, estimated) Viscosity (30ºC) :

Liquid None Faint Not applicable. 290 ºC approx. Max 18 ºC 177 ºC approx. 400 ºC approx. Not to be expected. < 1 hPa 1260 kg/m³ approx. Totally soluble in water (20 ºC). Soluble in ethanol, partly soluble in Acetone. Unsoluble in ether and chloroform. : -2,5 500 mPa.s approx.

_____________________________________________________________________________________________ Date: 2009-01-27 Trade name: Glycerine 99.5% Manufacturer: AarhusKarlshamn Sweden AB, Technical Products & Feed Web: www.aak.com

2(4)


MATERIAL SAFETY DATA SHEET _____________________________________________________________________________________________

10. STABILITY AND REACTIVITY Stability : Conditions to avoid : Materials to avoid : Hazardous decomposition products : Hazardous polymerization :

Stable under normal conditions. Finely divided in insulation etc the product can catch fire Strong oxidizing agents. Thermal decomposition may release acrolein. Will not occur.

11. TOXICOLOGICAL INFORMATION LD50 oral, rat

:

Skin and eye irritation, rabbit : Skin sensitization :

9,2 g/kg. Not irritating. No sensitization reactions.

12. ECOLOGICAL INFORMATION Degradability Ecotoxicity LC50, fish - 96 hours EC50 algae EC50, Pseudomonas Putida

:

Readily biodegradable BOD5 / COD = 0,75 / 1,00

: :

> 5000 mg/l > 2900 mg/l

:

> 10000 mg/l

13. DISPOSAL CONSIDERATIONS Waste disposal method

:

Contaminated packaging

Re-use/ recycling of waste highly recommended. Disposal according to local legislation.

:

Observe local regulations.

14. TRANSPORT INFORMATION Not classified in RID/ADR - ADNR - IMDG - ICAO/IATA-DGR. 15. REGULATORY INFORMATION EU classification

:

Inventories

:

This product is not dangerous according to the EU regulations (67/548/EEC - 88/379/EEC). Listed on EINECS (EC), TSCA-CSI (USA), DSL (Canada), AICS (Australia) and MITI (Japan).

_____________________________________________________________________________________________ Date: 2009-01-27 Trade name: Glycerine 99.5% Manufacturer: AarhusKarlshamn Sweden AB, Technical Products & Feed Web: www.aak.com

3(4)


MATERIAL SAFETY DATA SHEET _____________________________________________________________________________________________

16. OTHER INFORMATION Literature references

: Acute toxicity and irritation studies on a series of fatty acids. J. AM. Oil Chem. Soc., 56(1979), p. 760A :

Final report of the safety assessment for oleic acid, lauric acid, palmitic acid, myristic acid, stearic acid. CTFA, 1987.

This sheet is based on safety data sheet edited by APAG European association of Fatty Acid Producing companies. To the best of our knowledge, the information contained in this sheet is correct. However, we cannot accept responsibility or liability for any consequences arising from its use.

_____________________________________________________________________________________________ Date: 2009-01-27 Trade name: Glycerine 99.5% Manufacturer: AarhusKarlshamn Sweden AB, Technical Products & Feed Web: www.aak.com

4(4)

/Safety%20data%20sh  

http://www.aak.com/Global/Fatty%20acids,%20glycerine%20and%20deinking%20chemicals/Safety%20data%20sheet/English/e_glycerine_99_5_090127.pdf

Read more
Read more
Similar to
Popular now
Just for you